Periodic Table Groups 1. Color-code the following groups on your periodic table: -alkali group -alkaline group - transitional group -halogen group -noble gases -inner transitional group 2. Add the staircase (separates metals/non-metals.) 3. Place an asterisk by each metalloid. 4. Non-metals groups: Which group is most reactive and which is most stable? Explain how you know this. 5. Metal groups: Which group is most reactive and which is most stable? Explain how you know this. 6. Give an example of two elements that will form an ionic bond to reach stability. 7. Give an example of two elements that will form a covalent bond to reach stability. 8. What does each period on the periodic table symbolize for an atom? 9. What period and group is Bromine in? 10. a. What is electronegativity? b. What is the trend in electronegativity across a period and down a group on the periodic table. Chem II-Block: 9.2.14 Infinite Campus: • Scientific Skills and Matter Exam (53pts.) Avg.= 73% Objectives: • Periodic Table Organization and Trends • Classify and Name Compounds (Nomenclature) Homework: • Review polyatomic ions (quiz Thurs.) • Classifying compounds by their electronegativity differences. Bell Ringer: Periodic Table Check-up • Use your homework (Periodic Table Group)qts. and color-coded periodic table to answer qts. Periodic Table Groups-homework(9.2) 1. Color-code the following groups on your periodic table: -alkali group -alkaline group - transitional group -halogen group -noble gases -inner transitional group 2. Add the staircase (separates metals/non-metals.) 3. Place an asterisk by each metalloid. 4. Non-metals groups: Which group is most reactive and which is most stable? Explain how you know this. 5. Metal groups: Which group is most reactive and which is most stable? Explain how you know this. 6. Give an example of two elements that will form an ionic bond to reach stability. 7. Give an example of two elements that will form a covalent bond to reach stability. 8. What does each period on the periodic table symbolize for an atom? 9. What period and group is Bromine in? 10. a. What is electronegativity? b. What is the trend in electronegativity across a period and down a group on the periodic table. Periodic Table Periodic Table Check-Up Periodic Table Chem II-Block: 9.3.14 Objectives: • Periodic Table Organization and Trends • Classify and Name Compounds (Nomenclature) Homework: • Chemical Nomenclature Quiz-Thursday • Classifying compounds by their electronegativity differences. Periodic Table Check-Up • Assess peers work, make changes where necessary. Periodic Table Applications 1. Pick a representative element and a transitional element from your periodic table and answer the following qts. for each: a. What group is it in? b. Using electron configuration, validate the number of valence electrons it has. c. Would it participate in ionic and/or covalent bonding? Explain your answer. 2. Of the two elements you chose, which do you predict would have a greater electronegativity? Explain your answer. Periodic Table Applications 1. Pick a representative element and a transitional element from your periodic table and answer the following qts. for each: a. What group is it in? b. Using electron configuration, validate the number of valence electrons it has. c. Would it participate in ionic and/or covalent bonding? Explain your answer. 2. Of the two elements you chose, which do you predict would have a greater electronegativity? Explain your answer. Chemical Nomenclature Electronegativity • Electronegativity: The degree of attraction one atom has towards another atom’s valence electron in a compound. O H H Electronegativity and Chemical Bonding •Do metals or non-metals have a greater electronegativity value? Chemical Nomenclature • Review with peers and place problems on Activ board we need to address: • • • • • • • • • • Covalent Compounds Nomenclature: Prefixes One Two Three Four Five Six Seven Eight Nine Ten Homework: Polar vs. Non-Polar • Distinguish between polar and non-polar compounds with a Venn diagram. • Classify each compound from the bell ringer as either ionic, polar, or non-polar by calculating their electronegativity differences. Electronegativity Values webassign.net Chemical Bonding : Electronegativity Difference Chem II-Block: 9.4.14 Due: • Chemical Nomenclature Packet • Polar vs. Non-Polar Bonds Wksht. Objectives: • Classify and Name Compounds (Nomenclature) • Predict chemical bonding using electronegativity • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Classify geometries of covalent compounds. (VSEPR theory) Homework: • Classification of compounds and chemical nomenclature quiz-tomorrow. Chemical Nomenclature Gallery Walk • Watch roman numerals and prefixes. Think about when you need them and when you don’t. • Drop charges when expressing final answer for chemical formulas. Types of Chemical