Energy, Environment, and Industrial Development Frederick H. Abernathy Michael B. McElroy Lecture 10 March 9, 2005 2 © Science A 52 FHA + MBM Estimate for carbon incorporated globally in trees 3x109 tons C yr-1 How many people could this support at utilization rate in 1800 New England? About 0.7 billion (3x109/4.1) Current global consumption of carbon in fossil fuel is about 6x109 ton C/yr, roughly twice the carbon potentially available from trees But, large amount of energy required to harvest the trees. Plus transportation and seasoning 3 © Science A 52 FHA + MBM What is the better economic choice, to grow food or timber? Timber is sold in units of board feet 1 board foot = 1 foot x 12 inches x 1 inch Assuming a density of 1 g cm-3, the mass of a board food is about 0.25 kg Price for softwood: $35~$305/1000 board feet; price for hardwood: $230~$580/1000 board feet Take $300/1000 board feet as average timber worth $1200/metric ton Rice costs $0.48/lb $1.10/kg $1100/metric ton It would appear that wood and food are comparable as investments! 4 © Science A 52 FHA + MBM Wood in English History A Forest Journey, John Perlin, Harvard Univ. Press, 1991 England was industrially relatively backward in early 1500s. Henry VII built only four ships for the Royal Navy during his reign (14851509) Imported salt, iron, dyes, glass and arms from continent Change in 1530s. Concern about Spanish/French intention to depose Henry VIII (1509- 1547) Development of arms industry in Sussex. England is forefront of arms race to 1550 To produce 1 ton of bar iron required 48 cords of wood. Beginning of English deforestation © Science A 52 FHA + MBM 5 Wood in English History A Forest Journey, John Perlin, Harvard Univ. Press, 1991 Prior to Elizabeth I, England’s ships were mostly made elsewhere or were hired. Elizabeth took steps to promote domestic industry. Subsidies for large ships, fishing, policies on wine importation To build a large warship took 2000 oaks which had to be more than 100 years old. Increased wood demands for iron, copper, glass, construction. Wood becomes scarce. James I prescribes permissible uses of timber (houses, glass etc) English reach to Ireland for new sources of wood Great fire of London, 1666 6 © Science A 52 FHA + MBM Wood in English History A Forest Journey, John Perlin, Harvard Univ. Press, 1991 John Houghton proposed a strategic timber reserve: “in times of peace, enough might be laid up for war and I believe that once a tenyear store was gotten, we never need fear the want of timber…when we are so prepared, we need care for nobody” Growth in use of wood for rail carriages, mining, canal building, mills, water wheels Abraham Darby develops method to use coked coal rather than charcoal for metal smelting. First coal-fired iron furnace in 1754 England moves from wood to coal age 7 © Science A 52 FHA + MBM Diamond’s view of factors that can lead to the collapse of a society Collapse, Jared Diamond, 2005, Viking Penguin, member of Penguin Group 1. Damage people inadvertently inflict on their environment 2. Climate change 3. Hostile neighbors 4. Decreased support by friendly neighbors 5. Society’s response to problems 8 © Science A 52 FHA + MBM 9 © Science A 52 FHA + MBM 10 © Science A 52 FHA + MBM 11 © Science A 52 FHA + MBM http://www.efunda.com/Materials/water/steamtable_sat.cfm 12 © Science A 52 FHA + MBM http://www.keveney.com/newcommen.html © Science A 52 FHA + MBM 13 14 © Science A 52 FHA + MBM 15 © Science A 52 FHA + MBM What was the maximum possible efficiency of the Newcomen engine (or more properly that of the Watt modification)? Consider a cylinder of length L, cross-section S Suppose that the cylinder must be filled with steam to a pressure of 1 atm First calculate the mass of H2O corresponding to this steam The Perfect Gas Law: P = NRT N = P/RT = 1atm / (8.31 J mol-1K-1 * 373K) = 1.013x105 Pa / (8.31 J mol-1K-1 * 373K) = 32.68 mol/m3 Mass of H2O = N * L* S * 18g/mol = 588.23LS (gram) 16 © Science A 52 FHA + MBM What was the maximum possible efficiency of the Newcomen engine (or more properly that of the Watt modification)? Then calculate heat required to produce this steam Heat required = heat to raise water from 293K to 373K + latent heat of evaporation Q = (558.23LS)g * 4.8 J K-1g-1 * (373-293)K + (588.23LS)g * 2500J/g = 1.56x106 LS (Joule) Work done in one stroke of engine W = 1atm * S * L = 1.013x105 LS (Joule) Efficiency = 1.013x105 LS / (1.56x106 LS) = 6.5% 17 © Science A 52 FHA + MBM Calculate the energy required to raise 100 gallons of water by 100 ft. E = mgh m = density * volume = 1 g/cm3 * 100 gallons * 3785 cm3/gallon = 3.785x105 gram = 3.785x102 kg h = 100 ft = 100 ft * 0.305m/ft = 30.5 m E = 3.785x102 kg * 9.8 m/s2 * 30.5m = 1.13x105 J 18 © Science A 52 FHA + MBM Calculate the power required to raise 100 gallons of water by 100 ft per minute E = mgh = 1.13x105 J power = 1.13x105 J / min = 1.13x105 