ADVANCED CHEMISTRY To be able to know what is Chemistry. To be able to distinguish between mixture and substance. Know the properties of state of matter. Learn how to use scientific notation and significant figures. Remember the IS units. Chemistry is the study of matter and its properties (i.e. its composition, structure and reactions) Chemistry is the central science, central to the fundamental understanding of other sciences and technologies. Physics, biology, geology and other subjects share an essential tie to chemistry. Lies in the matters of public concerns: health care improvement, conservation of nature and environmental protection, provision of food, clothing and shelter. There are four states of matter namely solids, liquids, gases and plasma. A pure substance is matter that has distinct properties, cannot be separated by physical means and has a composition that does not vary from one sample to another. An element is a substance that cannot be decomposed into simpler substances. A compound is a substance that is composed of two or more elements combined together Mixtures are combinations of two or more substances in which each substance retains its chemical identity and can be separated by physical means. A homogenous mixture (solution) has a uniform distribution of the combined substances. A heterogeneous mixture has a non-uniform distribution of the composing substances. Physical Properties Can be observed without changing a substance into another substance (e.g. color, odor, boiling point, density, mass, volume, etc. Chemical Properties Can only be observed when a substance is changed into another substance (e.g. flammability, corrosiveness, reactivity with acid, etc.). Intensive Properties Are independent of the amount of the substance that is present (e.g. density, boiling point, color, etc.). Extensive Properties Depend upon the amount of the substance present (e.g. mass, volume, energy, etc.). Physical Changes These are changes in matter that do not change the composition of a substance i.e. changes of state, temperature, volume, etc. Chemical Changes Chemical changes result in new substances i.e. combustion, oxidation, decomposition, etc. Filtration In filtration, solid substances are separated from liquids and solutions. Distillation Distillation uses differences in the boiling points of substances to separate a homogeneous mixture into its components. Can include simple distillation and fractional distillation. Chromatography This technique separates substances on the basis of differences in solubility in a solvent. Others Decantation; evaporation; crystallization; sublimation; magnetic separation; centrifugation; precipitation, etc. Measuration is the process of or act of assigning numbers to phenomena according to a rule. METRIC SYSTEM (mks) This is the decimal system of weights and measures based on the meter, the kilogram and the second. INTERNATIONAL SYSTEM OF UNITS (SI Units) An international convention that measures everything in terms of seven basic units. BRITISH SYSTEM – BE (fps) Is a decimal system of weights and measures based on the foot, the pound and the second (and the pint). Mass = SI unit is kg Volume = SI unit is mL & cm^3 Density = SI unit is g/cm^3 Temperature = SI unit is K In scientific notation, the numbers are written in the form N x 10n where N is between 1 and 10 and n is an integer. Accuracy refers to the proximity of a measurement to the true value of a quantity. Precision refers to the proximity of several measurements to each other. The accepted value is the correct value for the measurement based on reliable references. The experiment value is one measured in the lab. The difference between the experimental values is called the error. Percent error is the absolute value of the error divided by the accepted value multiplied by 100% The term significant figures refer to digits that were measured. All nonzero digits are significant. Zeroes between two significant figures are themselves significant. Zeroes at the beginning of a number are never significant. Zeroes at the end of a number are significant if a decimal point is written in the number. When addition or subtraction is performed, answers are rounded to the least significant decimal place. When multiplication or division is performed, answers are rounded to the number of digits that corresponds to the least number of significant figures in any of the numbers used in the calculation. It is a practice of using all units, even in conversion factors, leading to cancellation of everything except the final correct units. 1.Lecture: Theodore E. B., Eugene, H. L. H., Bruce E. B., Catherine M., Patrick W., (2011). Chemistry: The Central Science (12 Ed). Prentice Hall. USA. 2. Laboratory: Theodore E. B., John H. N., Kenneth C. K., Matthew S. (2011). Laboratory Experiments for Chemistry: The Central Science (12 Ed). Prentice Hall. USA. 3. Theodore E. B., (2011). Solutions to Exercises for Chemistry: The Central Science. Prentice Hall. USA. 4. John M., Robert C. F. (2010). Chemistry (4 Ed): Prentice Hall Companion Website. http://wps.prenhall.com/esm_mcmurry_chemistry_4/9/2408/616516.cw/index.html 5. Chemistry Online at http://preparatorychemistry.com/Bishop_Chemistry_First.htm 6. Chemistry and You at http://www.saskschools.ca/curr_content/science9/chemistry/index.html 7. Teachers Notes