Going with the Trends: PERIODIC TRENDS Concept Presentation Andrew Selvam – HS Chemistry OISE/UT Instructors: Janine Extavour/Marty Zatzman Outline of Presentation • • • • • • • • Curriculum Expectations What do I need to know before? Where does the concept fit? Roadblocks and Misconceptions for Teachers and Students (incl. Solutions and Activities) Lesson Sequence (incl. Accommodations and A&E) Applications to Real World Period Trends War Game References Curriculum Expectations (Ontario Ministry of Education) SPECIFIC EXPECTATIONS A1.5 Conduct inquiries, controlling relevant variables, adapting or extending procedures as required, and using appropriate materials and equipment safely, accurately, and effectively, to collect observation and data. A1.6 Compile accurate data from laboratory and other sources, and organize and record the data using appropriate formats, including tables, charts, graphs, and/or diagrams A1.10 Draw conclusions based on inquiry results and research findings, and justify their conclusions with reference to scientific knowledge. Curriculum Expectations (Ontario Ministry of Education) B1.1 Analyse, on the basis of research, the properties of a commonly used but potentially harmful chemical substance and how that substance affects the environment, and propose ways to lessen the harmfulness of the substance or identify alternative substances that could be used for the same purpose. B2.1 Use appropriate terminology related to chemical trends and chemical bonding, including, but not limited to: atomic radius, effective nuclear charge, electronegativity, ionization energy, and electron affinity. B2.2 Analyze data related to the properties of elements within a period (e.g., ionization energy, atomic radius) to identify general trends in the periodic table Review Items • Grade 9 and 10 Science – The Atom • Composition of the Atom • Subatomic Particle – Formation of Ions F – Periodic Table • Elements • Features – Atomic Number and Atomic Mass • Periods (Rows) and Groups (Columns) of elements with similar properties F F1- The Unit • Periodic Trends is part of the first unit of SCH 3U • Integral for students to understand the molecular/atomic basis for the formation of compounds and the reaction of those compounds (later in the unit) Chapter 1 Observing Matter Chapter 2 Elements and the Periodic Table Chapter 3 Chemical Compounds and Bonding Chapter 4 Classifying Reactions: Chemicals in Balance Placement of Concept in the Chapter • The placement of the concept of the unit fits appropriately in the context of the chapter • Both McGraw-Hill and Nelson texts place the concept in the following way: Atoms, Elements and the Periodic Table Periodic Trends (Involving the Sizes and Energy Levels of Atoms) Classifying Chemical Compounds (Ionic vs. Covalent) Why do you think this is? The Concept Atomic Radius Ionization Energy Effective Nuclear Charge PERIODIC TRENDS Electron Affinity Shielding Effect Electronegativity Reactivity The Trends in Picture Major Roadblocks for Teachers Teachers have a two-fold problem when it comes to teaching periodic trends: 1. Explaining (as opposed to simply memorizing) the subatomic basis for all five trends • • • • • Atomic Radius (Ionic Radius) Ionization Energy Electron Affinity Electronegativity Reactivity of Metals and Non-Metals 2. Looking for ways to help students retain and review the knowledge of Periodic Trends Misconceptions for Students ROADBLOCK #1 • Visualizing attractive and repulsive forces between nucleus and electrons ROADBLOCK #2 • Understanding that the nucleus can have an ‘effective nuclear charge’ and that inner-level electrons can shield the nucleus from outer-level electrons Ryan Seacrest shows Effective Nuclear Charge with his smile! The Solution to Misconceptions 1 and 2: The Analogy with Atomic Radius • Ryan Seacrest = Nucleus • Mouthwash = Effective Nuclear Charge • Ladies = Electrons Using Desks in Your Classroom Teacher’s Desk = Nucleus = Electron ROADBLOCK #3 Each periodic trend is really its own separate concept. None of them are interconnected. Visual: Across a Period… Na Mg 11P 12N 12P 12N H Li Be Na Mg Na Mg 11P 12N 12P 12N IONIZATION ENERGY - It requires more energy to pull electrons that have been tightly held by the nucleus, therefore across a period, the ionization energy increases ATOMIC RADIUS - Adding one proton increases the charge of the nucleus to pull the electrons towards them, therefore across a period, the atomic size decreases ELECTRON AFFINITY/ ELECTRONEGATIVITY - Because the electrons are being tightly held by the nucleus, therefore across a period, electron affinity and electronegativity increases. Visual: Down a Group… Li Na 3P 4N 11P 12N H Li Be Na Mg Li Na 3P 4N 11P 12N IONIZATION ENERGY -It requires less energy to pull electrons that are not tightly held by the nucleus, therefore down a group, the ionization energy decreases ATOMIC RADIUS - Going down a period, there are additional energy levels to add to the size of the atom, thus the atomic radius increases ELECTRON AFFINITY/ ELECTRONEGATIVITY - The electrons are not being as tightly held by the nucleus, therefore across a period, electron affinity and electronegativity decreases. Each of you will receive two magnets: Here are your instructions: • Take a few minutes in pairs or in table groups to come up with a way to use the magnets to explain a periodic trend Now here is how you can use magnets to show some of the periodic trends... Using Magnets for Ionization Energy • Take two magnets. The first magnet is the nucleus and the second magnet are the electrons in the outer shell. • When the magnets are close together – hard to pull them away from each other – requires more energy • When the magnets are already far apart, – it is easy to pull them further away, because of a weak