Week 11 Chemistry Isotopes, Electron Configuration Warm Up: 4 Minutes Stay in your own seat Write the Learning Target You should be working SILENTLY Calculate the smallest increment of energy that is the quantum of energy, which an object can absorb from a red light whose wavelength is 3.2 x 10-7 m. Agenda Warm Up: 8 minutes Pre-Lab/Expectations: 7 minutes Lab: A Penny for Your Isotopes: 25 minutes Post Lab Discussion: 10 minutes Closing: 3 minutes Penny Lab Take 62 seconds to read the introduction paragraph. Atomic mass vs. Mass Number The Mass Number is the total number of Neutrons and Protons The Atomic Mass is an average of the different mass numbers It can be a decimal Mass Number 13 𝐶 6 Atomic Mass Problem Is there a difference in the mass of pennies made before 1982 versus pennies made after 1982? Hypothesis YOU HAVE 46 SECONDS WITH YOUR SHOULDER PARTNER TO WRITE A TESTABLE HYPOTHESIS BASED ON PRIOR KNOWLEDGE Pre-Lab Questions What is the difference between Atomic Mass and Mass Number? What is an isotope? Lab Expectations Work in assigned groups Utilize proper safety practices Raise your hand if you have a question Do NOT Throw Pennies! General information: How to do the lab 1. Sort the pennies into two groups (pre-1982 and post-1982) 2. Count number of pennies in each group 3. Find mass of all pennies in each group TOGETHER All pre-1982 together, All post-1982 together 4. Find average mass of each group of pennies 𝑇𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑝𝑒𝑛𝑛𝑖𝑒𝑠 𝑖𝑛 𝑔𝑟𝑜𝑢𝑝 𝐴𝑣𝑒𝑟𝑎𝑔𝑒 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑝𝑒𝑛𝑛𝑖𝑒𝑠 𝑖𝑛 𝑔𝑟𝑜𝑢𝑝 = 𝑁𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑝𝑒𝑛𝑛𝑖𝑒𝑠 𝑖𝑛 𝑔𝑟𝑜𝑢𝑝 5. Find average mass of all pennies 𝑇𝑜𝑡𝑎𝑙 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑝𝑒𝑛𝑛𝑖𝑒𝑠 𝐴𝑣𝑒𝑟𝑎𝑔𝑒 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑎𝑙𝑙 𝑝𝑒𝑛𝑖𝑒𝑠 = 𝑁𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑝𝑒𝑛𝑛𝑖𝑒𝑠 𝑖𝑛 𝑡𝑜𝑡𝑎𝑙 Penny Lab You need a Bag of Pennies and your Brain Good Luck!!! What is the difference between these pennies? Isotopes Atoms of the same element that have the same number of protons but different numbers of neutrons Examples: 13 6 C 12 6 C Naming Isotopes Put the mass number after the name of the element Example: a. Carbon-12 b. Carbon- 14 Practice this idea… By completing the Isotope Penny Lab Extension Worksheet Closing Identify the two isotopes of a penny. Define the term isotope. Warm Up: 3 Minutes Write the Learning Target Stay in your own seat You should be working SILENTLY What do these atoms have in common? How are they different? 15 7 X 14 7 X Agenda Warm Up- 7 minutes Cornell Style Notes/ Examples- 15 minutes Guided Practice- 15 minutes Independent Closing- Practice – 15 minutes 1 minute Take out paper for notes BLUE RED Atomic Mass Weighted average mass of naturally occurring isotopes of an element ** Each isotope has its own mass** UNITS FORMULA AMU Average Atomic Mass = (Percent in decimal x Mass) + (Percent in decimal x Mass) +(Percent in decimal x Mass) +… Relative Abundance The percent occurrence (in decimal form) of a specific isotope of an element Review: Converting percent to decimal To convert a percent to decimal, divide it by 100 Examples: 72% = 0.72 24% = 0.24 8% = 0.08 Check Point Convert 23.51% to a decimal 0.2351 What do you need to find Average Atomic Mass? 1.Mass of Individual Isotopes 2.Percent as a decimal Check Point What items are needed to calculate the atomic mass of an element utilizing isotopes? 1. Mass of individual isotopes 2. Relative abundance (Percent in decimal) I Do There are 3 naturally occurring isotopes of the element Simonium. The following is a list of these isotopes’ abundance in nature and their rounded masses. 