Nature’s CloCk When sedimentary rock The Law of Superposition doesn’t tell scientists how old a rock layer is, it only tells them that is deposited in layers it isisolder than another. one layer deposited horizontally. Another way to say this is that the Law of Superposition tells scientists the order the layers Scientists use this were deposited. “Principle of Original Horizontality” toofhelp Any method dating that only orders events only measures: them determine the age of the layers. The older layers of rock are found below the younger layers of rock. Relative Age If the Law of Superposition only tells scientists relativeToage, how radioactive can we dating determine theto understand you first need Any method that determines the numerical age of an object measures: numerical ageradioactive of a rock layer, fossilofor understand decay and theaconcept half-an artifact? life. To determine the numerical age of a geologic object fossil, stone scientists To(rock, understand radioactive decaytool, and the…) concept of half- use a method Radioactive Dating. lifecalled you need to understand the structure an atom. So radioactive dating measures absoluteof age. In radioactive dating, scientists find traces of a radioactive material in the object and determine the number of times that material has decayed to determine the age of the object. Absolute Age An atom consists of a nucleus containing positively charged protons and neutral neutrons. The negative electrons surround the nucleus in an electron cloud. Proton Electron Neutron 1 protons? 2 proton? What element has 76 H Hydrogen He C -- Carbon - Helium What element has 92 protons? You Decide!!!!!!! The number of protons determines the type of atom. On the periodic table, the number of protons is shown as the atomic number. Since the protons are all positively charged they want to repel (push away from) each other. So what keeps the nucleus of an atom together? Enter the neutrons. Neutrons have a very important job in the nucleus of an atom. They supply a strong force that glues the protons together in the nucleus. Neutrons are unstable when they are isolated from protons. When a neutron is by itself or just very far away from a proton they break apart (decay) into a proton and an electron. If I have two atoms of the same element, they must Carbon has 6 protons in its nucleus. have the same number of protons. But these same two atoms of the same element can A stable isotope of carbon also has 6 neutrons in its have different numbers of neutrons. nucleus. Atoms of the same element that have different numbers of neutrons are called isotopes. The symbol for this isotope of carbon is either: Different isotopes of an atom are shown as: or or When a nucleus is unstable it can emit (spit out) particles or energy. This is called radiation. When the nucleus emits particles it changes the type of atom. This is called radioactive decay. There are three types of radiation we will look at here: Alpha Decay Beta Decay Gamma Radiation An Alpha Decay changes the atom because during the decay the atom loses 2 protons. When the number of protons in the nucleus of an is very compared to(the the number ofdecay), Inatom the example shownlarge below, the parent nucleus nucleus before the Uranium, has 92 protons before it decays. neutrons, the protons repel each other with more After it decays and emits alpha particle, the daughter nucleus (what’s left after force than thean neutrons can provide to glue the the decay) now has 90 protons because it lost 2. protons together. This meanscauses the uranium nucleus with 92 neutrons protons has changed into thorium with This protons and to be expelled 90 protons! (pushed out) of the nucleus. An Alpha Particle (α) is what is expelled from the nucleus. An Alpha particle consists of 2 protons and two neutrons – it is the nucleus of a helium atom!!! A beta decay changes the atom because it adds a proton to its nucleus. When the number of neutrons in the nucleus In the beta decay shown below, the parent nucleus is potassium which of an atom has 19becomes protons in itsmuch nucleus larger before thethan decay. the number of protons the neutrons begin to After the decay, a beta particle is expelled adding one proton to the decayofinto a proton and an electron. nucleus the daughter nucleus giving it 20 protons. This makes the calcium!!! The proton isdaughter addednucleus to the nucleus of the atom. This changes the type of atom. The electron is expelled (pushed out) from the nucleus. This electron is the beta(β) particle. After an alpha or beta decay, the daughter nucleus has a large amount of stored energy in it. We say it is excited. When the nucleus “shakes out” this energy it releases a high