Modern Chemistry Chapter 7 Chemical Formulas and Chemical Compounds Sections 1, 3 & 4 Chemical Names and Formulas Using Chemical Formulas Determining Chemical Formulas Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 1 Chapter Vocabulary Monatomic ion Binary compound Nomenclature Oxyanion Salt Formula Mass Percent Composition Empirical Formula Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 2 Section 1 Chemical Names and Formulas Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 3 Chemical Formula Eight carbon atoms in the molecule Eighteen hydrogen atoms in the molecule Molecular compounds – for one molecule Ionic compounds – for one formula unit; the simplest ratio of cations to anions Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 4 Chemical Formula 2 Al atoms 4 O atoms 3 SO4 ions 5 ions – two Al 3+ ions and three (SO4) Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 2- ions 5 Definitions • Hydrocarbon – compounds containing hydrogen and carbon • Binary Compound – compound with only two types of atoms • Nomenclature – a naming system • Oxyanions – negative polyatomic ions with oxygen in them Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 6 Definitions • Monatomic ions – ions formed from a single atom • For negative monatomic ions, -ide is added to the root name Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 7 How can I tell if the compound is ionic or covalent ???? Ionic compounds contain a metal and/or a polyatomic ion !!! Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 8 Writing Fomulas and Naming Ionic Compounds Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 9 Charges on Monatomic Ions + 1 2+ + 3 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 32 1 10 Charges on Transition Metals Ag Zn Cu Fe/Cr Sn Pb 1+ 2+ 1+ 2+ 2+ 2+ or or or or 2+ 3+ 4+ 4+ Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 11 Charges of Metals PbO2 and PbO Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 12 Polyatomic Ions Page 226 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 13 Formulas Ionic Compounds 1. Write the symbols 2. Determine the charges 1. Monatomic ions from the periodic table 2. Transition metals from a roman numeral 3. Polyatomic ions from a chart on p. 226 3. Cross the charges. 4. Reduce to lowest ratio. Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 14 Names Ionic Compounds 1. Write the cation name. 2. Write the anion name. • Add –ide to the anion if monatomic 3. Add the roman numeral for any transition or group 14 metal. 4. NO PREFIXES!!!! Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 15 Ionic Binary Compounds FORMULAS Aluminum Oxide 3+ (3+ x 2 ) + (2- x 2- 3 )=0 Al2O3 (charge x subscript)+(charge x subscript) = 0 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 16 FORMULAS Ionic Binary Compounds Aluminum Oxide 3+ 2- Al2O3 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 17 NAMING Ionic BinaryCompounds Mg3N2 ide Magnesium Nitrogen Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 18 Practice Page 223 1. Write formulas for the binary ionic compounds formed between the following elements: a. potassium and iodine b. magnesium and chlorine c. sodium and sulfur d. aluminum and sulfur e. aluminum and nitrogen 2. Name the binary ionic compounds indicated by the following formulas: a. AgCl e. BaO b. ZnO f. CaCl2 c. CaBr2 d. SrF2 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 19 FORMULAS Ionic Compounds with Transition Metals Iron (III) Chloride 3+ (3+ x - x ) + (1 1 1- 3 )=0 FeCl3 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 20 FORMULAS Ionic Compounds with Transition Metals Tin (II) Oxide 2+ (2+ x - x ) + (2 1 2- 1 )=0 SnO Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 21 FORMULAS Ionic Compounds with Transition Metals Tin (II) Oxide 2+ 2- SnO Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 22 Practice Page 225 1. Write the formula and give the name for the compounds formed between the following ions: a. Cu 2+ and Br − d. Hg 2+ and S 2− b. Fe 2+ and O 2− e. Sn 2+ and F − c. Pb 2+ and Cl − f. Fe 3+ and O 2− 2. Give the names for the following compounds: a. CuO c. SnI4 b. CoF3 d. FeS Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 23 NAMING Ionic Compounds with Transition Metals PbO ( 2+ x 1 ) + ( 2 - x 1 ) = 0 Lead II Oxygen ide Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 24 FORMULAS Ionic Compounds with Polyatomic Ions Ammonium Sulfate + (1+ x 2 ) + (2- x 2- 1 )=0 (NH4)2SO4 Parenthesis are needed if the p. ion has a subscript from the crossed charge – outside the ( ). Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 25 NAMING Ionic Compounds with Polyatomic Ions Ca(NO3)2 Calcium Nitrate Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 26 Practice Page 227 1. Write formulas for the following ionic compounds: a. sodium iodide e. copper(II) sulfate b. calcium chloride f. sodium carbonate c. potassium sulfide g. calcium nitrite d. lithium nitrate h. potassium perchlorate 2. Give the names for the following compounds: a. Ag2O b. Ca(OH)2 c. KClO3 d.NH4OH e. Fe2(CrO4)3 f. KClO Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 27 Writing Fomulas and Naming Molecular Compounds Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 28 Prefixes for Covalent p. 228 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 29 Molecular Compound Formulas 1. Write the symbols. 2. Use prefixes for subscripts. 3. DON’T reduce. Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 30 Names Molecular Compound 1. Write the name of the elements. – Order: Smaller group number first; – Same group? Greater period number first. 2. Add –ide to the second element. 3. Add prefixes to each element for the number of atoms. Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 31 FORMULAS Binary Molecular Compounds Disulfur difluoride S2F2 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 32 NAMING Binary Molecular Compounds di nitrogen tetra oxygen ide Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 33 Practice Page 229 1. Name the following binary molecular compounds: a. SO3 b. ICl3 c. PBr5 2. Write formulas for the following compounds: a. carbon tetraiodide b. phosphorus trichloride c. dinitrogen trioxide Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 34 Acids and Salts • Acids – Chapter 14 • Binary Acids – two elements; hydrogen and one other element • Oxyacids – contain hydrogen, one other element and oxygen • Acid – a solution of the compound in water. Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 35 Acids and Salts • Salt – an ionic compound • Made from – the cation of a base and – the anion of an acid • Some retain an H in the anion – Example: CO3 2- carbonate HCO3 1- hydrogen carbonate or bicarbonate Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 36 Salt Definition Animation p. 230 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 37 List of Acids p. 230 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 38 Section 1 Homework Section Review Page 231 #1-5 Ch 7 Sec 1 Chemical Names & Formulas pages 219-231 39