Unit #2 Intro to Chemistry, Branches of Chemistry, Scientific Method, & Matter. AlchemyAncient practice in which the "scientist" attempted to turn common metals into gold. WE KNOW THIS IS IMPOSSIBLE, but they did not. However, they did help science in that they discovered chemicals, designed lab equipment, and even "discovered" how to separate mixtures by distillation and sublimation. ChemistryThe study of the composition of substances and the changes they undergo. Antoine Lavoiser"Father" of modern chemistry. He made and recorded changes of mass during chemical reactions. Chemistry is all around us. You live with it and its products on a daily basis. Can you think of any examples? Synthetic fibers - Nylon, Rayon, Spandex, Polyester… Clothing dyes Hair coloring Nail polish remover Soaps Calculators, iPods, Cell phones… Crude oil and its derivatives. Many others… Major Branches (types) of Chemistry Organic ChemistryThe study of essentially all substances containing carbon; deals with the "SPONCH" elements. SPONCH- an acronym made of the element symbols of: Sulfur, Phosphorus, Oxygen, Nitrogen, Carbon, & Hydrogen. Often used by: Chemical engineers (creators of tire compounds, insecticides, synthetic lubricants…), Lab technicians, Medicine inventors… Organic Chemistry (con’t) Examples: Synthetic fibers Non-stick cooking surfaces (Teflon) Tires… Physical ChemistryThe study of chemicals and the changes in energy as they undergo reactions and processes. Examples: Balloons Automobile engineers Explosive designers Energy = 1. work, 2. heat, 3. entropy (vibration and wasted energy (disorder)). Inorganic ChemistryThe study of substances without carbon; mainly from non-living things. Examples: Minerals Gemology Metal manufacturing Alloys Generally anything not “SPONCH” Analytical ChemistryConcerned with the composition of substances. There are two types: Qualitative and Quantitative. Examples: Soil testing Water testing Blood analysis. Qualitative Analytical Chemistry Determines if a substance is present by testing for its characteristic reactions with certain substances. Examples: Test for Lead paint Tests for “banned” substances Indicates only the presence of something Quantitative Analytical Chemistry Determines how much of a substance is present; its quantity; ("Percent composition"). Examples: Blood Alcohol Test Testing for Sugar in diabetic blood Testing for pH in swimming pools BiochemistryThe study of the chemistry of living things and their processes. Examples: Photosynthesis Respiration Marine biology Digestion WMD (Biological or chemical weapons) Some other Natural Sciences that involve Chemistry: 1) Geology: The study of the earth. Examples: Petroleum, distillation of crude oil, mining and how much sulfur may be in the coal. Some other Natural Sciences that involve Chemistry (con’t): 2) Biology: The study of the life. Examples: How body processes function, detoxification of poisons (including medicines), respiration, and photosynthesis. Some other Natural Sciences that involve Chemistry (con’t): 3) Physics: The study of energy and forces. Examples: Electronics, circuit boards, computer chips, diodes… Two types of Chemistry 1) Pure Chemistry 2) Applied Chemistry Pure ChemistryKnowledge is accumulated for its own sake; neither good nor bad. Examples: Chemical reactions, how much, what is it, color?, texture… Applied ChemistryKnowledge is either used to benefit or harm people or the environment. Examples: Medicine, chemical warfare, cloning. The Scientific Method A series of steps used to solve problems. 5 steps of the Scientific Method: 1) Observe the problem. “What’s wrong?” 5 steps of the Scientific Method (con’t): 2) Hypothesize the reason. Ask questions to find out why there is a problem. 5 steps of the Scientific Method (con’t): 3) Experiment To test your hypothesis. 5 steps of the Scientific Method (con’t): 4) Analyze Did the experiment prove your hypothesis correct? If not… go back to the hypothesis step. 5 steps of the Scientific Method (con’t): 5) Conclude / Theorize Conclude why the problem occurred. Theory vs. Law TheoryA thoroughly tested explanation of why experiments give certain results. LawA concise statement that summarizes the results of a broad spectrum of observations and experiments. What is the difference between a theory and a law? A theory explains why experiments give results. A law describes the results of observations. Matter Matter Anything that takes up space and has a mass. Mass Amount of matter in an object. Weight Effect of gravity on matter. What is the difference between mass and weight? Assume a jar of peanut butter weighs 600 g. (1.32 pound) on earth. The moon's gravity is 1/6th that of the earth's; therefore the same jar would weigh only 100 g. (0.22 pound) on the moon. That is weight. However, did the mass change ? (Assume it was never opened.) No. That is mass (the amount of matter). All matter belongs to one of two groups of matter: 1) Heterogeneous matter 2) Homogeneous matter Heterogeneous matterMatter that is different or not uniform in composition; each type of substance retains its own unique properties, and each can be separated from the other by ordinary chemical means. These are all mixtures. Examples of Heterogeneous Matter: M&Ms Tossed salad Lucky Charms Jell-O fruit salad… Homogeneous matterMatter that is uniform in composition. Examples of Homogeneous Matter: Oxygen Water salt water kool-aid Aluminum Iron Carbon dioxide tomato soup Juice These may be either mixtures (specifically solutions) or pure