CHAPTER 6 BONDS Polyatomic ions Name Nitrate Carbonate Chromate Acetate Permanganate Hydroxide Sulfate Chlorate Phosphate Ammonium Symbol NO3 CO3 CrO4 C2H3O2 MnO4 OH SO4 ClO3 PO4 NH4 Flashcards-due Tomorrow-you can make them out of cut paper if you don’t have index cards Charge -1 -2 -2 -1 -1 -1 -2 -1 -3 +1 Lewis DOT DIAGRAMS A model of an atom in which each dot represents a valence eMax # of dots is 8 Li He Ne C X DOT DIAGRAMS Directions Draw dot diagrams for the following elements. 1. Hydrogen 2. Fluorine On your paper 3. Tin Name 1. 4. Sodium 5. Krypton Dot Diagrams CHEMICAL FORMULA Tells what elements a compound contains & the ratio of those elements. Ex: H2O subscript- means “written below” Tells how many atoms of that element superscript-means “written above” Tells charge (oxidation #) of element or compound Ex: PO43- or PO4-3 Ex: List elements & give ratio Your paper Name My paper 1. CuSO4 2. Li2S 11. Mg(OH)2 19. C2H5OH Elements & ratios 1. CuSO4 = 2. Li2S = 11. Mg(OH)2 = 19. C2H5OH = Answers Ex: H2O = Hydrogen, Oxygen 2:1 Fe2O3 = Iron, Oxygen 2:3 Al(C2H3O2)3 = Aluminum, Carbon, Hydrogen, Oxygen 1:6:9:6 HC2H3O2 = Hydrogen, Carbon, Oxygen 1:2:3:2 Star questions How many dots would Helium receive? 2 Define Chemical Formula Tells what elements a compound contains & the ratio of those elements. Subscript means? Written below Superscript means? Written above CHEMICAL BONDS Occur through interactions between the valence electrons!!! Three major types of chemical bonds: 1. Metallic 2. Ionic 3. Covalent METALLIC BONDS Metal + Metal = Metallic Bonds “SEA of ELECTRONS”=valence e- are not held tightly. They are freely moving or swimming around the atom nucleus’ at all times. Forms a lattice structure METALLIC BONDS Characteristics: Malleable Ductile Ex: Aluminum foil: crumpling, wont tear due to strong bonds! More swimming electrons = stronger bonds! IONIC BONDS Formed when elements give up or take e Formed between Metal & NonMetal IONIC BONDS Protons no longer equal electrons!! Particles formed by ionic bonds are called ions (a charged atom) Anion—An ion w/ a negative charge (take e- , more negative) Cation—An ion w/ a positive charge (give up e-, more positive) IONIC BONDS EX: Na + Cl = Na+Cl- Na+ = Cation Cl- = Anion Write the purple words on your reference table! Charge, AKA: Oxidation # Group 1A 1 outer shell egives 1 e+1 charge Group 2A 2 outer shell egives 2 e+2 charge Group 3A Group 4A 3 outer shell e-*special group gives 3 ecan give, take +3 charge or share +/- 4 usually Carbon is -4 Group 5A Group 6A 5 outer shell e- 6 outer shell etakes 3 etakes 2 e-3 charge -2 charge Group 7A Group 8A 7 outer shell e- 8 outer shell etakes 1 e*already stable -1 charge 0 charge *Goal is to be stable by having 8 electrons (octet rule) Covalent Bonds •Formed when 2 atoms share electrons •You complete me! •Only between NONMETALS Particles formed by covalent bonds are called molecules (ex: O2 & H2O) Polar molecules have a separated + area & a - area b/c the e- are not shared equally! *most common covalent bond Ex: HCl, NH2 & WATER (H20) Nonpolar molecules have the same charge (+ or -) because the e- are shared equally! Ex: Cl2, CO2, O2 Ionic Diagrams 1.Identify each element as a metal or nonmetal 2.State if Ionic or Covalent 3.Draw the diagram for the formation of the compound Ionic Diagrams Need 4 things: •Equation •Dots •Arrows Your notes paper •Charges 1. Mg F2 Mg + F + F MgF2 Covalent Diagrams 1.Identify each element as a metal or nonmetal 2.State if Ionic or Covalent 3.Draw the diagram for the formation of the compound 4.If covalent, state if Polar or nonpolar Covalent Diagrams Need 2 things: •Dots Your notes paper •Circles 2. H F H F Ionic and Covalent Diagrams more examples My paper 1. LiCl 2. Cl2 Your paper 1. LiF 2. Cl2 Name I/C Diagrams STAR questions What type of bond would a metal and nonmetal be? Ionic What is the name of the particles formed by a covalent bond? Molecules What type of bond holds atoms of Au together? metallic Naming Binary Ionic Compounds Composed of 2 elements 1. Write the name of 1st element 2. Write the root of the 2nd element, changing the ending to –ide One Nonmetal and One Metal! ****(Name of cation, then anion) *See chart on page 171 Examples: MgO=Magnesium Oxide NaCl=Sodium Chloride Al2O3= Writing Formulas Binary Ionic Compounds 1. Write symbol for 1st element 2. Write symbol for 2nd element 3. Find the oxidation # (charge) for each element 4. drop n’ swap the oxidation # (drop=w/out the + or - ) (swap=give the # to the other element) 5. Reduce if possible Examples: Lead Oxide 1. Pb 2. O 3. Pb +/-4 and O -2 4. Pb2O4 5. PbO2 Aluminum Sulfide = Al S Al=+3, S=-2 , drop charges & swap #s Al2S3 Lithium Fluoride Calcium Oxide Molecular Binary # of atoms Greek Prefix 1 MonoCovalent Compounds The name & formula of a molecular compound describes the type & # of atoms in a molecule of the compound 2 3 4 5 6 7 8 9 10 DiTriTetraPentaHexaHeptaOctaNonaDeca- Naming molecular compounds ex: 1. N2O4 dinitrogen tetraoxide 2. CO2 carbon dioxide Writing Molecular Formula ex: 1. Diphosporous tetraflouride P2F4 2. Carbon dioxide CO2 More Binary and Molecular compounds examples 1. P2F4 2. Li2S 3. MgF2 4. Carbon Dioxide 5. Aluminum Oxide 6. Calcium Bromide STAR questions Another word for oxidation # is? Charge What is the difference between an Anion and a Cation? An Anion w/ a negative charge, a Cation is an ion w/ a positive charge How many elements are in Binary compounds? 2 Naming Polyatomic Compounds Polyatomic ion-positive or negative group of atoms 1. Write name of first element 2. Write name of the polyatomic ion Examples: CaCO3 = Calcium Carbonate Mg(ClO3)2 Writing Formulas Polyatomic Compounds 1. Write symbol of first element 2. Write symbol of polyatomic ion 3. Find the oxidation #’s 4. drop n’ swap! Use parenthesis around the polyatomic ion if crossing more than one! 5. Reduce if possible Examples: Lithium Sulfate 1. 2. 3. 4. Li SO4 Li +1, SO4 -2 Li2(SO4) Magnesium Nitrate Ammonium Bromide STAR questions Another word for oxidation # is? Charge What does a subscript tell me? The #s of atoms of each element What does the superscript tell me? The charge for the elements or compound What type of elements are Molecular compounds? Covalent (nonmetals) binary (2 elements)