Starter: Breaking Down Misconceptions Determine which of the following are true or false. Justify the statements you consider to be false. 1. The Modern Periodic Table organizes the elements based on atomic weight (mass). 2. Longitude is to GROUPS as Latitude is to PERIODS. 3. Although over 100 elements are found on the Periodic Table, several of them do not really exist. Mendeleev Activity (The Hoya Table) Organize yourselves into columns according to your similar physical properties and rows based on your age. Mendeleev and Moseley will facilitate. All students should help! The only rule is that Girls must be on the left side of the room and Boys on the left. The middle row can be mixed. Possible properties that you could use: shirt color, hair color, glasses, shoe types, shirt type You have 8 minutes to get as many of your classmates seated as possible. May the best Hoya Table win! Pre-Periodic Table Chemistry … …was a mess!!! No organization of elements. Imagine going to a grocery store with no organization!! Difficult to find information. Chemistry didn’t make sense. History of the Periodic Table: Mendeleev vs Moseley MENDELEEV Arranged the elements by MOSELEY Developed a new understanding of periodic law increasing ATOMIC and REVISED Mendeleev’s WEIGHT organization of the PT Put elements in columns by Realized that atomic mass the way they reacted. (weight) was NOT as He left blank spaces for what important in the organization he said were undiscovered of the elements as the elements. (Turned out he ATOMIC NUMBER was right!) Arranged the elements in order of increasing ATOMIC NUMBER Background: The Periodic Law The Periodic Law states that there is a recurring pattern in the PROPERTIES of elements when they are arranged in order of INCREASING ATOMIC NUMBER. This pattern can be seen every 8 representative elements The Periodic Road Map GROUPS PERIODS Groups are the COLUMNS found Periods are the ROWS on on the PT Elements in the same GROUP: Apart of the same FAMILY Have the SAME number of valence electrons Form the same kinds of IONS What would this say about their properties? They demonstrate SIMILAR properties the PT There are 7 periods on the PT that represent the 7 principal energy levels within the atom Elements in the same PERIOD: Valence Electrons exist within the SAME principal energy level What BLOCK do you stay on? The PT can also be broken down into a BLOCK SYSTEM Elements on the PT reside in certain blocks which are reflected at the end of their electron configuration The block system is based on the SUBLEVELS that electrons can be found in within the atom. What are they? S, P, D, F What BLOCK do you stay on? S block: blue D block: red P block: yellow F block: green To Be or Not To Be… Elements on the PT are either Metal, Non-metal or Metalloid These differences affect the properties of the elements METALS: solid at room temp, tend to LOSE electrons to become more stable (+ IONs), on the LEFT SIDE of the PT, good conductors of energy NON-Metals: typically your gases, tend to GAIN electrons to become more stable (- IONs), on the RIGHT SIDE of the PT, poor conductors of energy METALLOIDS: found in between metals and nonmetals and so are their properties, on the STAIRCASE in the middle right of the table To Be or Not To Be… Metals = Blue Metalloids = Pink Non-metals = Yellow Starter: PT Anatomy CFU Explain the difference between Mendeleev’s and Moseley’s organization of the Periodic Table. What are the columns and rows on the Periodic Table called and what information can you pull from them? Which element would conduct electricity better, Phosphorus or Sodium? Why? Families on the Periodic Table Elements on the periodic table can be grouped into families bases on their chemical properties. Each family has a specific name to differentiate it from the other families in the periodic table. Elements in each family have a stronger reactions as you move down the table. Why? Their valence electrons have more energy (on a higher energy level) ALKALI METALS Group 1 Hydrogen is not a member, it is a non-metal 1 electron in the outer shell Soft and silvery metals Very reactive, esp. with water Conduct electricity Image: http://www.learner.org/interactives/periodic/groups2.html ALKALINE EARTH METALS Group 2 2 electrons in the outer shell White and malleable Reactive, but less than Alkali metals Conduct electricity TRANSITION METALS Groups in the middle Good conductors of heat and electricity. Some are used for jewelry. The transition metals are able to put up to 32 electrons in their second to last shell. Can bond with many elements in a variety of shapes. BORON FAMILY Group 3 3 electrons in the outer shell Most are metals Boron is a metalloid CARBON FAMILY Group 4 4 electrons in the outer shell Contains metals, metalloids, and a non-metal Carbon (C) NITROGEN FAMILY Group 5 5 electrons in the outer shell Can share electrons to form compounds Contains metals, metalloids, and non-metals OXYGEN FAMILY Group 6 6 electrons in the outer shell Contains metals, metalloids, and non-metals Reactive Halogens Group 7 7 electrons in the outer shell All are non-metals Very reactive are often bonded with elements from Group 1 Noble Gases Group 8 Exist as gases Non-metals 8 electrons in the outer shell = Full Helium (He) has only 2 electrons in the outer shell = Full Not reactive with other elements Do NOT lose or gain electrons; They’re already stable Rare Earth Metals: Lanthanides and Actinides Some are Radioactive The rare earths are silver, silverywhite, or gray metals. Conduct electricity Can also