Chapter 1 HW Solutions Ch 1.1 – 1.3 #2 A) solid B) gas C) liquid D) gas #4 A) homogeneous mixture B) heterogeneous mixture C) pure substance D) mixture (hetero vs. homo can’t be determined by visual inspection) #8 A) Be B) Cs C) F D) Mn E) As F) Xe G) P H) Sc #10 A) Barium B) Californium C) Molybdenum D) Selenium F) Vanadium H) Zirconium E) Thallium G) Gold #11 A is a compound – rationale CO2 produced B is probably compound because it is a white solid Ch1.4 – 1.6 #18a 2 1X10 m 1pm 9 6.5X10 cm 65pm 12 1cm 1X10 m or cm 10 m vs pm is 10 m -2 -12 - 2 - - 12 10 places move decimal 10 places to right 18b 1L 1L 3.35X10 mL .335L 6 1000mL 1X10 L -4 or mL 10 L vs L is 10 m -3 -6 - 3 - - 6 3 places move decimal 3 places to right 18 c, d, e 1mmol C) 2.5 10 mol 2.5 mmol 3 110 mol 3 1mm 3 D) 4.23 10 -12 m 3 .00423mm (1 10 -3 m) 3 1us -8 E) 12.5 10 s .125us -6 110 s 3 18 f, g 1kL F) 3.5 10 L 3.5kL 3 1 10 L 1 10 15 s 1us 9 G) 6.54 10 fs 6.54us 6 1fs 1 10 s 3 #20 1000g A) 2.52X10 kg X 2.52X10 6 g 1kg 3 1X10 -3 m 1nm 3 B) .0023mm X X 2.3X10 nm 9 1mm 1X10 m 3 1X10 ms -4 C) 6.25 X10 s X .625ms 1s #24 Vol = length3; density = mass/vol vol (1.5cm)3 3.375cm3 42.0g density 12g/cm3 3.375cm3 No, ruthenium is more dense than wate r so it will sink #27 Thickness=volume/area 1g 1cm 3 vol 200mg X X .0104cm 3 1000mg 19.32g 12 2 in 2 2.54 2 cm 2 3 2 area 2.4ftX1ftX X 2.2X10 cm 1ft 2 in 2 .01035cm 3 1X10 2 m 8 thickness X 4.6X10 m 2 2,230cm 1cm or 46nm thick CH 1.7 – 1.9 #34 A) 4 B) 3 C) ambiguous 5,6, or 7 D) 6 E) 6 #36 A) 1.44 X 105 B) 9.75 X 102 C) 8.90 X 105 D) 6.76 X 104 E) 3.40 X 104 F) –6.56 #38 A) -2.3 X 103 B) 8.260 X 107 C) 3.4 X 104 D) 7.62 X 105 #41 1000mL 76mL 1L or move decimal 3 places A).076L 1nm 50.nm -9 1 10 m or move decimal 9 places B) 5.0 10 -8 m -9 1 10 m C) 6.88 105 ns 6.88 10 -4 s 1ns kg 1000g 1m 3 1dm 3 D) 1.55 3 1.55g/L 3 m 1kg (10dm) 1L #43 a-d 1.609km 1000m A) 8.60mi 1.38 10 4 m 1mi 1km 24hr 60min 60 s B) 3.00days 2.59 105 s 1day 1hr 1 min $1.55 1gal 1.057qt $.410 C) gal 4qt 1L L 5.0pm 110-12 m 1ms -9 D) 5.0 10 m/s -3 ms 1pm 110 s #43 e & f 75.00mi 1.609km 1000m 1hr E) 33.52m/s hr 1mi 1km 3600s 3 3 (12in) (2.54cm) 6 3 F) 55.35ft 3 1.567 10 cm 1ft 3 1in 3 #45 4qt 1L A) 31gal 1.2 10 2 L 1gal 1.057qt 6mg 1kg B) 150lb 4 10 2 mg kg 2.205lb 254mi 1.609km 1gal 1.057qt 9.64km C) 11.2gal 1mi 4qt 1L 1L 50cups 1qt 1L 1000mL 1lb 26ml D) 1lb 4cups 1.057qt 1L 453.6g g Chapter 2 HW Solutions 2.1 – 2.3 A) B) C) #2 6.500 g compound - .384 g H = 6.116g S Conservation of Mass Atoms are not created or destroyed so if a compound has only H and S and .384 grams is H the rest must be sulfur #4 integer ratio indicates combining F units that are indivisible 55.0g F 2.37 gF 1.143 4 23.2g S 1gS .59 9.8g F .59 gF .59 1 16.6g S 1gS .59 68.6g F 3.55 gF 3.55 6 19.3g S 1gS .59 #5 Evidence that cathode rays were negatively charged was the electric and magnetic field deflected the