Register Number SATHYABAMA UNIVERSITY (Established under section 3 of UGC Act,1956) Course & Branch :B.Tech - CHEM Title of the Paper :Mass Transfer – I Sub. Code :SCHX1025 (2010) Date :31/10/2012 Max. Marks:80 Time : 3 Hours Session :FN _______________________________________________________________________________________________________________________________ 1. PART - A (10 x 2 = 20) Answer ALL the Questions Define diffusion and what are the types of diffusion. 2. Explain Ficks-Law of diffusion. 3. Define Murphree efficiency. 4. Name any three theories of Mass transfer. 5. What is Molal Absolute Humidity? 6. Explain about wet bulb temperature. 7. Define free moisture and equilibrium moisture. 8. Discuss the terms constant rate period and falling rate period. 9. State Δ L law of crystal growth. 10. Define Nucleation. PART – B (5 x 12 = 60) Answer ALL the Questions 11. (a) Prove DAB = DBA for equimolar counter diffusion in gases. (b) Derive an equation for the steady state diffusion of A through non-diffusing B. (or) 12. (a) Ammonia diffuses through nitrogen gas under equimolal counter diffusion at a total pressure of 1.013 x 105 pa and at a temperature of 298K. The diffusion path is 0.15m. The partial pressure of ammonia at one point is 1.5 x 104 pa and at the other point is 5 x 103 pa. Diffusivity under the given condition is 2.3 x 10-5 m2/s. Calculate the flux of ammonia. (b) Discuss the molecular diffusion in liquids. 13. (a) Explain penetration theory. (b) Discuss Two-Phase Mass transfer. (or) 14. Sulphur-di-oxide is absorbed from air into water in a packed absorption tower. At a certain location in the tower, the mass transfer flux is 0.027 kmol So2/m2h and the liquid phase concentrations in mole fraction are 0.0025 and 0.0003 respectively at the two-phase interface and in the bulk liquid. If the diffusivity of So2 in water is 1.7 x 10-9m2/s, determine the mass transfer co-efficient Kc and film thickness. 15. Draw the various types of cooling tower arrangements and explain in detail. (or) 16. A mixture of nitrogen-acetone vapor at 800mmHg and 250C has percentage saturation of 80%. Calculate (a) Absolute humidity (b) Partial Pressure of acetone (c) Absolute molal humidity. Assume vapor pressure of acetone at 250C as 190mmHg. 17. (a) How will you calculate the drying time under constant drying conditions? (b) What are the parameters that affect the drying rate during constant rate? (or) 18. With a neat sketch explain the rotary dryer. 19. (a) Explain the classification of crystallizer. (4) (b) Explain the principle, construction and working of any one crystallizer with a neat diagram. (8) (or) 20. Sodium acetate solution is available at a temperature of 700C with a solute content of 58%. Find out (a) Percentage saturation (b) yield of crystal if 2000 Kg of this solution is cooled to 100C (c) Percentage yield. Data: Solubility at 70C = 146 gms of sodium acetate/100 gms of water Solubility at 10C = 121 gms of sodium acetate/100 gms of water