142.77 amu 32.0% 143.21 amu 6.4% 141.66 amu 61.6% Calculate the average atomic mass of Simonium from these data. We Do (CLASS) Naturally occurring Chlorine (Cl) consists of two isotopes with a mass of 35 and 37. Chlorine-35 has an abundance of 75.78% and Chlorine-37 has an abundance of 24.22%. What is the atomic mass of Chlorine? We Do (Team) Naturally occurring Carbon (C) consists of three naturally occurring isotopes. Carbon-14 has an abundance of 23.10 %, Carbon-12 has an abundance of 72.10 %, and Carbon-13 has an abundance of 4.8%. What is the atomic mass of Carbon? YOU DO Naturally occurring Gallium (Ga) consists of two naturally occurring isotopes. Gallium-69 has an abundance of 60.11 % and Gallium-71 has an abundance of 39.89 %. What is the atomic mass of Gallium? Practice Makes Perfect… 85% MASTERY Closing What items do you need to find the average atomic mass of an element? Warm Up: 4 Minutes Stay in your own seat Write the Learning Target You should be working SILENTLY Which of these examples of matter are composed of more than one substance that can physically be separated and have a uniform composition? a. Copper, Cu b. Glucose, C6H12O6 c. Double Cheese Burger d. Lemonade Warm Up: 4 Minutes Write the Learning Target Which of these examples of matter are composed of more than one substance that can physically be separated and have a uniform composition? a. Copper, Cu b. Glucose, C6H12O6 c. Double Cheese Burger d. Lemonade Agenda Warm Up- 6 Minutes Discussion/ Cornell Style Notes- 15 Minutes Guided Practice- 15 Minutes Independent Practice- 15 Minutes Closing- 2 Minutes Goal for the Next Few Days Construct Electron Configuration for Elements Aluminum Take out paper for notes BLUE RED Let’s Look at a Periodic Table… 1 1 IA 1 H Periodic Table 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 1.00797 2 3 Li 4 5 Be B 6.939 9.0122 3 4 5 6 7 11 Na 12 Mg 22.9898 24.305 19 20 K Ca 3 IIIB 21 Sc 4 IVB 22 Ti 5 VB 23 V 6 VIB 24 Cr 7 VIIB 25 Mn Rb Sr Mo Tc 85.47 55 87.62 88.905 91.22 92.906 95.94 56 57 72 73 74 [99] 75 Ba 7 N 8 O 9 F He 4.0026 10 Ne 10.811 12.0112 14.0067 15.9994 18.9984 20.179 8 26 Fe 9 VIIIB 27 Co 10 11 IB 28 Ni 39.102 40.08 44.956 47.90 50.942 51.996 54.9380 55.847 58.9332 58.71 37 38 39 40 41 42 43 44 45 46 Cs 6 C 18 VIIIA 2 Y La Zr Hf Nb Ta W Re 132.905 137.34 138.91 178.49 180.948 183.85 186.2 87 88 89 104 105 106 107 Fr Ra Ac Ku [223] [226] [227] [260] Ru Rh Pd 29 12 IIB 30 Cu Zn 63.54 47 65.37 48 Ag Cd 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar 26.9815 28.086 30.9738 32.064 35.453 39.948 31 32 33 34 35 36 Ga Ge 65.37 49 72.59 74.9216 78.96 79.909 83.80 50 51 52 53 54 In Sn As Sb Se Te Br I Kr Xe 101.07 102.905 106.4 107.870 112.40 114.82 118.69 121.75 127.60 126.904 131.30 76 77 78 79 80 81 82 83 84 85 86 Os 190.2 108 Ir Pt Au Hg Tl Pb Bi Po 192.2 195.09 196.967 200.59 204.37 207.19 208.980 [210] 109 At Rn [210] [222] Periods (or Energy Levels) Where do Electrons Really Live? Ok so, yes, Bohr was right. Electrons move around the nucleus at certain energy levels, but it’s a little more complicated. Within these levels: Sublevels: regions where an electron is likely to be found. Orbitals: Part of a sublevel, more exact descriptions of where an electron is found. Location of the Electron Energy Level (n = 1, 2, 3…) Sub-Levels (s, p, d, and f) Orbitals Check Point Celeste found that Helium had an electron configuration of 1s2 , What energy level would these electrons be found on? 1st Energy Level Warning!!! About to get all Chemistry-language on you! Sublevels Each sublevel corresponds to a different shape s sublevel spheres p sublevel dumbbell-shaped Sublevels d sublevel like balloons tied together or balloons with a hula hoop f sublevel like balloons with cupcake wrappers or bracelets Check Point What are the four types of sublevels? S, P, D, F More on Sublevels Each sublevel has a different number of orbitals: Sublevel s p d f # of orbitals