CHAPTER 2 • THE CHEMICAL FOUNDATIONS OF LIFE • Alchemy and Chemistry WHAT IS MATTER? • • • • • • • CHEMISTRY MATTER CHEMICAL REACTIONS ATOMS NUCLEAR REACTIONS MOLECULE COMPOUNDS What Is Chemistry? metallurgy WHAT DETERMINES THE PROPERTIES OF AN ATOM? MASS What Are Atoms Made Of? Calculate molecular weight. What Is the Internal Structure of an Atom? • • • • NUCLEUS PROTONS NEUTRONS ELECTRONS ISOTOPES • RADIOACTIVE ISOTOPES • HALF-LIFE What Does Radioactivity Do to Living Organisms? free radicals Where Are the Electrons in an Atom? • ENERGY • SHELLS • TWO RULES ON DISTRIBUTION • PRACTICE DRAWING COMMON ELEMENTS WHAT HOLDS MOLECULES TOGETHER? • • • • • Eight electrons to an energy level 1,2, or 3 electrons may be given up 4 electrons will usually be shared 5,6, or 7 electrons may gain more Inert elements have 8 electrons and are unreactive Covalent and ionic Bonds Are the Strong Interactions Among Atoms covalent bonds ionic bonds ions Atoms Share Electrons in Covalent Bonds • • • • SPONCH Organic compounds contain carbon Double covalent bonds Triple covalent bonds What Determines the Shape of a Molecule? Bonds give a 3-D structure. Fig. 2-8 How are radioisotopes useful? Give examples. Atoms Lose and Gain Electrons in Ionic Bonds Ions have a gain or loss of electrons to form + or - charges. Opposite charges attract. Fig. 2-9 Atoms Have Different Tendencies To Gain or Lose Electrons • polar- has uneven charge • Electronegativitity the tendency to gain electrons distribution • nonpolar-has uniform charge distribution Weak Interactions Also Hold Atoms Together aqueous (watery) environment Hydrophobic Molecules Cling Together in an Aqueous Solution Hydrophilic Hydrophobic Give examples. Van der Waals Attractions Reinforce Hydrophobic Interactions Hydrogen Bonds Are Weak But Important Hydrogen bonds in water, protein, and DNA. Fig. 2-12 Water Is Denser as a Liquid Than as a Solid • Table 2-2 • Compare water to alcohol and oil Water Absorbs More Heat Than Most Substances • Heat capacity • stores heat • cools coasts and the body Water Molecules Cling to One Another • Cohesion • Surface tension • Give examples. Water Molecules Cling to Many Other Substances • Adhesion • Capillary action • Give examples. Water Is a Powerful Solvent • Solvent • Solute • Amphipathic - contain both hydrophilic and hydrophobic regions • Examples- detergent and mayonnaise • Fig. 2-18 Water Participates in Many Biochemical Reactions Planet Water Water Molecules Continually Split into Hydrogen Ions and Hydroxide Ions Hydroxide ion (OH-) Hydronium ion (H3O+) Study equations. pH Scale • pH = power of the hydrogen • pH scale 1 - 14 • logarithm to the base 10 • A pH of 2 is 100 X as strong as a pH of 4 • each number is a 10 fold difference • acid - a pH of 0-6.99 • Contains more hydrogen than hydroxide ions • pH 7 = H + OH = H2O • base - a pH over 7 - 14 • Contains more hydroxide than hydrogen ions • Fig. 2-20 Life At Low pH Box 2-2 Why Is pH Important to Organisms? Discuss examples. Buffers: How Do Organisms Resist Changes in pH? • Buffers neutralize acids and bases. • Carbonic acid and bicarbonate are two important buffers of the body. • Body pH should be 7.35-7.45 or problems will occur. • Acids and bases combine to form salts and water. • Acids buffer bases - bases buffer acids