Chapter 1 Notes Chemistry: Matter and Change Chemistry Science dealing with the structure, properties and behavior of all substances that make up the universe. – Examples: elements; compounds; chemical reactions; nuclear reactions; color; phase changes; Six Areas of Chemistry • • • • • Organic – carbon containing Inorganic – non-organic Biochemistry – chemistry in living things Analytical – ID of composition of materials Physical – properties/changes of matter and energy associated • Theoretical – mathematical perspective of the behavior of chemical compounds Matter • Anything that has mass and takes up space. • Matter can be solid, liquid, gas or plasma. • It cannot be created or destroyed (in normal chemical reactions). However, it can change forms. Law of Conservation of Mass (also called Conservation of Matter and Conservation of Energy) • In a normal chemical reaction, matter cannot be created or destroyed. Mass • A measure of the amount of matter in an “object” • Units: g, mg, kg States of Matter • Solids – definite shape, definite volume • Liquids – no definite shape, definite volume • Gases – no definite shape, no definite volume • Gases vs Vapors – Gases are typically in the gaseous phase at room temperature. • Examples: oxygen, carbon dioxide – Vapors are substances that are typically in the solid or liquid phase at room temperature. • Examples: perfume, acetone, water, alcohol Phase changes • As temperature changes, as well as pressure, substances can change phases. • Phase changes can be from solid liquid gas or even solid gas. • Melting/Freezing – Occurs when a substance changes from solid liquid. – Melting of ice and freezing of water both occur at 0ºC. • Boiling/Condensing – occurs when a substance changes from liquid gas. – Water boils at 100ºC. Steam condenses at 100ºC. • Sublimation – occurs when a substance changes directly from solid to gas. – Dry ice (solid CO2) and iodine sublime. Properties of Matter • Describe the composition, structure and behavior of a substance. – Examples: color, mass, boiling pt., flammability, taste Quantitative vs. Qualitative Properties • Quantitative – a property that uses measurement – Examples: mass, temperature, melting point • Qualitative – a property that can be expressed without measurement – Examples: color, smell, flammability, reactivity with water Extensive vs. Intensive Properties • Extensive – depend on the amount of matter present – Examples: mass, volume, length • Intensive – not dependent on the amount of matter present – Examples: temperature, density, boiling point, electrical conductivity Physical vs. Chemical Properties • Physical properties – observable with the senses and can be determined without destroying the object. – Examples: color, shape, mass, length, density, specific heat, odor • Chemical properties – indicates how something reacts (or doesn’t) with something else. – Examples: the ability of iron to rust; the flammability of rubbing alcohol Physical Change vs. Chemical Change • Physical change – a change in matter that does not involve a change in the composition of individual substances. – A physical change does not produce a new substance. – Examples: ripping paper, melting ice, crushing potato chips, dissolving salt, evaporation • Chemical change – a change in matter that does involve a change in the composition of a substance. – A chemical change always produces a new substance. – Examples: burning paper, rusting metal, decaying of a dead mouse Indicators/Signs of a Chemical Change/Reaction 1) 2) 3) 4) 5) Color change Precipitate formed (solid formed) Gas produced (bubbles) Odor change (smells different) Energy change (gains or loses heat – feels warmer or cooler) Energy/Heat Change • Exothermic – Heat is lost; energy is given off; it feels warmer. – Examples: hand warmer, charcoal burning, dilution of acids • Endothermic – Heat is gained; energy is taken in; it feels cooler – Example: chemical ice pack • There can be an energy/heat change (endothermic or exothermic) even if there is not a chemical change Classification of Matter Pure Substance • Matter with the same composition throughout. It can be an element or a compound. Mixture • A combination of two or more substances in which each substance keeps its unique set of properties. It can be separated into two or more pure substances. Pure substance • Elements – Simplest form of matter that cannot be broken down in smaller substances. – Elements are represented by symbols from the periodic table. – Examples: iron (Fe), hydrogen (H), silver (Ag), potassium (K) • http://periodictable.com/ Pure substance • Compounds – Chemical combination of two or more elements joined together in a fixed proportion. – Compounds are represented by a formula – a combination of chemical symbols showing an exact ratio of elements. – Examples: calcium chloride (CaCl2), sodium bicarbonate (NaHCO3), butane (C4H10), water (H2O) Mixtures • Heterogeneous mixture – A mixture that has multiple phases. – Individual substances can clearly be “seen” in the mixture and are not uniformly distributed. – Examples: trail mix, oil and vinegar salad dressing, concrete, a glass of Dr. Pepper with ice Mixtures • Homogeneous mixture – A mixture that has one phase; substances are evenly distributed. – There is a constant composition throughout. – Examples: Kool-Aid, air, stainless steel Homogeneous mixtures are also known as solutions. • Solutions consist of solute and solvent. • Solute – the substance being dissolved. • Solvent – the substance that dissolves the solute. – Example: Salt water is a solution. Salt is the solute. Water is the solvent. Alloy • A solid solution usually made up of two or more metals. • Examples: stainless steel, brass, bronze HW: 4, 7, 9, 11, 12, 16, 17, 18, 19, 21, 23, 24, 27, 29 (pp. 23-24) • due Fri., 8/30 Periodic Table of Elements The periodic table is organized into periods, groups and families based on properties. • Periods – horizontal rows – there are 7 periods numbered from top to bottom (1-7) – each period represents a new energy level Periodic Table of Elements • Groups – vertical columns – there are 18 groups numbered from left to right (1-18) – they are sometimes called families – elements within groups have similar properties Metals, Nonmetals, and Metalloids • Metals – left of the stair-step – conduct heat and electricity well – high luster/shiny (often gray or white, but can be yellow or brown) – malleable (can be bent or hammered) – ductile (can be drawn out into a long thin wire) – generally solids at room temperature (Hg is a liquid) Metals, Nonmetals, and Metalloids • Nonmetals – right of the stair-step – do not conduct heat and electricity well – lack luster – brittle – many are gases at room temperature (some are solids, Br is a liquid) Metals, Nonmetals, and Metalloids • Metalloids – along the stair-step – B, Si, Ge, As, Sb, Te – have properties of both metals and nonmetals – some are semiconductors • they conduct electricity better than nonmetals but not as well as metals • conductivity can be improved by doping – adding another element