Post-Lab Notes: Chemical vs. Physical Changes Station Event 1 Observe water boiling in a beaker on a hot plate. Boiling points: Distilled water: 100° C Tap water: 102° C Salt water: 106 ° C 2 3 4 Add 50 mL of acetic acid solution (vinegar) to 5 g sodium bicarbonate (baking soda) in a 500-mL Erlenmeyer Flask. Light a wood splint and lower it into the bottle. Wax + Heat Find the mass of the test tube and wax. Melt wax in a test tube over a flame. Mass again. Read about the Law of Conservation of Mass Observe NaCl under magnification. Add 0.5 g table salt (NaCl) to 300 mL of water. Stir. Repeat with sucrose (C12H22O11) Observations/Inferences/ Explanations Observations: bubbles form in the water as liquid water turns to steam. Inferences: Molecules of water are gaining KE, therefore moving faster. As the liquid water vaporizes, the volume increases. (Charles’ Law) Explanations: A change in the state of matter is occurring; temperature is a measure of the average kinetic energy of the particles of a substance; this is a demonstration of the increase of average KE of the particles; kinetic theory of matter. Boiling Point Elevation: Adding substances to water raises the boiling point, so tap water and salt water have more dissolved substances than distilled water, and this raises the boiling point. Chemical or Physical? Why? Physical Change Observations: bubbles formed; the flame goes out when lowered into the flask Chemical change Inferences: A gas is produced; the gas is not oxygen -the gas does not support combustion A new substance is formed that does not burn Explanations: A new substance is formed (CO2 gas); Oxygen is required for a flame to burn; the gas produced is NOT oxygen Observations: The wax melts. When it cools, it is still wax; The mass before melting = mass after melting Inferences: Particle motion increases with the increase in temperature. Explanations: The identity of the wax did not change. Melting is a physical process Law of Conservation of Mass applies to both chemical and physical changes. (mass before = mass after the process) Observations: Sodium chloride: white, translucent, box-shaped crystals (when magnified) the salt does not immediately dissolve, but will dissolve after agitation. Salt + water can form a solution. Sucrose – the crystals were not as regularly-shaped as the sodium chloride crystals were. Sugar dissolved quickly in the water. solubility Give examples of types of solutions The ability of one substance to dissolve in another, or solubility, is affected by temperature, agitation, & the nature of the substances being dissolved Salt water, sugar and water both form solutions Inferences: salt and water can form a solution; the particles are too small to be filtered out Explanations: A mixture can be separated through physical means. Salt DOES NOT separate from water through filtration. In a solution, the particles are dissolved. To separate this mixture, it must be evaporated, or distilled through vaporization at the boiling point Change in the state of matter does not change the identity of water; it is still H2O, just in the form of water vapor Physical Change Wax is the same identity Physical The substances do not lose their identities; they can be separated through physical means (distillation or evaporation). 5 6 7 8 Define: solution solute solvent Add 1-2 drops of 0.1M AgNO3 to 1-2 drops of FeCl3 in a test tube. Mossy Zinc + hydrochloric acid Zn + HCl Light a wood splint. Let it burn for a few seconds. Lower the glowing splint into the bottle. Observations: Each compound was initially clear ( 2 solutions); AgNO3 was clear and colorless; FeCl3 was clear and yellow; when mixed, a light yellow cloudy substance formed (change in color and clarity); if you look closely, you can see little white particles in the liquid Inferences: a new substance was formed Explanations: the new substance is a precipitate (an insoluble solid compound that forms when solutions of certain ionic compounds in solution react). Balanced Equation: 3AgNO3 (aq)+ FeCl3 (aq) 3AgCl(s) + Fe(NO3) 3 (aq) Observations: zinc is grey and dull; HCl is clear and colorless; bubbles form; the test tube felt hot (exothermic reaction – gives off heat); a lit splint will ignite and “bark” inside the test tube Inferences: a gas is produced that is combustible copper__________ zinc____________ iron____________ aluminum_______ lead____________ Explanations: hydrogen gas is formed and is highly reactive Zn (s) + 2HCl (aq) ZnCl 2 (aq) + H2 Observations: The H2O2 is clear and colorless; the KI is a white powdery compound; when mixed, it turns orange, bubbles are formed, a glowing splint is ignited. The reaction produces heat (exothermic) If the flask is stoppered, pressure increases as the gas is produced, and the stopper will eventually pop off – be careful! Inferences: a gas is produced that supports combustion= oxygen gas Explanations: The reaction has multiple steps; oxygen gas is formed in one of the steps Pure Substances: (include observations) Elements: reddish-gold metallic, small pellets; grey; dull; metallic, irregular shape_______________ dark brown, magnetic, “iron filings”____________ silvery grey, light metal,_low density_____ cube, soft (irregular shape), grey, heavy metal, dense, cube _sodium chloride, NaCl _sucrose, C12H22O11____ _ CaCO3_____________ Compounds: _solid, white, granular, small cubes______________ _solid, white, granular, less regularly-shaped than NaCl_ _solid, white powder________________________ 100 mL Hydrogen Peroxide and ½ tsp. Potassium Iodide in a 250mL Erlenmeyer flask. Light a wood splint. Let it burn for a few seconds. Lower the glowing splint into the bottle. Classifying Matter (list names of samples) sodium carbonate solution (NaCO3 dissolved in water) brass_________________ steel_________________ _beans________________ _clay________________ _rocks & minerals_____ Homogeneous Mixtures: _clear, colorless, “poison”_(aqueous solution)_________ _gold-colored; alloy – a solid mixture of copper and zinc _grey, silvery metal with rust; made of iron, carbon, small % of other metals elements_________________________ Heterogeneous Mixtures: _multi-colored ______________________________ _red, soft, moldable, particles are visible___________ _various colors, textures________________________ Chemical A new substance was formed Chemical A new substance was formed Chemical A new substance was formed that supports combustion Explanations: Pure substances cannot be broken down by physical means.