Plasma Technology Opportunities for a Sustainable Future GTRI.ppt-1 Objective Present an initiative to produce sustainable energy from waste materials GTRI.ppt-2 Methodology • Use plasma arc technologies to destroy wastes (biomass, solid waste, hazardous materials) • Generate fuel gases including hydrogen and carbon monoxide • Use fuel cells to produce energy in the form of heat and electricity GTRI.ppt-3 What is PLASMA? 90 • “Fourth State” of matter • Ionized gas at high temperature capable of conducting electrical current • Lightning is an example from nature 80 70 60 50 East West North 40 30 20 10 0 1st Qtr 2nd Qtr 3rd Qtr 4th Qtr GTRI.ppt-4 Characteristics of Plasma Arc Technology • Plasma acts as a resistive heating element which • • • • cannot melt and fail Temperatures 4,000°C to over 7,000°C Torch power levels from 100kW to 200 MW produce high energy densities (up to 100 MW/m3) Torch operates with most gases-not a combustion process Elimination of requirement for combustion air – Reduces gas volume requiring treatment – Reduces potential for formation of complex organics (I.e., dioxins and furans) GTRI.ppt-5 Ideally suited for waste treatment • Hazardous & toxic compounds broken down to elemental constituents by high temperatures • Organic materials Pyrolyzed or volatilized May be converted to fuel gases Amenable to conventional off-gas treatment • Residual materials (radionuclides, heavy metals, etc.) immobilized in a rock-like vitrified mass which is highly resistant to leaching GTRI.ppt-6 Plasma torch in operation GTRI.ppt-7 Plasma Gasification of MSW Gas Heating Value Output = 4.30 Electricity Input Steam Negligible Gas Heat Energy 1.05 MBtu PLASMA MSW 1 Ton – 9.39 Mbtu 33% Moisture GASIFIER Electricity 0.56 MWHr – 1.90 MBtu Product Gas 30,300 SCF Heating Value = 8.16 MBTU Based on data from Resorption Canada, Ltd. 1995 (Summarized and converted to English units) GTRI.ppt-8 An Ultimate Solution to MSW? 376 tons/day MSW) Coke/Limestone Solid Residue: 50 tons/day Sell: Aggregate Metals Bricks Other Plasma Arc Torch 4.1 MW Fuel Gases: 3x107 Btu = 10.6 MW Net 6.5 MW GTRI.ppt-9 Experimental Results PRODUCT GAS DISTRIBUTION Compounds Test 1 ( with no moisture) Sample 2 (30 min) The gases measured were H2, O2, N2, CH4, and CO. Sample 3 (50 min) Test 2 ( with moisture) Sample 6 (110 min) Sample 3 (30 min) Sample 4 (50 min) CO 16.95% 18.56% 21.65% 17.42% 21.39% CO2 0.22% 0.24% 0.28% 0.44% 0.53% CH4 1.72% 2.94% 3.91% 2.06% 1.86% H2 8.36% 12.10% 18.31% 10.10% 16.31% H2O 0.16% 0.23% 0.35% 0.37% 0.60% N2 60.84% 54.74% 49.80% 47.59% 50.52% O2 7.17% 7.37% 5.42% 8.57% 8.64% C6H6 0.25% 0.25% 0.25% 0.13% 0.13% unidentified 4.33% 3.56% 0.03% 13.33% 0.02% 95.67% 96.44% 99.97% 86.67% 99.98% total •In addition to benzene, small amounts of methane and benzene and trace amounts of toluene, styrene, ethyl benzene, methyl-ethyl benzene, and benzonitrile were found in the DCM samples. •The high concentrations of O2 and N2 are due to air leaking into the system prior to the sample point. GTRI.ppt-10 Cobb County Plasma Arc Waste Processing System System Components GTRI.ppt-11 Next Steps • Assembly of the Cobb County Plasma Arc Waste Processing System • Optimization testing for integration with fuel cells • Testing of biomass, MSW and other feedstock • Hydrogen capture and optimization GTRI.ppt-12