Monday and Tuesday March 26 and 27 Lewis Dot Structures Review? 1.What is a valence electron? 2.What is the lewis dot structure of: a) Lithium b) Bromine Do your best to answer on your own. Valence Electrons The valence electrons are the electrons in the last shell or energy level of an atom. Why are they important? -BONDING! Valence Electrons How many for each element? www.chemprofessor.com/ptable5.gif Lewis Dot Structures What is the lewis dot structure of: a) Lithium b) Bromine Lewis Dot Structures Draw Draw the the lewis lewis dot dot structure structure of offor calcium oxygen gas: chloride: methane lithium (CH bromide: 4): Identify the lone pairs and bonding pairs! **NO LONELY ELECTRONS!! Chemical Bonding Types of Bonds, Polarity, and Dipoles What is electronegativity? The ability of an element to steal an electron from another element What are BONDS? • The attraction between atoms • Causes shape and structure of chemicals Types of Bonds • Non-polar (Covalent) 0.0 • Polar (Covalent) 0.1 to 1.9 • Ionic 2.0 or higher Nonpolar Covalent Bond Electronegativity Difference of 0.0 Electrons are shared equally Polar Covalent Bond Electronegativity Difference of 0.1 – 1.6 Electrons are shared, however, they favor one side of the molecule. Copyright © 2006 by the Regents of the University of California. Copyright © 2006 by the Regents of the University of California. Two types of Covalent Bonds NONPOLAR POLAR Ionic Bond Electronegativity Difference of 1.7 or higher Electrons are transferred to the other element. Types of Bonds • Non-polar (Covalent) 0.0 • Polar (Covalent) 0.1 to 1.9 • Ionic 2.0 or higher Practice Draw the lewis dot structure for the formulas below and identify the bond type: Potassium Bromide Carbon Disulfide Nitrogen Trifluoride Wednesday 3/28 and Thursday 3/29 Modeling Lab Friday 3/30 How are molecular shapes determined? VSEPR Lewis Structures & VSEPR Valence Shell Electron Pair Repulsion electron pairs spread apart as far as possible Electron Pair Geometry: Linear Molecular Geometry: Linear Number of Lone Pairs: 0 Number of Bonds: 2 Angle: 180̊ Electron Pair Geometry: Trigonal Planar Molecular Geometry: Trigonal Planar Number of Lone Pairs: 0 Number of Bonds: 3 Angle: 120̊ Electron Pair Geometry: Trigonal Planar Molecular Geometry: Bent Number of Lone Pairs: 1 Number of Bonds: 2 Angle: 117̊ Electron Pair Geometry: Tetrahedral Molecular Geometry: Tetrahedral Number of Lone Pairs: 0 Number of Bonds: 4 Angle: 109.5̊ Number of Lone Pairs: 1 Number of Bonds: 3 Electron Pair Geometry: Tetrahedral Molecular Geometry: Trigonal Pyramidal Angle: ~107̊ Electron Pair Geometry: Tetrahedral Molecular Geometry: Bent Number of Lone Pairs: 2 Number of Bonds: 2 Angle: 104.5̊ Questions on shape? Dipoles Contains a positive end and a negative end. Copyright © 2006 by the Regents of the University of California. Copyright © 2006 by the Regents of the University of California. Copyright © 2006 by the Regents of the University of California. Copyright © 2006 by the Regents of the University of California. Practice CO2 NH3 BF3 Li2O