Copy This Table More on Sublevels Each sublevel has a different number of orbitals: Sublevel s p d f # of orbitals 1 More on Sublevels Each sublevel has a different number of orbitals: Sublevel s p d f # of orbitals 1 3 More on Sublevels Each sublevel has a different number of orbitals: Sublevel s p d f # of orbitals 1 3 5 More on Sublevels Each sublevel has a different number of orbitals: Sublevel s p d f # of orbitals 1 3 5 7 Pauli Exclusion Principle Each atomic orbital may hold a maximum number of TWO electrons, each with opposite spin direction. Check Point As Raven composed the electron configuration for Neon, she completely filled the 2p sublevel. How many electrons were in the p sublevel? The Houses in the Neighborhood Must Be Filled in Order! The tree diagram shows us which sublevels are filled with electrons first…follow the arrows! Let’s Draw The Tree Diagram Check Point Which orbital fills first, 3d or 4s ? 4s Guided Practice 1. Within each sublevel, there is a greater chance of locating the electron, what is this area called? How many electrons can be held in this portion of the atom? Within each sublevel, there is a greater chance of finding the electron in an orbital. Orbitals can hold two electrons each. 2. Copper has a partially filled 3d sublevel. What is the maximum number of electrons that can be placed within the 3d sublevel? Why? In the d sublevel of any energy level, 10 electrons can be placed because all d sublevels have five orbitals. 3. Fluorine has an electron configuration of 1s22s22p5. What number indicates the outermost energy level? How many electrons are currently on the outermost energy level? The coefficient 2 indicates the outermost energy level. Considering that s on the second energy level has 2 electrons and p on the second energy level has 5 electrons, there are a total of seven electrons in the outermost shell. 4. How many f orbitals are in the third principal energy level? Explain your answer. According to the tree diagram, the third energy level only has the s, p, and d sublevel (i.e. orbitals). Therefore, there are ZERO f orbitals on the third energy level. Now You Practice! Finished early? Start your homework: Construct the tree diagram 10 times to help with memorizing it. Memorizing the tree diagram now will make your life SO much easier in the future Closing Where How do electrons live? many live together? Warm Up: 2 Minutes Stay in your own seat Write the Learning Target You should be working SILENTLY Draw the tree diagram. Include all arrows. POP QUIZ! Put everything away except for a pencil or pen Backpacks, binders, and notes on the floor Draw the tree diagram. Include all the arrows. 2. List the following sublevels in order of increasing energy: 1. 3s, 2p, 4d, 5s, 4f, 1s Agenda Warm Up- 7 Minutes Cornell Style Notes/ Examples- 15 minutes Guided Practice- 15 minutes Independent Practice – 13 minutes Closing – 3 minutes Take out paper for notes BLUE RED Review of Yesterday Energy Level (1, 2, 3) Sublevel (s, p, d, f) Neighborhood Streets Orbitals Houses Electrons People Key Points from Yesterday Energy Level MAXIMUM of 2 electrons per orbital Sublevel s p d f # of orbitals 1 3 5 7 Max # of electrons 2 6 10 14 Electrons 2 3s Sublevel Electron Configuration The ways in which electrons are arranged around the nuclei of atoms. HINT: You must include the Neighborhood, Street, and House. Example: Aluminum – ATTENTION!!! Three Laws You Must Follow In Order to Master Electron Configuration Law 1: Aufbau Principle Electrons enter orbitals of lowest energy first Law 2: Pauli Exclusion Principle 1. Each orbital holds up to two electrons “Two to a seat!” 2. The electrons in those “pairs” have to spin in opposite directions Law 3: Hund’s Rule 2p Electrons Then fill orbitals with the same spin first they “buddy up” Because if