J / 60 sec = 1.89 x 103 W = 2.53 horse power (1 hp = 746 Watts) 19 © Science A 52 FHA + MBM Major Players in the Steam Revolution Thomas Savery (1650-1715) awarded a patent in 1698 for “ the sole exercise of a new invention by him invented, for raising water, and occasioning motion to all sorts of mill works, by the important force of fire, which will be of great use for draining mines, serving towns with water, and for the working of all sorts of mills, when they have not the benefit of water nor constant winds; to hold for 14 years; with usual clauses”. Thomas Newcomen (1663-1729) had to work with Savery Newcomen’s first full scale engine delivered to Earl of Dudley’s colliery in 1712 James Watt (1736-1819). Met John Robison (17391805) in 1756. Important relationship with Joseph Black – “ pneumatic chemist” 20 © Science A 52 FHA + MBM Major Players in the Steam Revolution Began experimenting with Newcomen model in 1764. Hit on idea for separate condenser in 1765 Met Matthew Boulton (1728-1809) and had a tour of the Soho works in Birmingham in 1767 Watt obtained patent for his “fine engine” with separate condenser, 5 January 1769. “New method of lessening the consumption of steam and fuel in fire engines” 1773, Boulton acquires 2/3 share of patent from Roebuck 1774 Watt moved to Birmingham Boulton and Watt go into business in 1775 Patent extended to 1800 by act of Parliament in 1775 © Science A 52 FHA + MBM 21 Major Players in the Steam Revolution John Fitch (1743 – 1798) Frontiersman – escapes death from Delaware Indians Held captive by British in Detroit Heard about steam engine in New Jersey and had the idea to use steam to drive boat Partnership with German born clockmaker Henry Voight – the steamboat company funded in Philadelphia with $300 Made working model with 3” cylinder with piston driven by steam on both sides (1786) Monopoly licenses for Delaware (Feb. 3, 1787), New York (March 9, 1787), Pennsylvania (March 28, 1787) 22 © Science A 52 FHA + MBM Major Players in the Steam Revolution Demonstrated boat during Constitutional Convention in Philadelphia (August, 1787) Difficulty raising money Built 60’ boat with 8’ beam. Original arrangement of tubes in 18” cylinder. Propelled by paddleboards in rear Successful launch, April 16, 1790 – 76 stroke a minute Began ferry service. Traveled Philadelphia to Trenton (38 miles) in 1 ½ hours Service economically unsuccessful John Stevens (1749 – 1838), Aaron Vail French patent. Travels to France, spring 1793. Unable to buy engine from Boulton / Watt Returned to US. Suicide at age 55 by ingesting 23 opium pills prescribed for insomnia © Science A 52 FHA + MBM Major Players in the Steam Revolution John Stevens (1749 – 1838) – Mr. Stevens Robert Livingston (1749 – 1813), brother-inlaw of Stevens – congressman, judge, diplomat Livingston had Fitch’s 20 year license for the Hudson transferred to him Livingston – Stevens – Nicholas I. Roosevelt alliance. Polacca made 3 miles before boiler sprung a leak (March 1799) Alliance between Livingston and Fulton forged at dinner party in Paris, March 1802 24 © Science A 52 FHA + MBM Robert Fulton (1765 – 1815) Born in Lancaster, Pa Shady early years. Moved to London, summer 1786 Accepted patronage of Viscount Courtenay, later Earl of Devon. Began his career at inventor developing a mechanical saw Work on canals Moved to Paris, 1797. Invented a submarine and a torpedo Meeting with Livingston at Barlow’s house Fulton studies plans of everyone who had tried previously to make steam boat (Rumsey, Stevens). Ambition to design a large boat that would be profitable on the Hudson and Mississippi. 25 © Science A 52 FHA + MBM Robert Fulton (1765 – 1815) Thought of using board-like oars on chain running from bow to stern. Switched to wheels Partnership with Livingston signed October 10, 1802. Commitment to build 120’x8’ boat to carry passengers from Albany to New York Prototype built in France. Successful demonstration August 9, 1803 Livingston negotiated the Louisiana purchase with Napoleon (565x106 acres) and returned to New York Fulton went to London May 1804. Working with Royal Navy. To New York, December 1806 Demonstration voyage of the Clermont to Albany, August 17, 1807 Five years later, Fulton operated services on the Hudson, Delaware, Potomac, James, Chesapeake, 26 Mississippi, and Ohio © Science A 52 FHA + MBM Robert Fulton (1765 – 1815) Set up Nicholas Roosevelt to build steamboat to travel all the way from Pittsburg to New Orleans. The New Orleans left Pittsburg, October 1811. Overcame New Madrid earthquake, Indian Raid. Arrived in New Orleans, January 12, 1812 – 259 hours at 8 mph. January 1815. Fulton defended his precedence in use of side wheels by producing a letter he said he wrote to Lord Stanhope in 1793. Watermark showed 1796! Saved by his Irish lawyer, Thomas Addis Emmet. Died of pneumonia, February 23, 1815 27 © Science A 52 FHA + MBM