Intro to Chemical Bonds October 13 and 14, 2014 Do Now Define Which valence electrons of these atoms is more likely to bond with another atom? Explain your reasoning. Do Now Valence Electrons: the electrons in the outermost energy level of an atom. Atoms can have a maximum of 8 valence electrons (except helium with 2). Chlorine will bond more easily because it has 7 valence electrons. It only needs 1 more electron to have a full valence shell (8), so it is more likely to bond than phosphorous which needs 3 electrons. Objective • • I can write the chemical formulas for the ionic bond that will form between two elements. I can draw accurate Lewis Dot diagrams for ionic bonds. Agenda Do Now, Objective (7 min) What Do You See Electron Dot Structures Intro to Ions Ionic Bonding Notes Bonding With a Classmate Independent Practice Exit Ticket What Do You See? Discuss the picture above with a table partner. What do you think the picture represents? Why do you think all of the people are smiling? Why do you think the people are arranged in this order (from left to right) Electron Dot Structure Symbols of atoms with dots to represent the valence electrons IONIC BOND bond formed between two ions by the transfer of electrons Formation of Ions from Metals Ionic compounds result when metals react with nonmetals Metals lose electrons to match the number of valence electrons of their nearest noble gas Positive ions form when the number of electrons are less than the number of protons Group 1 metals ion 1+ Group 2 metals ion 2+ Group 13 metals Metals form Cations ion 3+ Formation of Sodium Ion Sodium atom Na 2-8-1 11 p+ 11 e0 – 1e Sodium ion Na + 2-8 ( = Ne) 11 p+ 10 e1+ Formation of Magnesium Ion Magnesium atom Mg 2-8-2 12 p+ 12 e0 – 2e Magnesium ion Mg2+ 2-8 (=Ne) 12 p+ 10 e2+ Some Typical Ions with Positive Charges (Cations) Group 1 Group 2 Group 13 H+ Mg2+ Al3+ Li+ Ca2+ Na+ Sr2+ K+ Ba2+ Learning Check A. Number of valence electrons in aluminum 1) 1e2) 2e3) 3e- B. C. Change in electrons for octet 1) lose 3e2) gain 3eIonic charge of aluminum 1) 32) 5- 3) gain 5e- 3) 3+ Solution A. Number of valence electrons in aluminum 3) 3 eB. Change in electrons for octet 1) lose 3e- C. Ionic charge of aluminum 3) 3+ Learning Check Give the ionic charge for each of the following: A. 12 p+ and 10 e1) 0 2) 2+ 3) 2B. 50p+ and 46 e1) 2+ 2) 4+ 3) 4- C. 15 p+ and 18e1) 3+ 2) 3- 3) 5- Formation of Ions from Nonmetals In ionic compounds, nonmetals in 15, 16, and 17 gain electrons from metals Nonmetal add electrons to achieve the octet arrangement Nonmetal ionic charge: 3-, 2-, or 1- Nonmetals form anions Fluoride Ion unpaired electron :F 2-7 9 p+ 9 e0 + e octet : F: 2-8 (= Ne) 9 p+ 10 e1ionic charge THOUGHT ACTIVITY • • Quietly answer 1-4 on your own. Turn and talk to your partner about a solution for #5. 1. How many valence electrons does magnesium have? __________ 2. How many valence electrons does a magnesium atom have to gain or lose to become a magnesium ion? ________________________________________ 3. How many valence electrons does chloride have? __________ 4. How many valence electrons does a chlorine atom have to gain or lose to become a chlorine ion? ________________________________________ 5. How might these two atoms make a compromise so that they are both stable (happy)? ____________________________________________________________________________________ IONIC BOND: electrons are transferred from one atom to another so they both will be stable • Between a CATION and an ANION • • ANSWER ON YOUR OWN (30 sec): Why do you think a cation and an anion are bonded together? Between a METAL and a NONMETAL • ANSWER ON YOUR OWN (30 sec): Why can metals and nonmetals easily form ionic bonds? BrainPop Video http://www.brainpop.com/science/matt erandchemistry/chemicalbonds/ EXPLORE FURTHER • • Draw the electron dot diagrams on your own. Turn and talk to your partner about the 2nd question. Draw the electron dot diagram for Mg and Cl. If these two were to transfer electrons, think about how many atoms of each you need for every atom to satisfy a full octet. CRISS-CROSS RULE 1. 