Teaching First Year Chemistry Dr. Kim Bolton, School of Environmental Sciences My Background Soil and Water Chemist My First Year Experience Environmental Chemistry I and II Equivalent to standard two term 1st year chemistry course Environmental chemistry examples (acid rain, ozone depletion, photochemical smog, etc.) Lectures/labs Course no longer exists My Background My First Year Experience Introductory Chemistry Equivalent to grade 12 chemistry Distance education format No labs Chemistry Today Chemistry for non-science students (Hotel and Food Administration) No labs Environmental Chemistry I and II Text: Introduction to Environmental Chemistry, Nigel Bunce Objectives Introduction to chemical principles which govern chemical reactions in the environment Introduction to some specific problems in environmental chemistry Part I Part II Stoichiometry Acids and Bases Energetics in Chemical Reactions: Enthalpy Solubility Equilibria Gases and the Atmosphere Acid Rain Kinetics Energetics in Chemical Reactions: Free Energy Gaseous Equilibria Stratospheric Ozone Depletion Water Electrochemistry Metals and Mining Environmental Chemistry I and II Ways to engage students Use of quantitative environmental examples: Stoichiometry; eg) Calculate the maximum yield of sulphuric acid produced from 125 tonnes of pyrite. Thermochemistry; eg) Calculate the mass of methane that must be burned to heat a typical house in S. Ontario on a winter day when the total heat requirement is 6.7 x 105 kJ Photochemistry; eg) The C-Cl bond has bond dissociation energy 330 kJ mol-1, while CFCl3 absorbs radiation having λ < 220 nm. Will CFCl3 undergo bond cleavage in the lower atmosphere? Environmental Chemistry I and II Ways to engage students Use of quantitative environmental examples: Kinetics; eg) The degradation of the pesticide fenvalerate in the envionment is found to be first order with k = 3.9 x 10-7 s-1. An accidental discharge of 100 kg of fenvalerate into a holding pond results in a fenvalerate concentration of 1.3 x 10-5 mol L-1. Calculate the concentration left after one month. How long before the fenvalerate concentration in the pond reaches 1 μM? Free Energy; eg) Calculate the equilibrium constant for 3/2 O2(g) ↔ O3(g) and estimate O3 content in stratosphere. (then compare to actual content). Environmental Chemistry I and II Ways to engage students Specific Environmental Topics: Greenhouse Gases and Climate Change Photochemical Smog and Ground Level Ozone Water Hardness and Water Softening Laboratory; water hardness by titration with standard EDTA Biological Oxygen Demand (sewage and industrial waste water) Phosphate removal from sewage Acid Mine Drainage “Stories” Solubility; eg) Why do walls of the Welland Canal crumble? (CaSO4•H2O solubility) Metal toxicity; Copper complexation story Chemistry Today Text: Chemistry in Focus, Nivaldo Tro (Brooks/Cole) First half of course addresses general chemistry principles: Atoms and Elements Compounds and Chemical Reactions (a little stoichiometry) Chemical Bonding (Lewis structures) Organic Chemistry Acids and Bases Second half examine some applications: Household Chemicals Biochemistry and Pharmaceuticals Chemistry of Food Chemistry of the Environment Chemistry Today Way to engage students Group Project - groups assigned "mystery ingredient list“ Required to produce report should be informative and should be written for the general public for a popular science or health magazine. Chemistry Today Introductory Chemistry and Chemistry Today Both Distance Education Courses Way to engage students OWL Homework (Cengage) 1st year students Student preparation quite variable Strengths Confidence Willingness to ask for help Weaknesses Math!! (basic algebra; dimensional analysis) Problem solving skills Fear (and loathing) of chemistry General 1st year issues Maturity Time management