What you really need to remember ! Metric System Lab safety (WHMIS, household symbols) Nomenclature (inorganic, organic) Quantum Theory Quantity length mass volume temperature time amount of matter electric current luminous intensity Base Unit metre gram litre kelvin second mole ampere candela Symbol m g L K s mol A cd Quantity Name of Unit Symbol in SI Base Units density kilogram per cubic metre kg · m-3 kg · m-3 (kg/m3) force Newton N kg · m · s-2 (kg · m / s2) pressure Pascal Pa N · m-2 (kg·s-2·m-1 , N / m2) heat energy Joule J N·m (kg·m2·s-2 ) Prefix Symbol Multiplication Factor exa E 1 000 000 000 000 000 000 peta P 1 000 000 000 000 000 tera T 1 000 000 000 000 giga G 1 000 000 000 mega M 1 000 000 kilo k 1 000 hecto h 100 deca da 10 THE BASE UNIT 1 Exponential Notation 1018 1015 1012 109 106 103 102 101 100 Prefix Symbol Multiplication Factor Exponential Notation THE BASE UNIT 1 100 deci d 0.1 10-1 centi c 0.01 10-2 milli m 0.001 10-3 micro μ 0.000 001 10-6 nano n 0.000 000 001 10-9 pico p 0.000 000 000 001 10-12 femto f 0.000 000 000 000 001 10-15 atto a 0.000 000 000 000 000 001 10-18 These tables must be memorized. The quiz will be on ...... The eight-sided outline (octagonal) signifies that the contents of the container is dangerous. The triangular outline signifies that the container is dangerous, usually because the contents are under high pressure. Poison poisons can enter the body in one of three ways: a) ingestion (eating) b) inhalation (breathing) c) absorption through the skin d) injection Corrosive are chemicals which can act on clothing, skin, eyes or internally by drinking or eating can cause symptoms ranging from mild rash to serious skin damage can damage clothing can cause blindness can cause death if ingested Flammable are substances which can burn easily or cause other materials to burn Radiation radioactive materials emit high energy atomic particles or high energy radiation (x-rays, gamma rays), or both found in smoke detectors and involve no danger if kept at a safe distance Explosive can cause injury or death as a result a blast or because of the materials expelled by the blast (metal shards) usually are pressurized aerosol containers which may explode when heated Workplace Hazardous Materials Information System Class A - Compressed Gas danger lies in the pressure, not in the contents. Class B - Combustible and Flammable Material may burn at relatively low temperatures, burn spontaneously or as a result of heat, sparks or friction hydrocarbons and several chemicals like phosphorus, sodium and calcium carbide would be included in the list. Class C - Oxidizing Material may cause a fire, react violently or explode when it comes into contact with combustible materials such as wood. an oxidizer supplies the oxygen for a chemical reaction. Class D, Division 1 – Poisonous and Infectious Material; Immediate and Serious Toxic Effects these substances have acute toxicity - refers to a substance which has immediate effects, usually within 24 hours Class D, Division 2 – Poisonous and Infectious Material; Other Toxic Effects these substances have chronic toxicity - refers to the effects of a substance through repeated exposure at low levels over a long period (weeks, months or years). effects include; organ damage, illness or death the effects can also include cancer, allergies or chronic diseases (bronchitis, emphysema, cirrhosis of the liver, etc.) long term alcohol or cigarette use would fall under this category Class D, Division 3 – Poisonous and Infectious Material; Biohazardous Infectious Material refers to an infectious agent (bacteria, virus or some other organism) which may spread disease if improperly handled, also called a biohazard this symbol is common in hospital emergency rooms on containers where used needles and dressings are deposited Class E - Corrosive Material causes severe eye and skin irritation upon contact causes severe tissue damage with prolonged exposure may be harmful if inhaled the effects are the same as under the household hazards Class F - Dangerously Reactive Material