SCH4U Unit 1 – Organic Chemistry Unit Preparation Name: _______________________________ Chemical Bonds 1. What is the difference (in terms of ∆EN) between ionic bonds, covalent bonds, and polar covalent bonds? 2. Determine the ∆EN for the following: a. HCl b. NaF c. MgO Representing Molecules 1. Provide both the classical and stock names for the following compounds: a. b. c. d. e. f. TiO2 Fe(OH)3 CuO Pb3(PO4)4 SnCl2 CoCl2 2. Write the correct chemical formula for each of the following compounds: a. b. c. d. e. f. Zinc perchlorate Mercury (II) nitride Stannous fluoride Ferric hydroxide Lead (IV) phosphate Nickel (III) sulfite Balancing Equations 1. Balance each of the following equations: ___ NaCl(aq ) ___ NaClO(aq) ___ H 2O(l ) a. ___ NaOH(aq ) ___ Cl2(g ) ___ Al2 (SO4 ) 3(aq ) ___ HNO3(aq) b. ___ Al(NO3 ) 3(aq) ___H 2SO4(aq) c. ___KI(aq) ___ MnO2(s) ___ H2SO4(aq) ___K2SO4(aq) ___ MnSO4(aq) ___ H2O(l ) I2(s ___ CO2(g ) ___ H 2O(g ) d. ___ C6 H 6(l ) ___ O2(g ) Ionic Equations 1. Aqueous solutions of several pairs of ionic solids are prepared and then mixed together. For each pair listed below, write the following: i. The balanced, total ionic equation ii. The net ionic reaction, if a precipitate forms iii. Any spectator ions a. Lead (II) nitrate and zinc iodide b. Sodium hydroxide and iron (III) nitrate Mole and Concentration Calculations 1. How many moles of lead (IV) carbonate have a mass of 2.56 x 105 g? 2. A 6.00g sample is 76.5% sodium hydroxide. How many atoms of sodium are in this sample? 3. A salt solution has a concentration of 1.00mol/L. What volume of this solution is needed to prepare 2.00L of a solution that has a concentration of 0.475mol/L? 4. A sample of lead (II) nitrate, with a mass of 0.00372g, is completely dissolved in 250.0mL of water. Assume that no change in volume occurs. Calculate the following concentrations. a. The concentration of the solution, expressed in mol/L. b. The concentration of Pb2+, expressed in ppm. c. The concentration of the solution, expressed as a m/m percent. Stoichiometric Calculations 1. 40.00mL of 0.0256mol/L gold (III) chloride is treated with 85.00mL of 0.105 mol/L potassium iodide. AuCl3(aq) 3KI(aq ) AuI(s) 3KCl(aq ) I2(aq) a. What is the theoretical yield of AuI(s) produced? 2. When 15.0g of copper and 4.83g of sulfur are heated, a 13.7g mass of copper (I) sulfide is produced. 2Cu(s) S(g ) Cu2 S(s) a. What is the percentage yield of Cu2S?