AP Chemistry Winter Intersession Assignment Memorize the names, formulas and charges on the following ions. You should also know how to combine them to form compounds. You should also know the charges and names of all main-group element ions on the periodic table. Common Ions cations + NH4 Ag+ Zn2+ 1- ammonium silver zinc CH3COO OHNO3NO2CNMnO4- - acetate hydroxide nitrate nitrite cyanide permanganate 22- CO3 SO42SO32- carbonate sulfate sulfite 3PO4 3- phosphate Memorize the formulas and names of the following strong acids and strong bases. We will be working with acids and bases for the majority of the third quarter and this will be essential. You must remember that ionic compound containing the following ions are ALWAYS water soluble: Group I cations, NH4+, NO3-, or CH3COOLastly you must remember the following elements always exist in a DIATOMIC state (a molecule of two atoms): H2, O2, N2, F2, Cl2, Br2, I2 Types of Reactions: For each of the following reactions write the complete ionic and net ionic equations. Metal Redox Reactions 1. Solid zinc is added to a solution of copper (II) chloride. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 2. Manganese metal is oxidized by a solution of cobalt (II) nitrate. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 3. A solution of iron (III) ion is reduced to iron (II) by solid lead. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ Reactions between metals and acids 4. Hydrobromic acid is added to a beaker containing chromium metal. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 5. A piece of magnesium metal is placed in a solution of sulfuric acid. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 6. Zinc metal is oxidized by a solution of nitric acid. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ Nonmetal Redox 7. Chlorine gas is reduced when it is bubbled through a solution of potassium iodide. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 8. Aqueous sodium iodide is combined with liquid bromine. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ Precipitation Reactions 9. Aqueous zinc nitrate is combined with a solution of sodium carbonate and a precipitate forms. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 10. Aqueous ammonia chloride is mixed with an aqueous solution of silver nitrate. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 11. A barium acetate solution is combined with a solution of calcium sulfate and a precipitate forms. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ Strong Acid – Strong Base Reactions 12. Aqueous perchloric acid reacts with an aqueous solution of sodium hydroxide. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 13. Aqueous hydrochloric acid reacts with an aqueous solution of calcium hydroxide. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 14. Aqueous sulfuric acid reacts with a solution of potassium hydroxide. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ 15. Solid sodium hydroxide is added to a solution of nitric acid. Complete Ionic Equation: _________________________________________________________ Net Ionic Equation: ______________________________________________________________ Empirical Formulas 16. Allicin is the compound responsible for the characteristic smell of garlic. An analysis of the compound gives the following percent composition by mass: C – 44.4%, H – 6.21%, S – 39.5%, and O – 9.86%. Calculate its empirical formula. What is its molecular formula given that its molar mass is about 162 g? 17. Peroxyacylnitrate (PAN) is one of the components of smot. It is acompound of C, H, N and O. Determine the percent composition of oxygen and the empirical formula from the following percent composition by mass: 19.8 percent C, 2.50 percent H, 11.6 percent N. What is the molecular formula given its molar mass is about 120 g/mol? 18. What are the empirical formulas of the compounds with the following compositions? a. 40.1 percent C, 6.6 percent H, 53.3 percent O. b. 18.4 percent C, 21.5 percnet N, 60.1 percent K c. 2.1% H, 65.3% O, 32.6% S d. 20.2% Al, 79.8 % Cl