be called Inner Transition Metals Periodicity Part II: TRENDS You must know the following trends for on the PT: Atomic Radius 2. Ionic Radius 3. Electronegativity 4. Ionization Energy 1. Trend 1: Atomic Radius Atomic Radius is A measure of the size of the atom half of the distance between the centers of two atoms of that element that are just touching each other Measured from the nucleus to the boundary of the farthest (highest) energy level for the valence electrons Trend 2: Ionic Radius Ionic Radius is… A measure of the size of the ion half of the distance between the centers of two atoms of that element that are just touching each other Measured from the nucleus to the boundary of the farthest (highest) energy level for valence electrons Trend 3: Electronegativity Electronegativity is… a measure of the tendency of an atom to attract electrons the desire an atom has for electrons in a bond Similar to Electron Affinity Trend 4: Ionization Energy Ionization energy is the amount of energy REQUIRED to remove an electron from an atom The Trends…What you need to know Know what each trend means How they change as you move to the… Right and left of a period 2. Up and down a group Be able to compare the elements according to the trends 1. PT Trends Activity Periodic Table Trends Mendeleev’s Castle Google: PT Trends Complete the activity and lynchburg Click on Cool PT Use the information that you find when you click on each element to complete the WS Important: You will have a quiz on this on Friday! correctly answer the questions Important: This assignment is due at the end of class! Starter: Analyzing Trends Explain the difference between the 4 trends on the Periodic Table. Does Sodium or Chlorine have a higher electronegativity? Does Copper or Gold have a higher atomic radius? Does Potassium or Xenon have a higher 1st Ionization energy? Analyzing Trends Important: When analyzing a trend for elements in different groups and different periods… 1. consider the trend going down the group 2. consider the trend going across the period. Analyzing the Trends Atomic Radius Increases as you move Ionic Radius Increases as you move DOWN the PT DOWN the PT Why? You’ve added more Why? You’ve added more energy levels. energy levels As you move across the PT… Decreases as you move to the - Decreases for Metals because RIGHT of the PT they tend to _______ Why? The force of the nucleus electrons. (+ Ion = Cation) is stronger and it pulls the - Increases for Non-metals electrons closer because they tend to _______ electrons ( - Ion = Anion) Analyzing the Trends Electronegativity Decreases as you move Ionization Energy Decreases as you move DOWN the PT DOWN the PT Why? Electrons are farther out Why? The attraction of the from the nucleus which has less positive nucleus decreases as of a hold; more likely to get the shell gets farther. taken because it takes less Increases as you move to the energy RIGHT across the PT Increases as you move to the Why? Elements want electrons RIGHT across the PT more and more to become Why? As you move to the right more stable. the elements really want to keep their electrons so it requires more energy to take them. Diatomic Molecules Why do atoms form ions? To Become More STABLE! Well…a few elements can also do something else to become stable. They come together and share electrons (or BOND) with each other. They are called DIATOMIC MOLECULES. Here are the Diatomic Molecules (Pay attention to which elements can form Diatomic Molecules!) N2, O2, F2, Cl2, H2, Br2, & I2 Starter: Which is larger Ra or Ra+2 ? I or I-? Why? Identify at least 1 element in the following families and what kind of ions they would form: Halogen, Alkali metals, Alkaline earth metals Bromine has less Ionization energy and less Electronegativity than Fluorine. Explain why this is. Which would have a more violent reaction to the same stimuli, Potassium or Francium? Why? Introduction to Halide Lab: In this lab, you will explore ions of the elements in Group 7A. Which family will you be observing? Your objective is to mix the solutions containing these ions with Silver Nitrate and Lead Nitrate. Record your observations in the data table provided. You may write on the lab handout. While in the lab area, be sure to wear your goggles and apron at all times. This assignment is graded and will be turned in today, so be sure to stay on task! Halide Lab (Important Information): Once you have completed the lab and cleaned your lab area, put your safety materials away and begin to answer the Analysis questions. You are responsible the following questions: 2, 3 (excluding the equation portion), 4, and the question below Based on your understanding of families on the Periodic Table, which halide ion would you expect to have the most reactivity in this experiment? Least reactivity? Why? Focus of Study: Know the history of the PT (Mendeleev vs Moseley) Know the organization of the PT (sublevel blocks, groups, periods, Metals vs Metalloids vs Nonmetals) Know the difference between GROUPS (FAMILY) and PERIODS; How to determine them… (Groups – same valence e- = similar activity/properties and types of IONS; Periods – principal (valence) energy level) Know the 4 trends and their meaning - Be able to explain WHY the trends occur as they do Starter: Do You Know the PT What is the valence energy level and number of valence electrons in Silicon? Does Copper, Gold, or Cadmium have a higher atomic radius? Does Cesium, Barium, or Francium have a lower 1st ionization energy? Does Oxygen, Sulfur or Fluorine have a higher electronegativity?