Science 10 Unit 2 YAY, WE’RE DONE 4.1 ! • GREAT JOB: Now you understand how to draw models of ionic and covalent compounds!! (Right? ) • WHAT’S NEXT?? • Now you will learn how to properly write the chemical formula of ionic and covalent compounds (e.g., H20 is the chemical formula for water) • You will also learn how to properly name ionic and covalent compounds (e.g., magnesium phosphide is the name of the ionic compound formed from magnesium and phosphorus) • Writing the name and chemical formula for a compound is done differently if it’s an ionic or covalent compound. (Can’t chemistry ever be simple?) • Today, we will focus on the method for ionic compounds; next class, we’ll cover the method for covalent compounds. SKILL 1: Writing the chemical formula for an ionic compound KEY IDEA: In an ionic compound, the positive charges must balance the negative charges. E.g.: What is the chemical formula for calcium oxide? • “oxide” means oxygen, so there are calcium and oxygen in the compound • look up the ions that calcium and oxygen typically form in an ionic compound on your Periodic Table … Calcium becomes Ca2+ Oxygen becomes O2- • Notice the charges balance if there is one Ca2+ ion and one O2– ion, so the chemical formula is written as: Ca1O1 Wrong!! (actually, the subscript 1 is never written…) CaO Right! But what if one ion of each do not balance each other out? E.g.: What is the formula for magnesium phosphide? • “phosphide” means phosphorus, so look up the ions that magnesium and phosphorus form… Magnesium is Mg2+ Phosphorous is P3- • Notice one ion of each will NOT balance the charges! • Can you figure out how many Mg ions and P ions will be needed to exactly balance each other out?? Lowest common multiple of 2 and 3 is 6 3 Mg2+ ions needed and 2 P3– ions needed to balance charges And the chemical formula is… Mg3P2 Mg2+ P3- Mg2+ P3- Mg2+ 6+ Mg3P2 6- The crystal lattice formed has 2 phosphide ions for every 3 magnesium ions, so charges are balanced! YOU TRY: What is the formula for aluminum fluoride? Aluminum is Al3+ Fluorine is F - To balance charges, 3 Fluoride ions are needed for every 1 Aluminum ion… AlF3 ** Notice that the metal is always written first!! (Useful, but unnecessary if you understand that + and - charges must balance!) Lead sulphide 1. Write both symbols (+ion first) with ion charge 2. Criss-cross the charges and write them as subscripts Pb 4+ S Pb 2 S 4 3. Reduce if possible Pb1S2 4. Remember that the subscript 1 is never written PbS2 2- In the shortcut example, you may have been confused because lead has more than one combining capacity (i.e., more than one ion charge listed on the Periodic Table) e.g. Pb4+ Pb2+ Cu2+ Cu1+ If this is the case, the name of the compound will always include a roman numeral to tell you which combining capacity to use… 1+ I 5+ V 2+ II 6+ VI 3+ III 7+ VII 4+ IV e.g. Iron II oxide Iron III oxide Fe 2+ Fe 3+ FeO O 2- O 2- Fe2O3 So Iron & Oxygen can form two different compounds together! PRACTICE! Try Practice Problems: p.188 #1 a-f & #2 a-f p.190 #1 a-f (It says in the text where to find the answers, so PLEASE check your work as you go and get help if needed!!) SKILL 2: Writing the name of an ionic compound KEY IDEA: Metal + Non-metal (with “-ide” ending) 1. Write the name of the metal first. 2. Write the name of the non-metal second, and change the ending to “-ide” 3. ONLY IF THE METAL HAS 2 OR MORE ION CHARGES, include a roman numeral to indicate which one it is. e.g. NaCl Sodium chloride MgF2 Magnesium fluoride CuCl2 copper has 2 ions: which one is it? Cu 1+ Cu 2+ To find out which copper ion it is, look at the charge on the anion and balance the charges in reverse. CuCl2 Cu 2+ Cl 1Cl 12- from periodic table Therefore it is copper II chloride (Can also be written as copper (II) chloride) YOU TRY: What is the name for Al2S3? Aluminum is NOT multivalent, so we don’t have to worry about Roman numerals Aluminum Sulphide YOU TRY: What is the name for Au3N? Gold is multivalent, so we must worry about Roman numerals!! Gold has 2 ions: Nitrogen is: N 3To balance charges, which Au ion must it be? Au3+ Au+ Gold (I) Nitride PRACTICE! Try Practice Problems: • p.187 #1 a-f • p.191 #1 a-j (the multivalent type!) Again, check your answers as you go! ACK! Can you handle ONE MORE complication? A polyatomic ion is a group of atoms that together act as an ion. (Think about what that means.) The group of atoms is given a name. Ion Charge e.g. SO4-2 OH-1 PO4-3 Sulphate ion Hydroxide ion Phosphate ion -2 -1 -3 Good news: All the polyatomic ions you need to know, and their charges, are included in your Data Pages! Have a look! Can you find the 3 examples? KEY IDEA: When you see a polyatomic ion, treat it as if it is just one atom and follow the rules as usual. e.g. K +1 Formula: PO4 -3 K3PO4 Name: Potassium phosphate Important note: Don’t change the endings of polyatomic ions! YOU TRY: If the ions below form an ionic bond, write the formula and name. Al +3 SO4 -2 formula name Al2(SO4)3 Aluminum sulphate Brackets are necessary around the SO4 to indicate 3 sulphate ions, not 43 oxygen atoms! Cu +2 SO4 -2 formula name CuSO4 Copper (II) sulphate Don’t forget the roman numeral since copper has more than one combining capacity PRACTICE! Try Practice Problems: p.193 #1 a-e & #2 a-e (Check answers!!) Homework If you feel shaky on this stuff, give yourself some more time to pick it up. You can do it! I suggest you read through text p.184-191. Each time you hit a set of “Practice Problems,” try doing some more of them and checking your answers. I suggest this for everyone but especially those feeling a little overwhelmed. Once you feel comfortable with the material, then: 1. Read and highlight workbook p.65-66 2. Complete workbook p.68-69 Be ready to have the workbook marked next class along with the workbook from last day. Don’t let yourself get behind here. We’re plowing forward next class and will be writing a test before the break!!