Mole Triangle Review Begin Stoichiometry Chemistry GT 3/5/15 Drill • How many moles are equivalent to: – 450. g Ca(OH)2 – 935.2 g zinc chloride • HW: Mole-Mole/Mass-Mass WS (finish) Objectives • IWBAT – Convert from moles to grams and back – Convert from moles to units and back – Convert from moles to liters and back – Use the mole triangle to do two step conversions Mole Triangle • We can convert between – Mol g and back – mol particle and back – mol L and back • Ms. Bloedorn will show you how! The study of quantitative relationships between amounts of reactants used and products formed by a chemical reaction What’s going on here? • The candle burns freely in air, but what happens when it is covered with a beaker? – smothered, goes out • What fuel runs out first? – oxygen runs out Mole Chemical Relationships • Mole-Mass Relationships in Chemical Reactions: – Law of Conservation of Mass: • Mass cannot be created or destroyed by ordinary chemical changes – Look at: • Fe(s) + O2(g) Fe2O3(s) • Is it balanced? If not, balance it. • 4 Fe(s) + 3 O2(g) 2 Fe2O3(s) Interpret the equation • Iron + oxygen Iron (III) oxide • 4Fe(s) + 3O2(g) 2Fe2O3(s) • 4 atoms Fe + 3 molecules O2 2 molecules Fe2O3 • 4 mol Fe + 3 mol O2 2 mol Fe2O3 • 223.4 g Fe + 96.00 g O2 319.4 g Fe2O3 • These all tell you different information, but also represent the same reaction. Stoichiometric Calculations • • • • • • • • • 1/2 cup butter 1/2 cup brown sugar 1/2 cup granulated sugar 1 egg 1/2 teaspoon vanilla 1 cup all-purpose flour 1/2 teaspoon salt 1/2 teaspoon baking soda 1/2 cup semisweet chocolate chips • Makes 42 cookies. • What is the product of this chemical reaction? – 42 cookies • How would you adjust the ingredients to make seven dozen cookies? – Make twice as much (7 x 6, then 7 x 12) The Mole “Bridge” moles of B moles of A Moles of A Moles of B 1 mol A # grams B # grams A 1 mol B Grams of A Grams of B *** You MUST have a balanced equation! *** Stoichiometry Conversion Flowchart wA + xB yC + zD Liters B Liters A 22.4L A mol A 6.022 x 10231units 1 mol A Atoms/ mol A units A 1 mol A 6.022 x 1023 units A 1 mol A Molar mass A grams A 22.4L B 1 mol A 1 mol B 22.4L Aw mol A 1 mol B 22.4L B 1 mol B 6.022 x 1023 units B x mol B mol B x mol B mol B w mol1 A Molar mass B Molar mass g A 1 mol A grams B Atoms/ units B 6.022 x 1023 units B Molar mass g B 1 mol B 1 mol B Stoich. Calculations, cont. • Sometimes, a chemist needs to make a certain amount of a product, or only has a certain amount of a starting material. How much reactant should be used? How much product will be made? • ex. How many moles of hydrogen will be produced when 0.0400 mol potassium react with water? • 2K(s) + 2H2O(l) 2KOH(aq) + H2(g) – 0.0400 mol K • 1 mol H2 = 0.0200 mol H2 2 mol K Mass to Mass Conversion • Ammonium nitrate (NH4NO3) decomposes into N2O and water. Determine the mass of water produced from the decomposition of 25.0 g solid ammonium nitrate. • NH4NO3 N2O + 2H2O 25.0 g NH4NO3 • 1 mol NH4NO3 • 2 mol H2O • 18.02 g H2O = 11.3 g H2O 80.04 g NH4NO3 1 mol NH4NO3 1 mol H2O Practice • Start on Mole-Mole side of WS • Then, Mass-Mass side of WS Closure • Calculate, in 2.3 mol Na3PO4, – How many grams?