you could have a seat to yourself, you’d take that before having to cram in with someone else! Right? How do we find valence electrons? Look at the highest energy level Count the number of electrons in this level Example: Aluminum – 3 valence electrons 3rd Energy Level Steps for Orbital notation 1. Find the element on the periodic table to know how many electrons you have 2. Use Aufbau Principle (the tree diagram) to determine which sublevels you fill first 3. Place electrons in the sublevels using the 3 Laws from today 4. Continue until all electrons have been placed You will need your Periodic Table 1 1 IA 1 H Periodic Table 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 1.00797 2 3 Li 4 5 Be B 6.939 9.0122 3 4 5 6 7 11 Na 12 Mg 22.9898 24.305 19 20 K Ca 3 IIIB 21 Sc 4 IVB 22 Ti 5 VB 23 V 6 VIB 24 Cr 7 VIIB 25 Mn Rb Sr Mo Tc 85.47 55 87.62 88.905 91.22 92.906 95.94 56 57 72 73 74 [99] 75 Ba 7 N 8 O 9 F He 4.0026 10 Ne 10.811 12.0112 14.0067 15.9994 18.9984 20.179 8 26 Fe 9 VIIIB 27 Co 10 28 Ni 39.102 40.08 44.956 47.90 50.942 51.996 54.9380 55.847 58.9332 58.71 37 38 39 40 41 42 43 44 45 46 Cs 6 C 18 VIIIA 2 Y La Zr Hf Nb Ta W Re 132.905 137.34 138.91 178.49 180.948 183.85 186.2 87 88 89 104 105 106 107 Fr Ra Ac Ku [223] [226] [227] [260] Ru Rh Pd 11 IB 29 12 IIB 30 Cu Zn 63.54 47 65.37 48 Ag Cd 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar 26.9815 28.086 30.9738 32.064 35.453 39.948 31 32 33 34 35 36 Ga Ge 65.37 49 72.59 74.9216 78.96 79.909 83.80 50 51 52 53 54 In Sn As Sb Se Te Br I Kr Xe 101.07 102.905 106.4 107.870 112.40 114.82 118.69 121.75 127.60 126.904 131.30 76 77 78 79 80 81 82 83 84 85 86 Os 190.2 108 Ir Pt Au Hg Tl Pb Bi Po 192.2 195.09 196.967 200.59 204.37 207.19 208.980 [210] 109 At Rn [210] [222] Example (1) Lithium Example (2) Aluminum Example (3) Vanadium Guided Practice 1. Compose the FULL orbital notation for Nitrogen and based on the orbital notation, write the number of valence electrons in the box 2. Compose the FULL orbital notation for Calcium and based on the orbital notation, write the number of valence electrons in the box 3. Compose the FULL orbital notation for Cobalt and based on the orbital notation, write the number of valence electrons in the box Work… Work… Work… Spend the remainder of class practicing Electron Configuration Closing How many electrons can be held in an orbital? What will help you fill the electrons in the correct order? Warm Up: 4 Minutes Stay in your own seat Write the Learning Target You should be working SILENTLY Construct the Orbital Notation Electron Configuration for Titanium Agenda Warm up: 8 Minutes Expectations Quiz: for Quiz: 5 Minutes 30 Minutes Closing: 2 Minutes Goals for Assessment 85% 13 Questions Topics Covered Atomic Theory Scientist Electromagnetic Speed Spectrum of Light Formula Energy Formula Atomic Mass Calculations (Isotopes) Orbital Notation Electron Configuration Clear your desks Clear desk of everything except for a pencil/pen and calculator Backpacks, binders, and notes on the FLOOR Testing Tips Read the problem and answer choices CAREFULLY If you don’t know the answer, make sure you at least take a guess Guessing on questions you don’t know can only help you! All formulas and constants you need are in the quiz packet Quiz Rules Students will remain SILENT for the duration of the quiz. Even if you are done, YOU CANNOT TALK Keep your eyes on YOUR OWN PAPER Failure to follow the testing rules will result in your quiz being taken. You will then receive a ZERO and a dean referral. Expectations for Assessment Silence Desk Cleared [Except A Pencil & A Calculator Focused mind When you are finished, see Mr. Ghosh for Orbital Notation Electron Configuration Practice Closing Do you feel like you did well on your quiz? What can you do differently to improve your performance?