Final Exam Review 2015 HONORS Chemistry Name ______________________________ For problems, you must show all work INCLUDING a formula, filling in the formula, the answer and unit for full credit. Unit 1: Math and Moles: There will be 20 questions on your final from this section. Define and give an example of each Word Define 1. Accuracy 2. Precision 3. Qualitative 4. Quantitative 5. Physical Properties 6. Extrinsic Properties 7. Intrinsic Properties 8. Chemical Properties 9. Chemical changes Example 10. Physical changes 11. Density 12. Mole 13. Molar mass 14. Molar Volume 15. Avogadro’s Number 16. Particles (in mole conversions) 17. Atom (in mole conversions) 18. Molecule (in mole conversions) 19. Formula Unit (in mole conversions) 20. Ion (in mole conversions) 21. Molecular Formula 22. Empirical Formula (word definition) Number = 23. List the metric conversions for your class. ( ___ m= ____ km; etc.) Convert the following: 24. 456 m to cm 25. 90.8 mm to m 26. 459 km to m 27. 0.158 um to Gm 28. List and define the parts of the scientific method. 29. Describe how to solve a density problem when you are given mass and volume and want density. 30. A box has a mass of 15.0 g and a volume of 45.0 mL. What is the density? 31. Describe how to solve a density problem when you want mass and are given density and volume. 32. A box has a density of 25.0 g/mL and a volume of 5.0 mL. What is the mass? 33. Describe how to solve a density problem when you want volume and are given mass and density. 34. A box has a density of 50.0 g/mL and a mass of 10.0 g. What is the volume? 35. Describe how to find the molar mass and what unit you would use. 36. Find the molar mass of: H2O, Zn3(PO4)2, C6H12O6 37. Describe how to find the % by mass given the formula. 38. Find the % by mass for each element in H2O, Zn3(PO4)2, C6H12O6 39. Describe how to convert from grams to moles. 40. Convert 16.0 g of helium to moles. 41. Convert 9.01 g of water to moles. 42. Describe how to convert from moles to grams. 43. Convert 5.6 moles of ZnCl2 to grams. 44. Convert .086 moles of lead (II) chloride to grams. 45. Describe how to convert from moles to particles. 46. Convert 1.5 moles of zinc acetate to particles (make sure to specify the particle!). 47. Convert 0.52 moles of carbon dioxide to particles. 48. Describe how to convert from particles to moles. 49. Convert 5 atoms of lithium to moles. 50. Convert 0.75 atoms of vanadium to moles. 51. Describe how to convert from moles to volume. 52. Convert 75 moles of helium to volume. 53. Convert 0.412 moles of hydrochloric acid (g) to volume. 54. Describe how to convert from volume to moles. 55. Convert 44.8 L of oxygen gas to moles 56. Convert 0.75 L iodine gas to moles 57. Describe how to convert from molar mass to molar volume. 58. Convert 100.0g hydrogen gas to liters. 59. Convert 0.89 g astatine gas to liters. 60. Describe how to convert from molar volume to molar mass. 61. Describe how to find empirical formula. 62. A compound is 94.1 % oxygen & the rest hydrogen. Find the empirical formula. 63. A compound if 53.0% aluminum & the rest oxygen. Find the empirical formula. 64. Describe how to find molecular formula. 65. A compound has a molar mass of 100. The mystery compound has the formula X 2Z4. If the empirical formula mass is found to be 20, what is the molecular formula? (The most important person in the room is …) 66. A compound has a molar mass of 150. The mystery compound has the formula X4Z6. If the empirical formula mass is found to be 50, what is the molecular formula? (The most important person in the room is …) Unit 2: Thermo There will be 10 questions on your final from this section. Define the following words and give an example of each. Word Definition 67. Endothermic 68. Exothermic 69. Phase Diagram 70. Heating Curve Example For each of the following phase changes, define it and tell if the process is endothermic or exothermic. Phase change Definition Endothermic or exothermic 71. Deposition 72. Fusion 73. Condensation 74. Sublimation 75. Solidification 76. Vaporization 77. Label 1-5 of the phase diagram. 78. At 0C and 8 atm, what is the phase of matter? 79. In a thermo-chemical equation, the heat is on the right in a 2 1 3 ___ reaction and the left in a ____ reaction. 5 80. In a thermo-chemical equation, the delta H is positive in a ___ reaction and negative in a ____ reaction. 4 81. 500 g of a metal is heated to 150C. When transferred to 200 g of water, the water T rises from 20C to 50C. Assume no heat is lost. The specific heat of water is 4.184 J/gC. Find the specific heat of the metal. 82. Draw graphs of endothermic reaction and an exothermic reaction. In each graph, label the both axis, products, reactants, & activation energy. 83. If the temperature of 600 g of ethanol (CH3CH2OH) decreases to 50 C from 150 C, how much energy was released? The specific heat of ethanol is 2.44 J/g C. 84. Find the specific heat of an object with a mass of 250g that had a decrease of 10 C when 150 J of energy was removed. 