substances. Mixtures A general type of matter that may be either heterogeneous or homogeneous. (They are a physical blend of two or more substances.) All homogeneous matter belongs to one of two groups: 1) 2) Pure substances Solutions Pure substancesA particular kind of matter with a definite and uniform composition. Examples: Water CO2 Oxygen Lead Americium SolutionsHomogeneous mixtures. Examples: Salt water Orange juice… Solutions have phases that are either solid, liquid, gas, or a combination of the three. They are always listed with the lesser constituent first. All solutions are a mixture of the solute and solvent. Solute- The substance that is dissolved. It is the lesser constituent by volume. Example: The “Salt” in saltwater. SolventThe substance that does the dissolving. It is the greater constituent by volume. Example: The water in saltwater. There are 6 types of solutions based on the phases of their components. Remember: The components are always listed with the solute first, followed by the solvent. 1) Gas - Gas Examples: Oxygen in the air. Recall the composition of “Air” 75% Nitrogen 20% Oxygen 4% Carbon dioxide 1% Argon and all others. 100% Air 2) Liquid - Gas Examples: Water vapor in the air. 3) Gas - Liquid Examples: Carbon dioxide in water. 4) Liquid - Liquid Examples: “2 - Stroke Fuel” (Oil in Gas). 5) Solid - Liquid Examples: Sugar / flavoring in water (“Kool-aid”) 6) Solid - Solid Examples: Alloys: 1. (Copper in Silver, “Sterling Silver”) 2. A homogeneous solution has only one phase (“Kool-aid”), while a heterogeneous solution has 2 or more phases. (Vinegar & Oil). All pure substances belong to one of two groups: 1) Elements 2) Compounds Elements A substance that cannot be decomposed by ordinary physical or chemical means, under normal laboratory conditions. Each has its own unique and identifiable characteristics. Examples: Anything on the periodic table. Compound A chemical combination of elements. Each has its own unique and identifiable characteristics. Cannot be separated by physical means. Can be separated by chemical means. Examples: NaCl, H20, CO2 There are two main groups of elements: 1) 2) Metals Non-metals MetalsElements that are usually solid / liquid at room temperature, good conductors of heat and electricity, malleable, ductile, often shiny (luster). Examples: Magnesium Sodium Iron Non-metals Elements that may be either solid, liquid, or gaseous, poor conductors of heat and electricity, brittle, and often dull. Examples: Argon Sulfur Iodine Two specific types of non-metals are: 1) Metalloids 2) Gases MetalloidsNon-metals with some metal like properties. Often used in electronics. Examples: Silicon Arsenic Boron Gases Elements that are "gases". They are matter with no definite shape or volume, are fluid (they "flow"). Examples: Oxygen Helium Radon Compound Remember- A compound is a chemical combination of elements. Each with its own unique and identifiable characteristics. They cannot be separated by physical means, but can be separated by chemical means. Another example: Na is explosive when wet Cl2 is a poisonous gas. When combined, they produce the compound known as Sodium chloride ("table salt”). Law of Definite CompositionAll compounds have a definite composition by mass. Example: Water has a mass of 18g. / mole. Of those 18 grams, 11.1% are always from the Hydrogen. The remaining 88.9% are from the Oxygen. Matter Homogeneous Heterogeneous Solutions Compounds Mixtures Metals Pure substances Elements Non-metals Others Physical propertyA quality or condition of a substance that can be observed or measured without changing its composition. The value does not change with the amount of substance. Examples: 1) 2) 3) 4) 5) 6) 7) 8) 9) Density Boiling / Condensation point Melting / Freezing point Color State Odor Texture Solubility Hardness Chemical propertyThe ability of a substance to undergo a chemical reaction (a change) and form a new substance with new, unique properties. Physical changeAltering a substance without changing its composition, physical or chemical properties. Examples: Grinding Melting / Freezing / Boiling Chopping… Chemical changeAlters a substance by changing its composition. Examples: Combustion of hydrogen to produce water Oxidation of iron to make "rust" Decomposition of carbonic acid to make water and CO2. The States of Matter. Identify each drawing below as either a gas, liquid, or a solid Solid Liquid Gas SolidMatter with a definite shape and volume. (Low energy and entropy). LiquidMatter without a definite shape, has a definite volume, "flows", takes the shape of the container as it fills it from the bottom up. ("Moderate" energy & entropy). GasMatter without a definite shape or volume. (High energy & entropy). FluidAny matter that flows. Includes both liquids and gases. LiquidMatter without a definite shape, but with a definite volume. Does not include gases. Fluid Liquid VaporDescribes a substance that although it is in a gaseous state (like a gas), is either a liquid or a solid at room temperature. Examples: Steam Gasoline vapor in an internal combustion engine. Sodium vapor in street lights Xenon vapor in HID headlamps, GasMatter without a definite shape or volume. (High energy & entropy). Examples: Oxygen Helium Radon Gas Vapor Processes in nature are driven two ways: 1) Toward lowest energy. 2) Toward greatest entropy. Entropy - The amount of disorder in a system. Ga s Condensat ion Decreasing Entropy & Energy Cooling Liquid Evaporating Freezing Melting Solid Increasing Entropy & Energy Warming