Bonding Covalent Bonding Ionic Bonding Chemical Bonding Chem II-Block: 9.5.14 Infinite Campus: • Chemical Nomenclature Gallery Walk (10pts.) Objectives: • Chemical Compounds: classify/nomenclature-quiz • Predict chemical bonding using electronegativity. • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Identify geometries of covalent compounds. (VSEPR theory) • Classify covalent compounds as either polar or nonpolar. • Identify types of intermolecular forces. . Electronegativity and Bonding Complete the table below. Chemical Bond Electronegativity Difference (Use electronegativity Periodic table) Type of Bond Ionic Bonding (Lewis Dot Transfer) Metal (Lewis Dot) Al Non-metal (Lewis Dot) S Ionic Bonding (Lewis Dot Transfer) Molecular Structures: Lewis Dot Sharing Molecules CS2 CO2 N2 Lewis Dot Sharing Molecular Name Polar or NonPolar Bonds Chem II-Block: 9.8.14 Infinite Campus: • Chemical Nomenclature Quiz (26pts.)’ • Density Lab Report (25pts.) Objectives: • Chemical Compounds: classify/nomenclature-quiz • Predict chemical bonding using electronegativity. • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Identify geometries of covalent compounds. (VSEPR theory) • Classify covalent compounds as either polar or nonpolar. • Identify types of intermolecular forces. Bell Ringer: Chemical Bonding Chemical Formula CO2 CF4 Mg3N2 N2 FeO Classify Compound Lewis Dot Structures Chemical Name Chem II-Block: 9.9.14 Objectives: • Chemical Compounds: classify/nomenclature-quiz • Predict chemical bonding using electronegativity. • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Identify geometries of covalent compounds. (VSEPR theory) • Classify covalent compounds as either polar or nonpolar. • Identify types of intermolecular forces. . Nomenclature Quiz Density Lab Report Strengths: • Organization of data tables • Graphing data (hand-graph, calculator) • Analyzing group and class’s data Weaknesses: • Organization of lab report (headings) • Analysis section should be in paragraph form • Graph titles should be specific to experiment. • Use line of best fit to interpret data VSEPR Theory (Valence Shell Electron Pair Repulsion) liakatas.org Bell Ringer: Chemical Bonding Chemical Formula Lewis Dot Structure Molecular Structure Molecular Geometry Chemical Compounds Structure: Ionic Compounds 7.2 Crystalline Lattice • The orderly arrangement of ions produces beautiful crystalline structure. Covalent Compounds: Crystal Lattice • Attraction between each molecule (covalent compounds). • What is that force called between molecules? o o C C o o C http://iscience.ru/wp-content/uploads/2008/12/sugarmolecule-02.jpg C http://www.michigansugar.com/images/ag/production/th_me d_crystals.jpg Bell Ringer: Chemical Bonding Chemical Formula Lewis Dot Structure Molecular Structure Molecular Geometry Molecular Geometry • Shape of the molecule in 3-D space. • VSEPR Theory: -(Valence Shell Electron Pair Repulsion) -How bonds and lone pairs are arranged around atoms to minimize electron repulsion. VSEPR Theory (Valence Shell Electron Pair Repulsion) liakatas.org Molecular Geometry Molecules Molecular Structure Molecular Geometry Name; Bond Angle CBr4 PH3 SiS2 Using the VESPR hand-out classify the geometries and bond angles for each molecule from your homework/bell ringer Covalent Compound Questions 1. What does the VSEPR acronym stand for? 2. How is VSEPR theory applied to covalent compounds? Explain for full credit. 3. What are molecular orbitals? Covalent Compound Questions 1. What does the VSEPR acronym stand for? 2. How is VSEPR theory applied to covalent compounds? Explain for full credit. 3. What are molecular orbitals? Chem II Homework: due 9.8.14 • Using the VESPR hand-out classify the molecular geometry and bond angle of each of your molecules from your packet. • Distinguish between sigma and pi bonds within a molecule. Give an example of a molecule that has both a sigma and pi bond. • • Identify, define, and give an example of the three classes of intermolecular forces that exist between molecules in the solid and liquid state. Chem II-Block: 9.11.14 Objectives: • Chemical Compounds: classify/nomenclature-quiz • Predict chemical bonding using electronegativity. • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Identify geometries of covalent compounds. (VSEPR theory) • Classify covalent compounds as either polar or nonpolar. • Classify the type of bonds between atoms. (sigma/pi) • Identify types of intermolecular forces. . Bell Ringer: Chemical Bonding Chemical Formula Lewis Dot Structure Molecular Structure Molecular Geometry VSEPR Theory (Valence Shell Electron Pair Repulsion) liakatas.org Drawing Molecular Structures 1.Draw Lewis Dot Structure for each element. 2.Calculate the total number of ve- for the molecule . 3.Share unpaired ve- with atoms. (covalent bonds) 4.Place lone pairs around appropriate atoms. 