Unit: Nuclear Chemistry Fission, Fusion, and Applications of Nuclear Chemistry After today you will be able to… • Describe what happens in a nuclear chain reaction. • Differentiate between fission and fusion reactions. • Identify examples of how radioisotopes are used in everyday life. Recall, during transmutations an atom can be converted into a different atom through radioactive decay or by bombarding a nucleus with particles. Today, we will focus on the latter by learning about fission and fusion. Nuclear Fission Fission: occurs when a nucleus is split into smaller pieces. • This process begins by colliding a nucleus with particles such as neutrons. • The resulting nucleus is highly unstable and decays. • This causes a chain reaction where particles emitted from the initial reaction bombard other nuclei, causing them to break apart. Example: Uranium-235 1 0 n 235 The neutrons released U 92 from the decay of U-236 will collide with other Kr n 236 U-235 atoms, repeating ENERG 92 U n Y this process all over n again (chain reaction). Ba 91 36 1 0 1 0 142 56 1 0 Nuclear Fission • Uranium-235 and Plutonium-239 are the only fissionable isotopes. • These reactions release a large amount of energy. Nuclear Fusion Fusion: occurs when nuclei combine (or fuse together) to produce a new nucleus of greater mass. • Example: Production of energy from the sun 1 1 4 H 4 2 He + 2 e + 0 +1 energy Nuclear Fusion • Releases far more energy than fission reactions. • These reactions require very high temperatures in order to occur (~40,000,000°C). Real-World Applications: C-14 Dating Scientists often find the age of an object that was once living by measuring the amount of carbon-14 it contains. • Recall, C-14 has a half-life of 5730 years. • This is its nuclear decay: 14 6 C 14 7 0 -1 N + e Real-World Applications: C-14 Dating • All living things contain C-12 and C-14 in a fixed ratio. • Once an organism dies, the ratio of C-14:C-12 changes, which allows archeologists to estimate its age. Real-World Applications: C-14 Dating • The most accurate way to examine the C-14 content is through use of a mass spectrometer. • First, the carbon in the sample must be converted into graphite or carbon dioxide. ―This is can be done by burning a portion of the sample. Real-World Applications: C-14 Dating • The sample is then injected into a mass spectrometer and ionized. • Due to the different masses of carbon having different angles of deflection, a scientist can count the individual C-14 atoms in the sample. Mass Spectrometer: Real-World Applications: U-238 But what if all of the C-14 in a sample has decayed or the sample is non-living? • Similar to carbon-14, uranium-238 is used to date specimens. • Uranium is naturally found in most rocks, seawater, and in Earth’s crust. • It has a half-life of 4.5 billion years. • U-238 is specifically used in dating rocks and fossils. Real-World Applications: I-131 Radioisotopes can be used to diagnose medical problems or treat diseases. • Specifically, iodine-131 is a radioisotope given to patients to check for abnormal thyroid function. • Patients are given a drink containing the radioisotope (Na131I). Real-World Applications: I-131 • Since the thyroid extracts iodide ions from the bloodstream, the ions are absorbed and its radioactivity is used to create an image on a screen. • From the image, doctors can examine the amount of iodine absorbed and determine if a person has hyperthyroidism or thyroiditis. Real-World Applications: Co-60 The strong penetrating power of gamma rays allows it to be useful in the treatment of cancer. • Cobalt-60, which is produced in particle accelerators, emits both beta and gamma radiation. Real-World Applications: Co-60 • The Co-60 is placed into a gun that is used to direct the radiation to where the tumor is located. • The cells of the tumor are destroyed and it decreases in size. • However, gamma radiation can also destroy healthy cells making those treated very ill. Questions? Begin WS4