ray the same way it would a negative charge and that the negative plate exposed to the cathode rays acquired a negative charge. #11 1 X 10 10 m 1nm 2.4Α.X X .24nm 9 1Α 1 X 10 m 1 X 10 10 m 1pm 2.4Α.X X 240pm 12 1Α 1 X 10 m 1m 1A 1Cr atom 7 1.0 cm X X X 4.2X10 atoms 10 100 cm 1 X 10 m 2.4A #14 A) 32P has 15 p, 17n, 15 e B) 51Cr has 24p, 27n C) 60Co has 27 p, 33 n Ch 2.4 – 2.5 #20 A) Lithium (metal) B) scandium (metal) C) germanium (Metalloid) D) ytterbium (metal) E) manganese (metal) F) gold (metal) G) tellurium (metalloid) #21 A) K, alkali metals (metal) B) I, halogens (nonmetal) C) Mg, alkaline earth metals (metal) D) Ar, noble gases (nonmetal) E) S, chalcogens (nonmetals) #23 An empirical formula shows the simplest ratio of the different atoms in a molecule. A molecular formula shows the exact number and kinds of atoms in a molecule. A structural formulas shows how these atoms are arranged. #26 A) 4 B) 6 C) 9 #28 See board A) Draw C2H5Br (1-bromo-ethane) B) Draw C2H7N ( dimethylamine) C) Draw CH2Cl2 ( dichloromethane) D) Draw NH2Cl (chloroamine) #30 A) SN B) C7H15 C) C3H5O D) P2O3 E) C3H5F4 F)SiO3 #32 A) Ba2+ B) La2+ or La3+ C) Ga3+ D) S2 E) Br #61 Symbol 52Cr3+ 130I- 107Ag+ 119Sn2+ 75As3- Protons 24 53 47 50 33 Neutron 28 77 60 69 42 Electron 21 54 46 48 36 Net 3+ charge 1- 1+ 2+ 3- Chapter 2.6 – 2.7 #38 Molecular (all atoms are nonmetals) c) SCl2 Ionic (formed by a cation and an anion, usually contains a metal cation)— a) Sc2O3 b) NaI d) Ca(NO3) 2 e) FeCl3 f) LaP g) CoCO3 h) (NH4) 2SO4 #39 A) ClO2 D) ClO4 B) ClE) ClO- C) ClO3- #42 A) silver sulfide B) barium phosphate C) magnesium chlorate D) strontium sulfite E) cobalt (II) bromide (cobaltous bromide) F) tin (II) iodide (stannous iodide) G) chromium (III) nitrate (chromic #42 continued H) zinc hydrogen phosphate (notice the lack of roman numerals—it has a definite charge of +2) I) silver perchlorate (notice the lack of roman numerals—it has a definite charge of +1) J) ammonium dichromate #44 A) Mg3N2 B) FeSO3 C) Cr2(CO3)3 D) CaH2 E) Mg(HCO3)2 F) KClO G) Cu(C2H3O2)2 #46 A) HBr B) H2SO3 C) HNO2 D) carbonic acid E) chloric acid F) acetic acid #48 A) dinitrogen monoxide B) nitrogen monoxide C) nitrogen dioxide D) dinitrogen pentoxide E) dinitrogen tetroxide #58 A) alkali metal – K B) an alkaline earth metal – Ca C) a noble gas – Ar D) a halogen – Br E) a metalliod – Ge F) a nonmetal in 1A – H G) a metal that forms a 3+ charge- Al H) a nonmetal that forms a 2- charge – O I) a metal that resembles Al - Ga #62 A) Nickel (II) oxide, 2+ B) Manganese (IV) oxide, 4+ C) Chromium (III) oxide, 3+ D) Molybdenium (VI) oxide, 6+ #63 Fe3S4 could be aq homo mixture where the Fe2+ and the Fe3+ ions are portions of the lattice structure #64 A) IO3 B) IO4 C) IO D) HIO E) HIO4 (or H5IO6) #67 A) potassium nitrate B) sodium carbonate C) calcium oxide D) hydrochloric acid E) magnesium sulfate F) magnesium hydroxide