Chemistry Tutorial #4 Chemical Compounds Elements – pure substance made of one type of particle Compound – when two or more elements combine Elements are held together by chemical bonds Chemical bonds form when an element gains,loses or shares an electron (charged particle) Chemical Formulas Use symbols and numbers (subscripts) to represent the composition of a pure substance Symbols for each element are used Subscript (#’s) represent the number of atoms of each element Eg. H2o – H=symbol of hydrogen o=symbol for oxygen 2= 2 atoms of hydrogen * note: if a symbol has no subscript it is said to represent having 1 atom. Molecular Compounds Two types of compounds: Molecular and Ionic Ionic compounds form when two atoms transfer electrons to other atoms Molecular compounds form when atoms share electrons Molecule is smallest unit of a pure substance (cluster of atoms) Diatomic molecule is a molecule made of two atoms of the same element. Eg. O, N, H are all diatomic and thus written as O2, N2, H2 Most molecular compounds form sm.structures therefore, have strong bonds between atoms but very weak bonds between molecules. As a result, they have low boiling points and low melting points Naming Molecular Compounds Compounds are named by IUPAC (international union of pure and applied chemistry) recommendations. Binary compounds are made from two elements. Rules for naming: 1. 2. 3. Write the name of the first element Change the ending of the second to “ide” Use a prefix to indicate the # of each type of atom Mono=1 (only used for the second element) Di = 2 Tri = 3 Tetra = 4 Eg. CO2 Carbon Dioxide To change from name to chemical formula 1. 2. Write the symbol for each element in the same order Use subscripts to indicate the # of each atom. When naming a compound, often it has sm.symbols in ( ) to indicate the state of matter (s), (l), (g) or (aq) which = aqueous (solid dissolved in water) Naming Molecular Compounds Try the following: CO _____________________________ SiO2_____________________________ Carbon tetrachloride ________________ Sulfur Dioxide _____________________ Naming Molecular Compounds Try the following: CO carbon monoxide SiO2 Silicon dioxide Carbon tetrachloride CCl4 Sulfur Dioxide SO2 Ionic Compounds Form when atoms transfer electrons An ion is formed when an atom gains or loses an electron and is no longer neutral Ions always have a + or – charge When dissolved in water ionic compounds separate into ions and thus carry an electric current. Naming Ionic Compounds Rules are similar to molecular The main difference is the name doesn’t indicate the #of ions in each element. The Rules: 1. 2. 3. Name includes both elements with the metallic element first Non metallic element is second with “ide” ending Subscripts indicate the ratio of ions in a compound. Eg. CaCl2 calcium chloride (ratio = 1Ca to 2Cl Try the following: NaCl ______________ LiCl _______________ Sodium Fluoride ________ Zinc Sulfide ____________ Try the following: NaCl sodium chloride LiCl Lithium chloride Sodium Fluoride NaF Zinc Sulfide ZnS Properties of Ionic & Molecular Compounds Ionic Molecular Formed from metallic and non-metallic elements Forms ions in solution Conducts electricity Usually formed from only non-metallic elements Doesn’t form ions in solution Non-conducting Solid at room temperature Solid, liquid or gas at room temperature Chemical Reactions Two or more substances combine to form a new substance. Cannot be reversed. Reactants – substances that go into a reaction. Products- what is formed in the reaction Chemical equations How chemists describe reactions Word equations and chemical equations Chemical equations use symbols Eg. Magnesium + oxygen magnesium oxide Or 2Mg(s) + O2 2 MgO (s) + light Balancing Chemical Equations Remember the law of conservation of mass? It says that atoms can’t be lost or created. The atoms essentially change partners. Therefore, you will have the same # of atoms of each element just combined differently. Eg. HC2H3O2 (aq) + NaHCO3 (s) NaC2H3O2 (aq) + H2O (l) + CO2 (g) (vinegar) (baking soda) (sodium acetate) + (water) + (Carbon dioxide) Take a minute to add up the number of atoms of each element on both sides of the equation It is important to balance a chemical equation so that each side of the equation has the same number of atoms of each element. To balance an equation you need to count the number of atoms of each element on the each side of the equation and make both sides equal by using co-efficiants Eg. Magnesium + oxygen magnesium oxide Step 1: write the chemical equation Mg + O2 MgO *oxygen is a diatomic molecule so it is always written O2 Step 2: count the # of atoms of each element. 1Mg & 2O Step 3: balance the equation: there are 2 O’s on the left so we need 2 on the right. Mg + O2 2MgO Step 4: now, we have 2 Mg on the right and only 1 on the left. So, use a coefficiant. 2Mg + O2 2MgO Step 5: count the atoms and make sure eveyone is happy! You now have a balanced equation. Balancing Try the following: CH4 +_ O CO +_ H O 2 2 2 _H + O _ H O 2 2 2 _Na + Cl _NaCl 2 _CaCO +_ H SO _CaSO + _H O +_ CO 3 2 4 4 2 2 Balancing Try the following: CH4 +2 O CO +2 H O 2 2 2 2H + O 2 H O 2 2 2 2Na + Cl 2NaCl 2 _CaCO +_ H SO _CaSO + _H O +_ CO 3 2 4 4 2 2 Breaking Chemical Bonds Chemical bonds are forces that cause a group of atoms to behave as a unit. To break these bonds, energy must be added. When bonds form energy is released Energy is produced or absorbed during a reaction. Exothermic reactions- eg. combustion Endothermic reactions eg. Baking cookies; baking soda breaks down and release CO2 and puffs up the cookies Eg. Corrosion – prevent by zinc / galvanization Reaction Rate You can increase or decrease the rate of a reaction by: Changing the temp. Stirring Changing size and conc. Of reactants Catalysts – speed up a reaction without being changed Eg. Enzymes – these occur naturally in our bodies. Saliva (contains enzymes) helps breaks down the starches in our food Inhibiter – slows down the reaction Eg. Preservatives in food. Quick Note: Memorize the chemical names of common chemicals. These are found on pg 442 -445 in your text. This will be on your midterm! You should know the chemical formula’s for the following: Vinegar Table salt Propane Sugar (sucrose) Glucose Hydrogen peroxide