January 6 Ch. 9 Notes: Stoichiometry – Mole/Mole and Mole to Mass Calculations 7 Ch. 9 Notes: Stoichiometry – Mass/Mass Calc. and Combination 8 Chapter 9 In-Class Team Review WS 9 Ch. 9 Notes: Limiting reagents HW: LR 10 Ch. 9 Notes: Percent Yield HW: % Yield Chapter 9 WS #3 HW: Mole to Mole and Mole to Mass HW: Mass to Mass 13 Lab in Room Percent Yield 14 Finish Lab and Quiz 15 Tums Lab With Percent Yield 16 Go Over Quiz Chapter 9 Review 17 Chapter 9 Test STOICH Bell Work Stoichiometry- Chapter 9 Stoichiometry – study of calculations of quantities in chemical reactions using balanced chemical equations. Balanced Equation 2 Mg + 1 O2 2 MgO Moles 2 moles Mg + 1mole O2 2 moles MgO Mass 46.3 g Mg + 32 g O2 78.3 g MgO Liters 44.8 L Mg + 22.4 L O2 44.8 L MgO The mole ratios can be obtained from the coefficients in the balanced chemical equation. Mole ratios can be used as conversion factors to predict the amount of any reactant or product involved in a reaction if the amount of another reactant and/or product is known. The New Mole Map! __________________________________________________________________________________ Mole - Mole Calculations – Mole ratios are used to calculate the number of moles of product from the given number of moles of reactant, or vice versa. Example: Calculate the number of moles of Na2O that will be produced when 5.00 moles of Na completely react with oxygen gas. 1) Write the equation: _____________________________________________________ 2) Given: ___________________ 3) Want: ____________________ __________________________________________________________________________________ Mole-Mass Calculations - We use mole ratios from balanced chemical equations and the molar conversions from Ch. 7 to calculate amounts (grams) of substances needed or produced in chemical reactions. Example: How many grams of KClO3 must decompose to produce KCl and 1.45 moles O2? 1) Write the equation: _______________________________________________ 2) Given: ___________________ 3) Want: ____________________ __________________________________________________________________________________ Mass-Mass Calculations - Same as mole-mass calculations, with an additional step of converting mass to moles. Example: When 24.0 g of Na are mixed with Cl2, are 52.0 g of NaCl produced? 1) Write the equation: _______________________________________________ 2) Given: ___________________ 3) Want: ____________________ Example: CaCO3, limestone, is heated to produce calcium oxide, CaO, and CO2. What mass of limestone is required to produce 156.0 g of CaO? 1) Write the equation: _______________________________________________ 2) Given: ___________________ 3) Want: ____________________ __________________________________________________________________________________ Combination Calculations: Example: At STP, how many grams of oxygen are needed to produce 19.8 L SO3 according to the balanced equation below? 2SO2 (g) + O2 (g) 2SO3 (g) 1) Given: ___________________ 2) Want: ____________________ __________________________________________________________________________________ Reactants in Excess and Limiting Reactants • Limiting Reactant - the reactant that is used up in a reaction. When you run out of a reactant, the reaction stops and no more product is formed. • Excess Reactant - the reactant that is not used up in a chemical reaction. • The limiting reactant determines the amount of product formed. Steps to determining limiting reactant: 1. Find out how much could be produced from each amount of reactant. 2. Whichever produces less is limiting the amount produced. It is therefore the Limiting Reactant. Example: If 6.70 mol of Na reacts with 3.20 mol Cl2, what is the limiting reagent? How many moles of NaCl will be produced? Na + Cl2 → NaCl ***notice 2 givens, both reactants*** To determine how much excess reactant is left after a reaction, subtract how much of the excess reactant reacted from how much excess reactant you started with. Example: When 0.50 mole of aluminum reacts with 0.72 mole of iodine, to form aluminum iodide, AlI3(s), what mass of AlI3 is produced? How much of the excess reactant will remain? Separate this problem into two different steps. 1. Find the limiting reactant and amount produced (as in previous example) 2. Find amount in excess (left over) 2 Al + 3 I2 → 2 AlI3 Limiting Reactant ________ Excess left over in grams ____________ __________________________________________________________________________________ Percent Yield: Theoretical Yield – The maximum amount of product that could be formed from given amounts of reactants. (What you should get). Actual Yield - amount of product actually obtained in the reaction (What you really get). (Actual/Theoretical) x 100 = % Yield Example: If 12.5 g of copper are reacted with an excess of chlorine gas, then 25.4 g of copper(II) chloride, CuCl2(s), are obtained. Calculate the theoretical yield and the percent yield. 1) Write the equation: ___________________________________________________________ 2) Find the theoretical yield (amount you “should get”) 3) Now do the % yield equation