Atoms are the smallest quantities of matter that still retain the property of that matter Democritus was the first to develop this idea of an atom in the 5th century John Dalton was the first to formalize the idea of an atom with Dalton’s atomic theory Known as the “father of atomic theory” The word “atom” comes from the Greek word “atomos” meaning “uncuttable.” All matter is made up of atoms Atoms are indivisible Atoms of the same element are identical Atoms of one element are different than atoms of another element Atoms come together to form compounds If two elements can combine to create multiple compounds, then the ratios of the masses of the second element which combine with a fixed mass of the first element will be ratios of small whole numbers CO 100 g of C 133 g of O CO2 100 g of C 266 g of O Discovery Who Discovered It How was it Discovered Electron (and Charge-to-Mass ratio) Charge of the Electron Proton & Nucleus J.J. Thomson Cathode Ray Tube (Cathode Ray Experiment) Oil Drop Experiment Gold Foil Experiment Neutron James Chadwick Robert Millikan Ernest Rutherford Beryllium Bombardment Subatomic Particle Proton Charge Location +1 Neutron 0 Electron -1 In the nucleus In the nucleus Outside nucleus Contributio n to Atom Mass Mass Volume Not all atoms of a given element are identical Most elements have 2 or more isotopes (atoms with same # of protons, different # of neutrons) Isotopes behave like each other Named after their mass number Ex: U-235 (“Uranium two thirty five”) If mass number is not given, use rounded atomic mass from PT. If mass number is given (or if protons & neutrons are given), use that value instead of on the PT. If mass # is different than what’s on PT, it is an isotope Atoms with charges (different # of electrons) Positive ions called cations Negative ions called anions # of Protons 14 # of Neutrons # of Electrons Mass Number 14 18 20 14 13 Atomic Number 10 29 6 Ion? Isotope? List the number of protons, neutrons, and electrons in the following elements: Carbon-14 Iodine-128 An atom has a mass number of 114 and 66 neutrons. Write the isotope notation for this atom. Mass of an atom in atomic mass units (a.m.u) Based off of 1/12 of a carbon atom Most elements are mix of isotopes in nature Average Atomic Mass is reported The atomic masses of two stable isotopes of copper, copper-63 and copper 65, are 62.929599 and 64.927793 amu, respectively. If copper-63 is 69.17% and copper-65 is 30.83%, what is the average atomic mass of copper? The atomic masses of 34Cl and 35Cl are 34.0578 amu and 35.0147 amu, respectively. Calculate the natural abundance of these two isotopes. The average atomic mass of Cl is 35.45 amu. Mostly metals (left of stair step) Good conductors of heat/electricity Non metals (right of stair step) Poor conductors of heat/electricity Metalloids/Semi-metals (on stair step) Properties of both metal and nonmetal B, Si, Ge, As, Sb, Te, Po, At Groups: vertical columns Elements in the same group share similar chemical properties 18 groups Periods: horizontal rows Elements transition from metal to nonmetal across a period A unit of quantity (how much) Mole = mol 1 mole = 6.022 x 1023 “particles” “particles” can be atoms, molecules, or formula units This number is called Avogadro’s Number Molar Mass = the mass of ONE MOLE of a substance g/mol 1 mole of water = 18.02 grams 1 mole sodium chloride = 58.44 g 1 mole helium gas = 4.003 g Molar mass is found by Listing elements in compound Determining their mass found on periodic table Multiplying by how many atoms there are Adding these values Ex: H2SO4 How many molecules of magnesium chloride (MgCl2) are there in 67.35 grams of magnesium chloride? How many chlorine atoms are there in the same mass of magnesium chloride? 1)Write the appropriate isotope notation for the following: Z=29, A=64 +3 2)How many protons, neutrons, & electrons in 3)Rb-85(72.17%) is 84.911794. If the average atomic mass of Rb is 85.4678, what is the atomic mass of Rb-87(27.83%). 4)How many grams is 5.30 x 1023 molecules of K2O?