The Acid/Base Square: This square helps convert between [H+], pH, pOH, and [OH-] Example Calculations: a) What is the pH of a 0.050 M HNO3? Since we are dealing with an acid, we know the [H+]… pH = -log[H+] pH = -log[0.050] pH = 1.3 = acidic b) Find the hydroxide ion concentration of 3.010-2 M HCl. [H+][OH-] = 1.0 10-14 [3.0 10-2][OH-] = 1.0 10-14 [OH-] = 3.3 10-13 M = acidic c) What is the molarity of HBr in a solution that has a pOH of 9.6? pH + pOH = 14 H+ = 10-pH pH + 9.6 = 14 H+ = 10-4.4 pH = 4.4 [H+] = 3.98 10-5 M HBr = acidic pH Practice 1. Draw the pH scale, labeled 0-14. Identify where a solution is acidic, basic and neutral. 2. Calculate the pH of the following solutions. Identify the solution as acidic, basic or neutral. a) [H+] = 1.00 x 10-3 M b) [H+] = 1.00 x 10-10 M c) [H+] = 6.59 x 10-10 M d) [H+] = 9.47 x 10-3 M 3. Find the pH of each of the following solutions and identify them as acidic, basic or neutral. a) pOH = 2.00 b) pOH = 8.00 c) pOH = 1.263 d) pOH = 9.714 4. Calculate the pH of the following solutions and identify them as acidic, basic or neutral. a) [OH-] = 1.00 x 10-9 M b) [OH-] = 1.00 x 10-3 M c) [OH-] = 9.56 x 10-4 M d) [OH-] = 7.49 x 10-10 M 5. Find the pH and the [H+] of each of the following solutions and identify them as acidic, basic or neutral. a) pOH = 9.50 b) pOH = 3.65 c) pOH = 12.63 d) pOH = 1.14 pH, pOH, [H+], and [OH-] Calculations WS 1. 2. Calculate the pH and pOH for the following solutions: a) [H+] = 1.0 x 10-5 M d) [OH-] = 3.0 x 10-8 M b) [H+] = 2.5 x 10-2 M e) [OH-] = 7.5 x 10-3 M c) [H+] = 1.2 x 10-14 M f) [OH-] = 6.0 M Calculate the [H+] and [OH-] for the following solutions: a) pOH = 2.60 d) pH = 3 b) pOH = 5.63 e) pH = 7.51 c) pOH = 1.13 f) pH = 0.03 Directions: Fill in the missing information in the table below. pH [H+] pOH [OH-] 3.78 3.89 x 10-4 M 5.19 4.88 x 10-6 M 8.46 8.45 x 10-13 M 2.14 2.31 x 10-11 M 10.91 7.49 x 10-6 M 9.94 2.57 x 10-8 M 4.16 1.06 x 10-1 M 3.82 8.53 x 10-7 M 7.05 4.73 x 10-10 M 1.33 9.87 x 10-3 M 11.68 9.22 x 10-8 M 12.24 5.39 x 10-12 M Acid or Base?