5.If an atom is not stable, then lone pairs can be used to reach maximum stability. 6.There are some exceptions to Octet Rule • Elements with d-orbitals • Molecules with an odd number of ve- (total) Molecular Structures Lab Molecular Orbitals • When ve- are shared between two atoms in a molecule, their atomic orbitals overlap. • The overlap of atomic orbitals between two atoms create molecular orbitals. • Each molecular orbital is also called a bonding orbital because it represents the sharing of two ve- between two atoms. • Two types of bonding orbitals: Sigma and Pi Molecular Orbitals wikis.lawrence.edu Bonding Orbitals chemistryland.com Molecular Geometry • Using the VESPR hand-out and the molecular model kit, classify each of these molecules. Molecules Molecular Structure Molecular Geometry Name; Bond Angle Type of Bonds (Sigma/Pi) NCl3 Trigonal pyramidal sigma CBr4 Tetrahedral sigma CH4 Tetrahedral sigma PF3 Trigonal pyramidal sigma In addition: CO , SiCl , SBr , N , C H 2 4 2 2 2 2 Homework 1. Draw the molecular structure of the following molecules: a. SiCl4 b. SBr2 c. d. *BF3 *d. SO3 *(bonus) b. Determine the molecular geometry (shape) of the molecules above including bond angles. 2. a. Illustrate the difference between sigma an pi of bonding orbitals. b. Classify the bonding orbitals in the following molecules. -CH4 tetrahderal; sigma bonds - N2 linear; sigma and 2 pi bonds - C2H2 linear; 3 sigma and 1 pi bond Chem II-Block: 9.12.14 Due: • Polar vs. Non-Polar Molecules: (CH4 and CCl4) • Intermolecular Forces between molecules. Objectives: • Chemical Compounds: classification/nomenclature. • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Assess type of bonds(sigma/pi) and polarity of bonds. • Identify geometries of molecules. (VSEPR theory). • Classify molecules as either polar or non-polar. • Predict the type of intermolecular forces that exist between molecules in the solid and liquid state. . Polar Molecules • Polar molecules: One end of the molecule is partially positive and the other end is partially negative. • Also called dipole molecules. • Draw the following molecular structures: CH4 and CF4 Polar or Non-Polar Molecules? P 3dchem.com Assess type of bonds (sigma/pi) andF polarity of bonds. F en.wikipedia.org ieshermanosbilingual.blogspot.com F Polar vs. Non-Polar Molecules Polar Molecules Non-Polar Molecules Polar vs. Non-Polar Molecules • Classify your molecules as either polar or non-polar molecules. Chem II-Block: 9.16.14 Infinite Campus: Molecule Lab (16pts) Objectives: • Chemical Compounds: classification/nomenclature. • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Assess type of bonds(sigma/pi) and polarity of bonds. • Identify geometries of molecules. (VSEPR theory). • Classify molecules as either polar or non-polar. • Predict the type of intermolecular forces that exist between molecules in the solid and liquid state. . Intramolecular Forces . Intermolecular Forces Types of Intermolecular Forces • Identify and define the types of intermolecular forces that can exist between molecules in the liquid and solid state. • Give an example of a molecule that applies each type of intermolecular force when in the solid and liquid state. Intermolecular Forces itl.chem.ufl.edu Types of Intermolecular Forces 1.Dipole Forces : Prentice Hall: Chemistry Types of Intermolecular Forces 1.Dipole Forces : • Attraction b/w polar molecules • Partial charges oppositely attract Prentice Hall: Chemistry Types of Intermolecular Forces Hydrogen Bonds : http://employees.csbsju.edu/hjakubowski/classes/Chem%20 and%20Society/IMF_Solutions/olIMF_solutions.htm Types of Intermolecular Forces Hydrogen Bonds : • Very strong dipole force. Pre-resquiste for H bonding to occur: • H must be covalently bonded to a very electronegative element (N, O, F). Types of Intermolecular Forces • 3. London Dispersion Forces: I I elmhurst.edu Chem II-Block: 9.17.14 Objectives: • Chemical Compounds: classification/nomenclature. • Illustrate ionic and covalent bonding using Lewis Dot Structures. • Assess type of bonds(sigma/pi) and polarity of bonds. • Identify geometries of molecules. (VSEPR theory). • Classify molecules as either polar or non-polar. • Predict the type of intermolecular forces that exist between molecules in the solid and liquid state. Homework: Test on Friday-will not meet tomorrow. . Types of Intermolecular Forces • 3. London Dispersion Forces: • Caused by randomn motion of electrons in an atom. • Occur in non-polar and polar molecules. • Temporary and dynamic dipole forces between atoms. • Use the data below to explain what influences the strength of dispersion forces? *States of Matter: Diatomic Molecules solid I2 liquid Br2 *At Room Tempearatue gases F2; Cl2 elmhurst.edu Intermolecular Forces Molecular Formula CS2 NH3 OCl2 Polar or Nonpolar Molecule Intermolecular Forces Molecular Name Gallery Walk: Chemical Bonding Review