force of attraction Lesson Day 1 Focus: Review of Atomic Composition and Atomic Structure Activities: - Chalk and Talk on Composition/Structure - Demo 1: Atomic Emission Spectra (Use Diffraction Gratings and Spectroscopes) - Demo 2: Metal Reactivity (With Alkali Metals) - Will Refer Back to Later in the Lesson Sequence Accomodations: For IEP/ELL students, provide them with tables that give them an idea of how the number of valence electrons relate to groups on the periodic table Assessment/Evaluation: Assessment for Grade 9 Review Items Formative Assessment – Metal Reactivity Demo Homework – Effective Nuclear Charge Demo: Observing the Spectra of Elements H2 He D2 Ne N2 O2 Ar Kr Hg Xe Demo: Metal Reactivity Li Na K Metal Reactivity increases as you move down the group. Safety Precautions for Demo • Lab not recommended for students as it can be quite violent • Metals like lithium, potassium, and sodium react violently with air and so are kept in a special mineral oil • If you have a shield, put this up to prevent injury or ask students to move back Lesson Day 2 Focus: Introduction to Periodic Trends Activities: - PowerPoint on Periodic Trends including Analogies - VAK Activities: - Magnet Analogy (Visual) - Classroom Kinesthetic Activity - Trends Exercise (Aural) (Students can pair together to try activities) - Discussion on Applications to the Real World Assessment/Evaluation: Diagnostic Questioning – Previous Day Learning Formative Assessment – Worksheet/Text Ques. Formative Assessment – Exit Pass Multiple Intelligences: Visual, Logical, Tactile, Interpersonal, Intrapersonal Lesson Day 3 Focus: Reinforcement of Periodic Trends Activities: - Periodic Trends War Game (We will do this at the end!) - Graphical Analysis of Periodic Trends - Atomic Radius vs. Atomic Number - Ionization Energy vs. Atomic Number Assessment/Evaluation: Formative Assessment – - Taking in Game Sheet for Periodic Trends War - Taking in Graphs to get proof of student understanding - Teacher will go around to help students one-on-one with activity Multiple Intelligences: Visual, Logical, Intrapersonal, Interpersonal Graphic Resource for Periodic Trends <http://www.teachersdomain.org/resource/l sps07.sci.phys.matter.graphperiodic/> Assessment & Evaluation: KICA Knowledge Questions that ask to find the element with the greatest or least atomic radius, ionization energy Inquiry Questions that ask students to explain the atomic basis for periodic trends Communication Graphical analysis of periodic trends Application Discussion on uses of elements based on their place in the Periodic Table Applications to the Real World • Medical (Surgical) – Because of the low reactivity of Tantalum (Ta) [bottom-left] of the PT, used in surgical sutures, pins, and implants • Cooking – Because fluorine is so reactive it reacts with another substance, and becomes very stable. Teflon used in pans is a combination of carbon and fluorine. More Applications... • Industrial – Tantalum oxide is used in camera lenses – Cesium (Cs) has a low ionization energy and is very reactive – It is used in TV cameras and traffic signals – Chlorine and bromine are used for sterilization (high reactivity) Periodic Trends War • This is an adaptation of the card game ‘war’, except instead of using playing cards, we will use index cards with an element on it • We will also use dice, where each face represents one of the trends: • • • • • • 1 – Atomic Radius/Ionic Radius 2 – Ionization Energy 3 – Electron Affinity 4 – Electronegativity 5 – Reactivity 6 – ‘Wild’ – Any of the trends above Periodic Trend War Cont’d Instructions: 1. Students get into groups of 3 or 4. Assign someone to be the dealer. 2. The dealer will roll the die. Each student in the group will reveal the element card from the top of their pile 3. It is now up to them to determine who wins the deal based on who has the greatest value based on the trend 4. The person who wins becomes the dealer Activity Assessment and Evaluation • Each student will get a game card • The student will document the name of the trend, the choices they had and the atom with the greatest value • At the end of class, students will hand the game card in as a formative assessment • The teacher now has a better understanding of whether the student knows the trend Potential Advantage: Peer Collaboration Potential Disadvantage: Peer Plagarizing Text References McGraw-Hill Chemistry 11 • Student Text and Teacher’s Resource Addison-Wesley Chemistry 11 •Teacher’s Resource Provides Suggestions for: • Common Student Misconceptions • Lesson Ideas for all Learning Styles • Accommodations for Identified / ELL Learners • Assessment and Evaluation • Possible Lab Investigations Journal Articles Montogomery, M. (2005). Periodic Table Trends. The Science Teacher, 72(4), 50-51. • This resource comes from a science teacher at a local highschool in Southaven, Mississippi. The author attempts to provide examples of how to demonstrate the trends of atomic radius, ionic radius, and ionization energy by reorganizing the desks in a classroom. He also tackles concepts such as the shielding effect. • Also goes into great explanations for ionic radii as well Websites Website: Howe, M., Krone, B., Reiter, S., and D. Verby. Chemistry as Fun and Games. <http://nobel.scas.bcit.ca/chemed2005/tradingPost/TUPM_S2_4_15C hemFunGames.pdf.> • Good resource for games that apply to concepts learned in Grade 11 and 12 Chemistry YouTube Videos – Periodic Trends Song <http://www.youtube.com/watch?v=MGTKVaZcq8Y> • Cheesy song for students who might enjoy learning in the musical genres of hip-hop and rap Don't forget me! Thanks for listening to my presentation! And thanks to Cora for all her support! If you ever thought periodic trends could not be cool, wait until you listen to this cheesy music video...