Unit 1: The Chemical Basis of Life Refresher from Chem 20 1. Atoms: All matter has mass and takes up space All matter is composed of atoms Atoms are composed of three particles: Proton (+) Neutrons (no charge) Electrons (-) 1. Atoms: Nucleus of the atom is made of protons and neutrons Number of protons and electrons in an atom are the same making the charge neutral Electrons circle the nucleus at different energy levels to form an energy cloud 2. Elements An element is a substance composed of only one type of atom Every atom in the element has the same number of protons Isotopes occur when atoms of the same element have a different number of neutrons 3. Molecules Molecule: when atoms join with other atoms of the same or different elements Stable molecules are created when outermost energy levels are completely filled Covalent Bonds: the forces involved in the sharing of electrons to fill up an energy level 3. Molecules Bonds are held together by energy and when broken that energy is released Weakest chemical bond is hydrogen because it has only one electron 4. Compounds Compounds: substances composed of different kinds of atoms chemically bonded together There are two main types of compounds: Inorganic compounds Organic compounds 4. Compounds Inorganic Compounds: contain no carbon Only a single carbon atom per molecule Contain energy that is not useful for organisms 4. Compounds Organic compounds: Built with long carbon-to-carbon chains Large molecules containing stored energy Energy can be used by organisms Ex: CHO’s, Proteins, Lipids 5. Chemical Reactions Chemical Reaction: results from rearranging atoms and molecules of the materials involved Ex: burning wood adds oxygen to the wood substances 5. Chemical Reactions Reactions can be written as chemical equations Reactants: beginning substances Products: end of reaction Law of Conservation of Mass: same number of atoms at the beginning and the end of a reaction Energy is either required or produced when a reaction occurs 6. Ions Ions: atoms that gained or lost electrons have an imbalance of charged particles Positive Ions: atoms that donate electrons have an excess of positive charge Negative Ions: atoms that accept electrons have an excess of negative charge Ionic bonds form when electrons are transferred 7. Acids and Bases Water is made of 2 H atoms and 1 O atom A hydrogen atom breaks away from water molecule: Positive hydrogen ion Negative hydroxide ion Neutral solutions have the same number of hydrogen and hydroxide ions 7. Acids and Bases Water is made of 2 H atoms and 1 O atom A hydrogen atom breaks away from water molecule: Positive hydrogen ion Negative hydroxide ion Neutral solutions have the same number of hydrogen and hydroxide ions 7. Acids and Bases Acids: concentration of hydrogen ions > concentration of hydroxide ions Have a sour taste... Lemon juice Basic: concentration of hydroxide ions > concentration of hydrogen ions Ammonia, soap, oven cleaner pH scale 1-14 1-6 Acids 7 Neutral 8-14 Basic Carbohydrates These are composed of carbon, hydrogen, and oxygen with the ratio of H:O=2:1 Monosaccharides (C6H12O6) are called simple sugars because they are made of only one sugar unit. Glucose is formed by plants during photosynthesis and is the form of energy most easily used by cells. Monosaccharaide’s link together to form other types of sugars Carbohydrates Disaccharides (C12H22O11 ) are called double sugars because they are formed when two monosaccharides join together. Sucrose is made when a glucose and a fructose are joined together. Whenever monosaccharides link together, a molecule of water is released. This is called a dehydration reaction. Polysaccharides (C6H12O6)n are called many sugars because they are formed when three or more monosaccharides are linked together. 4 calories per gram How to Identify Carbohydrates Only carbon’s, hydrogen’s, and oxygen’s 2. Twice as many H’s as O’s 3. Dehydration reaction has H2O as a product 4. Hydrolysis reaction has H2O as a reactant 5. The names end in ‘ose’ Lab Tests: 6. Benedict’s solution changes from blue to a variety of other colors to indicate percentage of sugar 7. Iodine turns blue black to indicate starch 1. Examples of Charbohydrates Glucose Sucrose Starch Cellulose Glycogen Chitin Diagrams of Charbohydrates Proteins These are composed of carbon, hydrogen, oxygen, and nitrogen ( and sometimes sulphur) Built from a combination of twenty subunits called amino acids The long chains (thousands of subunits) are called polypeptide Green plants can synthesize all amino acids from simple materials Animals cannot so they must get them from their diet Proteins The particular combination of amino acids and the 3D folded shape it forms determines the function of the protein. Important in living organisms because each type of chemical reaction is controlled by a different type of enzyme, which is formed from proteins Enzymes are complex proteins that cause a specific chemical change in all parts of the body. The production of many different enzymes makes thousands of chemical reactions 4 Calories per gram How to Identify Proteins Must contain ‘N’ 2. Sometimes contains ‘S’ 3. Most labeled molecules end in ‘ine’ Lab Test: 4. The Bluret Test indicates peptide bonds when color changes from blue to pink purples 1. Examples of Proteins hair Webs Nails Scabs Steak (animal flesh) Blood cells Milk whey Enzymes Silk hormones Diagrams of Proteins Lipids These are oily or waxy substances that are composed of carbon, hydrogen, and oxygen but the ratio of H:O is always greater than 2:1 Fats are made of two types of lipid building blocks: Glycerole which is a single sugar Fatty acids which are chains of carbon and hydrogen with an acid grouping on one end Different fatty acids produce different lipids. Lipids Lipids can be grouped into: Fats (animals) Oils (plants) Waxes (animals & plants) Generally fats are used as a concentrated source of stored energy but can also be found in cell membranes and as cushions around body organs. How to Identify Lipids Only carbon’s, hydrogen’s, oxygen’s but more than double H’s than O’s 2. Several carbons with double bonds Lab Test: 3. Sudan IV solution identifies most lipids with a color change from pinks to reds 4. Translucence test indicates lipids by making untreated paper to transmit light 1. Examples of Lipids Fats: Margarine Butter Lard Blubber Oils: Canola oil Flax oil Vegetable Oil Waxes: Bee wax Ear wax Cuticle on leaves Diagrams of Lipids Nucleic Acid Another important group is nucleic acids (DNA, RNA) They are part of chromosomes and the reading of chromosomes