2. 3. Write the ion (charges) for the atoms involved. Criss-cross the charges and bring them down as subscripts. Simplify if there is a common factor. EX 1: Mg + Cl Copy my example! Copy my example! cRISS-CROSS RULE 1. 2. 3. Write the ion (charges) for the atoms involved. Criss-cross the charges and bring them down as subscripts. Simplify if there is a common factor. EX 2: What is the ionic bond that is formed between Li and F? cRISS-CROSS RULE 1. 2. 3. Write the ion (charges) for the atoms involved. Criss-cross the charges and bring them down as subscripts. Simplify if there is a common factor. COMPLETE PRACTICE 1-3 on your own! LEWIS DOT DIAGRAMS for IONIC BONDS EX 1: Mg + Cl 1. 2. 3. 4. Determine stable ion for each element. Draw LD for cation. Draw LD for anion. Write number of ions in bond in front of LD LEWIS DOT DIAGRAMS for IONIC BONDS EX 2: Draw the Lewis 1. 2. 3. 4. Determine stable ion for each element. Draw LD for cation. Draw LD for anion. Write number of ions in bond in front of LD Dot diagram for the ionic compound Ca3N2. IONIC BONDING WITH A CLASSMATE DIRECTIONS: 1. 2. Everyone is assigned an element. You must find 5 classmates who you can make an ionic bond with. When you find them, write the formula of your bond and draw the Lewis dot diagram for your bond EXPECTATIONS: • • Work efficiently! Talking science only! (low voices) CLASSWORK COMPLETE • • • #1-11 Independently Quietly Raise a hand for ?’s EXIT TICKET • • • • Put all materials away Try your best! NO TALKING! Finished? Raise your hand and work on HW. Chemical Bonds Day 2 Students will gain practice Balancing ionic compounds Naming ionic compounds Drawing Lewis structures for covalent compounds Do Now What conditions favor the formation of ionic compounds? 1. a. b. c. d. 1. Both atoms must be nonmetals A metal and a nonmetal Both atoms must be metals Must have a metal atom and a noble gas atom What is the definition of a covalent compound? Do Now What conditions favor the formation of ionic compounds? 1. a. b. c. d. Both atoms must be nonmetals A metal and a nonmetal Both atoms must be metals Must have a metal atom and a noble gas atom Do Now What compound would the following ions form? 1. a. b. c. 2. H and Br Mg and Cl Ca and F What group would element X be found in if it forms this compound: Al2X3 Do Now What compound would the following ions form? Criss-Cross! 1. a. b. c. 2. H and Br HBr Mg and Cl MgCl2 Ca and F CaF2 What group would element X be found in if it forms this compound: Al2X3 X is in group 2 (reverse criss-cross) Objective I can name ionic compounds including polyatomic ions and transition metals using independent practice Agenda 1. 2. 3. 4. Do Now, Objective Catalyst Activity Naming Ionic Compounds Going Backwards CATALYST ACTIVITY You will have 8 minutes to circulate the room and find the chemical formulas and names of common household products. Debrief Activity: 1. Which type of ion is listed first in each chemical formula? Which is second? 2. Which type of element is named first in the compound name? Named second? 3. Are there any changes to the name of either element when bonded? 4. How do you think ionic compounds are named? STEPS FOR NAMING IONIC COMPOUNDS FOR YOUR INFORMATION PRACTICE GOING BACKWARDS: From Name Formula PRACTICE Independent Practice Complete the independent practice at your table, and turn it in for an accuracy grade at the end of class. Day 3 Polyatomic ions Transition metals Weekly quiz