85. Describe in words what happens when you add a catalyst to a reaction. 86. Label the heating curve below. Make sure to label the axes, the states of matter, the phase changes, endo and exo thermic and the boiling point and freezing point of water. 87. Explain why the temperature doesn’t change during a phase change on a heating curve. 88. Calculate the heat required to change 75.0 g of ice at -15.8 C to steam at 145 C. (cwater=4.184 J/gC; cice = 2.06 J/gC; csteam= 2.06 J/gC; Hvap = 40.7kJ/mol; Hfus = 6.01 kJ/mol) 89. Find the H of the reaction below using: C(s) + O2(g) CO2 (g) H = -393.5 kJ H2 (g) + ½ O2 (g) H2O (l)H=-285.5kJ 2C2H2(g) + 5O2(g) 4CO2(g) + H2O(l) H = -2598.8 kJ Target: C2H2 (g) 2 C(s) + H2 (g) H = ? 90. How much heat is evolved when 50.6 g oxygen is burned according to this equation? C(s) + O2(g) CO2 (g) H = -393.5 kJ 91. Calculate the heat required to freeze 456.36 g of liquid ethanol (C 2H5OH) at its freezing point. ( Hvap = 38.6kJ/mol; Hfus = 4.94 kJ/mol) 92. If the T of 67.00 g of gold decreases from 150.0 to 70.0C, how much heat has been released? (specific heat of gold is 0.13 J/gC). 93. 46 g of metal is heated to 190C. When transferred to 50.0g H2O in a calorimeter, the water T raises from 25.6C to 35.3C. Assume no heat is lost. Find the specific heat of the metal. 94. Find the Hrxn for 2F2 (g) + 2H2O (l) 4HF (g) + O2 (g) Hrxn=? Given: F2(g) = 0kJ/mol; H2O (l)= -571.6 kJ/mol; HF(g)= -542.2kJ/mol; O2 (g)= 0kJ/mol 95. Find the Hrxn for 2F2 (g) + 2H2O (l) 4HF (g) + O2 (g) Hrxn=? Given:F2(g) = 0kJ/mol; H2O (l)= -571.6 kJ/mol; HF(g)= -542.2kJ/mol; O2 (g)= 0kJ/mol 96. Write the thermochemical equation using the following information: H2O2(l) →2H2(g)+ O2(g) Hrxn = +188 kJ/mol Is this an exothermic or endothermic equation? How do you know? 97. What is the specific heat of a metal with a temperature of a 50.0g sample is increased by 15.0 oC when 45.8 J of heat is added? Unit 3: Nomenclature & Bonding There will be 10 questions on your final from this section. Word Define 98. Ionic Bond 99. Ion 100. Anion 101. Cation 102. Covalent Bond 103. Polar 104. Nonpolar 105. Metallic 106. Write the rules for writing and naming ionic compounds 107. Write the rules for writing and naming covalent compounds 108. Write the rules for writing and naming acidic compounds 109. Name the Following 110. Write formulas for the following: 111. sodium fluoride 112. aluminum trichloride 113. carbon dioxide 114. silver sulfate 115. nitrogen dioxide 116. lithium sulfide 117. dinitrogen trisulfide 118. Nitric acid 119. Phosphorous acid 120. Calcium phosphide Example 121. Sulfuric acid Name the following compounds and molecules. 122. PbCl4 123. P4I7 124. AgCl 125. N6O10 126. H3PO4 127. CaS 128. (NH4)2SO3 129. Al2(CO3)3 130. HCl 131. KClO4 132. Si4Cl10 Unit 4 Reactions: There will be 10 questions on your final from this section. Define the following and given an example: Word Definition Generic Example: Example A + B AB 133. Reactant X 134. Product X 135. Yield X 136. Synthesis 137. Single Replacement 138. Decomposition 139. Double displacement 140. Combustion 141. Redox reaction 142. Oxidized 143. Reduced 144. Oxidizing agent 145. Reducing agent 146. Using a balanced chemical equation, how can you tell what the state of matter is? How do you show solid, liquid, gas & aqueous in a balanced chemical equation? Give an example of each. 147. List the seven indicators of a chemical reaction. 148. List and give formulas of 7 Diatomic Elements 149. Balance the following equations and give the type of reaction. 150. ____________________ Sn + P Sn3P2 151. ____________________ AgNO3 + Zn Zn (NO3)2 + Ag 152. ____________________ H2CO3 153. ____________________ C2H6 + H2O 154. ____________________ Na + 155. ____________________ MnCl 2 + CO2 + H2O O2 CO2 + NaOH + H2 AgNO3 Mn(NO3)2 156. ______________________ CaCO3 + HCl 157. _____________________ C4H10 + O2 CaCl2 H2O + + AgCl H2CO3 CO2 + H2O Predict the products, write and balance the following equations. Give the type of reaction. 158. Sodium + chlorine gas 159. Aluminum oxide decomposes 160. copper + nickel (III) nitrite 161. silver nitrate + potassium acetate 162. Combustion of C2H6O 163. Which of the questions 150-162 are redox? Identify what is being oxidized, reduced, the oxidizing agent and the reducing agent. 164. Assign oxidation numbers a. KCl b. Ca(ClO4)2 Unit 5 Stoichiometry – there will only be 6 questions from this section because we have not completed this unit 165. Write the balanced chemical equation for the production of water from its elements. Use this equation for the remaining questions. 166. How many moles of hydrogen are needed to completely react 4.5 moles of oxygen gas? 167. How many grams of water are produced when 3.0 moles of hydrogen gas completely react with excess oxygen? 168. How many moles of water are produced when 95 g of oxygen gas react completely? 169. How many grams of oxygen are needed to completely react with 800. g of hydrogen gas? 170. What volume of hydrogen gas is needed to produce 450 g of water?