energy gamma (γ). The release of the gamma ray does not change the type of atom, although the atom changed due to the alpha or beta decay. Below is a radioactive link to an animation half-life. While you When element of decays it decays gradually over time, notnotice: all at once. work with this animation The time it takes half (50%) of the atoms in a decay is called the half-life of the 1)substance What effecttodoes changing the half-life have on substance. how quickly the dots disappear? For example, if you now have 200 atoms of a 2)How much time does it then take for halfhalf-life the dotsof tothe radioactive substance, in one disappear?you will have 100 atoms. substance That is half of 200. The half-life for different substances can be less Click on pictureto to go to the than a the second millions of years. animation! But the half-life of the same substance (isotope) will remain the same. A very important radioactive isotope for radioactive Number of HalfNumber of Number of C-14 Fraction of C-14 Percent of C-14 dating is carbon-14. Lives Years Atoms Left Atoms Left Atoms Left C-14 undergoes a beta decay and decays into nitrogen-14. 5730 256 1 100% C-140 has a half-life of 5730-years. 11,430 128 1/2 50% This1 means that on average ½ (50%) of the C-14 will 2 17,190 64 25% decay every 5730-years into N-14. 1/4 22,920 started with 32 1/8 Let’s3 assume we 256 C-14 atoms,12.5% this 4 28,650 5730-years 16 1/16 6.25% means that after we should have 128 atoms (1/2 or 34,380 50%). 5 8 1/32 3.125% After 5730-years4 we should1/64have 64 1.5625% atoms 6 another40,110 (1/47or 25%).45,840 2 1/128 0.78125% This8 will continue until there are no more C-14 51,570 1 1/256 0.390625% atoms left. 9 57,300 0 0 0% While an animal or plant is living it takes in two different isotopes of carbon. Carbon 12 which is stable and Carbon-14 which is unstable. After the animal or plant dies, it no longer takes in C-12 or C-14. At this point the C-14 in the animal or plant will decay and not be replaced but the amount of C-12 will remain the same. Scientists can use the amount of C-12 in the animal or plant to determine the amount of C-14 in the animal or plant at its death. Once the original amount of C-14 is known scientists can compare this to what is left and figure out the number of half-lives that have occurred since the animal or plant died. Since the half-life of C-14 is 5730 years, multiplying the number of half-lives that have occurred by 5730 years gives a very good estimate of absolute age of the plant or animal. A clay pot was found buried near an ancient temple . Based on an analysis of the amount of C-12 in the clay pot, it has been determined that the pot originally had 0.034 grams of C-14. The same analysis has determined that the clay pot now contains 0.0010625 grams of C-14. How old is the clay pot? The best way to solve this problem is to use a table to figure out the number of halflives: Mass 0f C14 Number of Half-Lives 0.034-g 0 0.017-g 1 0.0085-g 2 Each half-life takes 5730years. 0.00425-g 3 This means that the pot is 0.0002125-g 4 5 X 5730 = 28,650 years old. 0.0010625-g 5 5 half-lives have occurred since the materials that contained carbon in the clay pot “died”. Using this technique, almost any sample of organic material can be ABSOLUTELY dated. There are a number of limitations, however: 1) First, the size of the archaeological sample is important. Larger samples are better, because purification and distillation remove some matter. 2) Second, great care must be taken in collecting and packing samples to avoid contamination by more recent carbon. Also, the sample should be carefully examined to determine that a carbon sample location was not contaminated by carbon from a later or an earlier period. Using this technique, almost any sample of organic material can be ABSOLUTELY dated. There are a number of limitations, however: 3) Third radiocarbon dating has significant upper and lower limits. It is not very accurate for fairly recent deposits. In recent deposits so little decay has occurred that the error factor may be larger than the date obtained. The practical upper limit is about 50,000 years, because so little C-14 remains after almost 9 half-lives that it may be hard to detect and obtain an accurate reading, regardless of the size of the sample. Using this technique, almost any sample of organic material can be ABSOLUTELY dated. There are a number of limitations, however: 4) Fourth, the ratio of C-14 to C-12 in the atmosphere is not constant, although it was originally thought that it was. To compensate for this variation, dates obtained from radiocarbon laboratories are now corrected using standard calibration tables developed in the past 15-20 years.