Why Study Chemistry in Biology? I. Atoms Definition: smallest particle of an element B. Composition Subatomic Particle Charge Mass Location Proton +1 1 Nucleus Neutron 0 1 Nucleus Electron -1 1/1840 the mass of a proton Orbiting nucleus C. If Neutral Atom: # protons = # electrons II. Elements A. Definition: substance that cannot be broken down into other substances B. Biologically important elements i. Major: C H O N ii. Minor: Ca Fe Mg I Se P K Na Cl C. Symbol: usually from first letter or two of full name Elements Con’t. Mass Number Atomic Mass 12.0107 amu D. Atomic Number: # of protons in nucleus E. Atomic Mass / Mass Number ii. Atomic mass: count of the total number of protons and neutrons in an atom's nucleus F. Isotopes i. Definition: forms of the same element have same # of protons but different # of neutrons Mass Number ii. Radioactive isotopes: An isotope having an unstable nucleus that decomposes spontaneously G. Chemical Compounds i. Molecules definition: two or more atoms held together by COVALENT bonds ii. Compound definition: a substance containing two or more elements in a fixed ratio – Ex: H2O, NaCl Decoding Chemical Formulas?? C6H12O6 Element subscript is the NUMBER of ATOMS So in this molecule, there are 6 carbon atoms, 12 hydrogen, and 6 oxygen 2H2O • The number in front of H2O means two entire molecules of H2O • Think of it like 2 x (H20) • Sooooo… how many total atoms of H are there? • Of oxygen? • Atoms want to fill their outer energy levels to be • In order to do this, they will meet up with other atoms and either share or exchange electrons A. Covalent Bonds • Atoms share electrons so that both atoms fill their outer energy level B. Ionic Bonds: gimme that electron! • Atoms transfer electrons, becoming (+) or (-) charged • This attraction brings them together – Ex: Na and Cl i. Ions > An electrically charged atom Hydrogen Has 1 electron, needs 1 to fill its orbital Carbon Has 4 electrons in outer level, needs 4 more to fill its orbital Can form ONE bond Can form FOUR bonds IV. Water A. B. C. D. Human Composition: 65–90% water Plant Composition: 80-90% Formula: H2O Bonds: i. Hydrogen bonds: the slightly (+) H atoms are attracted to nearby (-) O atoms, and develop a weak bond. ii. Covalent bonds: are shared between oxygen and hydrogen in a single molecule. V. Water (con.’t) 5. Water is a polar molecule: i. Definition of polarity: molecule that has opposite electrical charges on opposite ends ii. Why? Oxygen does not share electrons equally- pulls them closer to itself, making it more negative and Hydrogen more positive V. Water (con.’t) F. Unique molecule: i. Cohesion: 1. Definition: molecules of same kind stick to one another 2. Example: Surface tension; trees transporting water from roots to leaves ii. Adhesion: 1. Definition: attraction that occurs between unlike molecules 2. Example: Water molecules and cotton string. iii. Solutions: 1. Water is able to dissolve other polar and ionic compounds when mixed by causing the ions to break away and surround them. Ex.: Salt Water 2. Suspensions a. Definition: A heterogeneous mixture in which particles settle out of solvent-like phase some time after their introduction b. Example: oil & water iv. Boiling Point: water will boil at 100C or 212F G. Acids and Bases i. A water molecule can react to form ions ii. An ion is when a molecule breaks down and the atoms get a charge 1. Example: H+ and OH- iii. pH Scale 1. How? Scale of 0-14; each pH unit represents a tenfold change in the concentration of H+ ions 2. Acid definition: pH 0-6 3. Base definition: pH 8-14 4. Buffer definition: substances that cause a solution to resist changes in pH.; works by accepting H+ ions when levels rise and donating H+ ions when levels fall, maintaining a constant pH a. Weak acid or base