Chapter 12 Section 12.2 part 1

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Chapter 12: Chemical Quantities

Section 12.2: Using Moles

Balanced chemical equations

• Used to relate moles of one substance to moles of another substance

• Use coefficients in the equation to convert to moles of other reactants or products

The following recipe serves 4:

4 potatoes (.3 lb each)

2 onions (.2 lb each)

8 carrots (.1 lb each)

4 stalks of celery (.05 lb each)

1.4 lbs of water

What is the total mass of the soup?

How would you make enough for 8?

How about 1240?

**With a balanced chemical equation and number of moles, we can predict the exact amount of reactant and product in a reaction**

There are 4 steps to follow:

1) Write the balanced chemical equation

2) Convert the given mass or volume to moles

3) Use the coefficients in the chemical equation to set up a mole ratio (the coefficients are the # of moles!)

HINT: The substance you are solving for goes on TOP

4) Convert these moles back to mass or volume as required

Steps

Use:

Grams A ↔ Moles A ↔ Moles B ↔ Grams B molar mass coefficients molar mass

N

2

+ 3H

2

 2NH

3

• This reaction can be stated as: 1 mole of nitrogen will react with 3 moles of hydrogen to produce 2 moles of ammonia.

Practice Problems (pg. 415)

#10) What mass of CO

2 forms when 95.6 g of C

3

H

8

C

3

H

8

(g) + 5O

2

(g) → 3CO

2

(g) + 4H

2

O(g) burns?

3 C = 36.033 g C= 12.011g

8 H= 8.064 g

C

3

H

8

2 O = 32 g

= 44.097 g/mol CO

2

= 44.011 g/mol

95.6 g C

3

H

8 x 1 mol C

3

H

8 x 3 mol CO

44.097g C

3

H

8

1 mol C

3

H

2

8 x 44.011 g CO

2

=

1 mol CO

2

= 286.2 g CO

2

Practice (cont)

#11) How many grams of fluorine are required to produce 10 g

XeF

6

?

Xe (g) + 3F

2

(g) → Xe F

6

(s)

F

2

: 2 x 18.998 g = 37.996 g

Xe F

6

: 131.29 + (6 x 18.998) = 245.278 g

10 g XeF

6 x 1 mol XeF

6

245.278 g XeF

6 x 3 mol F

2 x 37.996 g F

2

=

1 mol XeF

6

1 mol F

2

= 4.65 g F

2

LIMITING REACTANT

The reactant that runs out first in a reaction/ stops the reaction

Practice Problems

#1) What is the limiting reactant in producing water (H

H

2 or 5 g of O

2

2

? (convert g reactant → mol of product)

O), 5 g

2H

2

+ O

2

→ 2H

2

O

5 g H

2 x 1 mol H

2

2.0158 g H

2 x 2 mol H

2

O = 2.48 mol H

2

O

2 mol H

2

5 g O

2 x 1 mol O2 x 2 mol H2O = 0.31 mol H

2

O

31.998 g O2 1mol O

2

Limiting reactant is O

2

(runs out first)

Practice (cont)

2) Which is the limiting reactant in producing NH

3 g N

2 or 3.75 g H

2

?

, 3.75

N

2

+ 3H

2

→ 2 NH

3

3.75g H

2 x 1 mol H

2

2.0158 g H

2 x 2 mol NH

3

3 mol H

2

= 1.24 mol NH

3

3.75g N

2 x 1 mol N

2

28 g N

2 x 2 mol NH

3

1 mol N

2

= 0.27 mol NH

3

Limiting reactant is N

2

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