Wednesday October 5, 2011 (Ionization Energy; Electron Affinity) Announcements We will have a test next Tuesday. Assignment Currently Open Summative or Formative Date Issued Date Due WS – The Electromagnetic Spectrum F 9/23 9/27 WS – Average Atomic Mass F 9/27 9/29 WS – Periodic Properties F 10/3 10/6 TEKSCheck #! F 10/4 10/4 Date Into Grade Book Last Day Bell Ringer Wednesday, 10-5-11 Ionization energy is the _______________ energy required to remove one electron from a neutral atom of an element. Bell Ringer Wednesday, 10-5-11 Ionization energy increases _______ from left to right across a period because of: increasing nuclear charge. An increase in the number of protons more strongly attracts electrons in the same energy level. Ionization energy decreases ______ from top to bottom down a group because: electrons removed from atoms of each succeeding element in a group are in higher energy levels, farther from the nucleus. Ionization Energy Ionization energy may be defined as the energy required to remove one electron from a neutral atom of an element. This property determines the extent to which an atom is capable of losing electrons in order to begin the chemical bonding process. Ionization Energy In general, ionization energies of the main-group elements increase across each period. This increase is caused by increasing nuclear charge. A higher charge more strongly attracts electrons in the same energy level. Generally speaking, the increases energy required for an atom to lose electrons increases as you move from left to right across a period. Ionization Energy Among the main-group elements, ionization energies generally decrease down the groups. Electrons removed from atoms of each succeeding element in a group are in higher energy levels, farther from the nucleus. Generally speaking, the energy required to lose electrons get less as you move down a group. Therefore, they are removed more easily. decrease Bell Ringer Wednesday, 10-5-11 Electron affinity is the __________________ energy change that occurs when an electron is acquired by a neutral atom. Bell Ringer Wednesday, 10-5-11 Electron affinity increases _______ from left to right across a period because: adding an electron to an empty sublevel takes less energy than adding electrons to a half-filled sublevel. Electron affinity decreases _______ from top to bottom down a group because of: a slight increase in effective nuclear charge down a group, and an increase in atomic radius down a group. Electron Affinity . Electron affinity is defined as the energy change that occurs when an electron is acquired by a neutral atom. Most atoms release energy when they acquire an electron - the quantity of energy released is represented by a negative number. Some atoms must be “forced” to gain an electron by the addition of energy - the quantity of energy absorbed is represented by a positive number. Electron Affinity In general, as electrons add to the same p sublevel of atoms with increasing nuclear charge, electron affinities become more negative across each period within the p block, although there are exceptions. For example, adding an electron to a nitrogen atom gives a half-filled p sublevel. This occurs much more easily than forcing an electron to pair with another electron in an orbital of the already halffilled p sublevel of a oxygen atom. negativity increases Electron Affinity As a general rule, electrons add with greater difficulty down a group. This pattern is a result of two competing factors. The first is a slight increase in effective nuclear charge down a group, which increases electron affinities. The second is an increase in atomic radius down a group, which decreases electron affinities. In general, the size effect predominates. decrease Complete the worksheet entitled “Periodic Properties.” Begin the worksheet entitled “The Periodic Law.”