is very unstable may react with water to release a toxic or flammable gas may explode as a result of shock, friction or increase in temperature undergoes vigorous polymerization all of these reactions happen very quickly; you have to be extremely careful around these substances 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. No eating or drinking in the lab. Treat all chemicals as if they were hazardous: Never perform unauthorized experiments. Report all accidents immediately. If you get a chemical solution in your eye go to the eyewash station immediately and wash the eye for at least 5 minutes. If you get chemicals on your clothes, wash the clothes thoroughly. Do not wear loose clothing during a lab. Tie long hair back. Do not sit on the lab bench; you do not know how clean it is. Clean all equipment thoroughly and put it back where it belongs. Follow directions concerning the safe disposal of chemicals and solutions. Clean your lab station thoroughly after a lab. Inhaled Poison - Remove the patient to fresh air and apply artificial respiration if necessary. Keep the victim warm with blankets. Contact of Poison with Skin or Eyes - Flood affected area with water, for at least 5 minutes. Remove contaminated clothing. DO NOT attempt to use chemical antidote. Swallowed Poison - If the person is conscious and able to swallow, immediately dilute the poison by giving the victim 2 to 4 cups of milk or water. Swallowed Corrosives - DO NOT INDUCE VOMITING. Give milk and water. If vomiting occurs naturally, hold head below hips to avoid choking. Be able to identify the items on the sheet given. Note: the flask is an erlenmeyer flask Inorganic elements molecular ionic Organic aliphatic cyclic substituted Common substances inorganic or organic must be simple as possible must be unique one kind of atom most are monoatomic (one atom) Cu, Fe, Al, He 8 elements are diatomic (2 atoms) H2 N2 O2 F2 Cl2 Br2 I2 (At2) 2 are polyatomic S8 P4 known by names other than their systematic names be familiar with formulas systematic name common name know whether systematic or common name takes precedence Formula Chemical Name Common Name H 2O NaCl HCl HNO3 H2SO4 H3PO4 CH3COOH CaSO4 NH3 hydrogen oxide sodium chloride hydrogen chloride hydrogen nitrate hydrogen sulfate hydrogen phosphate acetic acid calcium sulfate nitrogen trihydride water table salt hydrochloric acid nitric acid sulfuric acid phosphoric acid vinegar gypsum (dry wall) ammonia Formula Chemical Name Common Name H2O2 C2H5OH CH3OH CH4 O3 C12H22O11 KCl NaOH CaO hydrogen peroxide ethanol methanol methane ozone sucrose potassium chloride sodium hydroxide calcium oxide hydrogen peroxide drinking alcohol wood alcohol natural gas ozone table sugar potash lye, caustic soda lime made up of 2 non-metals bound together with covalent bonds: can’t predict formula so naming is done on a numbering system. prefixes in front of the element name tell you how many of that element are present in the compound: mono 1 hexa 6 di 2 hepta 7 tri 3 octa 8 tetra 4 nona 9 penta 5 deca 10 N2O5 dinitrogen pentaoxide (note ending) CO2 carbon dioxide CO carbon monoxide Cl2O7 dichlorine heptaoxide (no mono on first atom) C N O F Si P S carbide nitride oxide fluoride silicide phosphide sulfide Cl As Se Br Te I chloride arsenide selenide bromide telluride iodide tetraphosphorus decaoxide P4O10 tetrasulfur tetranitride S4N4 bromine monofluoride BrF diarsenic triselenide As2Se3 made up of cations and anions which come together as a result of ionic attraction: there is no molecule, rather a crystal lattice. chemical formula is ratio of cations to anions in crystal; formula unit ionic substances are recognized because they contain a metal + non-metal the formula unit of any ionic compound is the ratio of cations to anions in the crystal lattice. the net charge of a formula unit is zero. it is written as the lowest ratio of cations to anions. K1+ Mg2+ Al3+ Ca2+ Sr2+ NH41+ F1Cl1S2S2OH1SO42- gives KF gives MgCl2 gives Al2S3 gives CaS gives Sr(OH)2 gives (NH4)2SO4 Do first half of nomenclature assignment a) K1+, Br1- f) Zn2+ , O2KBr b) Ca2+, Cl1c) Li1+, H1- ZnO g) Mg2+ , NO31- CaCl2 h) Fe2+, O2- LiH d) Fe3+, OH1e) Ca2+, OH1- Mg(NO3)2 FeO i) Fe3+ , O2- Fe(OH)3 Ca(OH)2 j) Sn4+, F1- Fe2O3 SnF4 k) Hg2+, O2- p) Mn7+ , O2HgO l) K1+, PO43m) Si4+, O2- K3PO4 q) Na1+, SeO32r) Na1+, SeO42- SiO2 n) NH41+, SO42s) Al3+, SO42(NH4)2SO4 o) Na1+, PO43t) H1+, S2Na3PO4 Mn2O7 Na2SeO3 Na2SeO4 Al2(SO4)3 H2S a) ZnSO4 Zn2+ SO42b) Mn(NO3)3 Mn3+ NO31c) SnO Sn2+ O2d) LiHCO3 Li1+ HCO31e) Hg2Cl2 Hg22+ Cl1- f) KSCN K1+ SCN1g) Na2SO3 Na1+ SO32h) Al2(Cr2O7)3 Al3+ Cr2O72i) MgC2O4 Mg2+ C2O42j) SrH2 Sr2+ H1- cations from groups 1 & 2, Al, Zn, Ag, Cd, NH41+ (all have only one possible charge) anions can be anything on the chart (including polyatomic ions) only one formula unit possible, so name is a repetition of the ion names: NaCl Na1+ Cl1sodium chloride NH4NO3 NH41+ NO31ammonium nitrate Al2(CO3)3 Al3+ CO32aluminum carbonate Ag3P Ag1+ P3silver phosphide cadmium chlorite Cd2+ strontium nitride Sr2+ ClO21Cd(ClO2)2 N3- Sr3N2 used when the cation can have more than one possible charge used for all other metals on the Periodic Table. the name of the compound includes the charge of the cation in roman numerals, in brackets after the cation name. The Stock System of Nomenclature Formula Charge of Cation Charge of Anion Name of Compound SnF2 Sn2+ F1- Tin (II) fluoride SnF4 Sn4+ F1- Tin (IV) fluoride Co(ClO)3 Co3+ ClO1- MnO2 Mn4+ O2- US3 U6+ S2- Cobalt (III) hypochlorite Manganese (IV) oxide Uranium (VI) sulfide older system much, much, older largely replaced by Stock system, but is still around. if see name be able to give formula. never give classical name for any formula. The Stock and Classical Systems of Nomenclature Charge of Charge of Formula Stock Name Cation Anion Classical Name SnF2 Sn2+ F1- Tin (II) fluoride Stannous fluoride SnF4 Sn4+ F1- Tin (IV) fluoride Stannic fluoride CoCl2 Co2+ Cl1- Cobalt (II) chloride Cobaltous chloride CoCl3 Co3+ Cl1- Cobalt (III) chloride Cobaltic chloride Cu2O Cu1+ O2- Copper (I) oxide Cuprous oxide CuO Cu2+ O2- Copper (II) oxide Cupric oxide water molecules physically attached to ionic and molecular substances. name and formula recognizes their presence. gypsum typically attracts 4 water molecules per formula unit: CaSO4 · 4 H2O name the substance then use a numbering prefix followed by subscript hydrate: calcium sulfate tetrahydrate Naming Hydrated Compounds Formula Name of Compound P2O5 · 10 H2O diphosphorus pentaoxide decahydrate Na2CO3 · H2O sodium carbonate monohydrate Complete second half of nomenclature assignment 1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 11) 12) 13) 14) 15) NH3 Fe(NO3)2 SO2 MgBr2 GeCl4 N2 AlPO4 C2H5OH Li2CrO4 KH CuCr2O7 NH4NO3 H2SO4 Pb3(PO4)2 KSCN Fe2+ NO31Mg2+ Br1Ge4+ Cl1Al3+ PO43Li1+ CrO42K1+ H1Cu2+ Cr2O72NH41+ NO31H1+ SO42Pb2+ PO43H1+ SCN1- ammonia iron (II) nitrate sulfur dioxide magnesium bromide germanium (IV) chloride nitrogen aluminum phosphate ethanol lithium chromate potassium hydride copper (II) dichromate ammonium nitrate sulfuric acid lead (II) phosphate potassium thiocyanate 16) 17) CO2 P2O5 6 H2O 18) 19) 20) 21) 22) 23) PbO Pb2+ O2BaS Ba2+ S2S8 Mo(NO3)7 Mo7+ NO31BaH2 Ba2+ H1CaSO4 4 H2O Ca2+ SO42O2 Al2O3 Al3+ O2PCl3 NO3 Mn2O3 Mn3+ O2U(CO3)3 U6+ CO32SnSO3 Sn2+ SO32- 24) 25) 26) 27) 28) 29) 30) carbon dioxide diphosphorus pentaoxide hexahydrate lead (II) oxide barium sulfide sulfur molybdenum (VII) nitrate barium hydride calcium sulfate tetrahydrate oxygen aluminum oxide phosphorus trichloride nitrogen trioxide manganese (III) oxide uranium (VI) carbonate tin (II) sulfite 1) sodium fluoride 2) potassium carbonate 3) aluminum sulfide 4) calcium bromide 5) chlorine heptafluoride 6) silver oxide 7) ammonium sulfide 8) barium hydroxide 9) phosphorus 10) mercurous chloride 11) tin (II) nitrate 12) potassium bisulfite 13) caustic soda 14) boric acid 15) cupric sulfate Na1+ F1K1+ CO32Al3+ S2Ca2+ Br1Ag1+ O2NH41+ S2Ba2+ OH1Hg22+ Cl1Sn2+ NO31K1+ HSO31Na1+ OH1H1+ BO33Cu2+ SO42- NaF K2CO3 Al2S3 CaBr2 ClF7 Ag2O (NH4)2S Ba(OH)2 P4 Hg2Cl2 Sn(NO3)2 KHSO3 NaOH H3BO3 CuSO4 16) 17) 18) 19) 20) 21) 22) 23) 24) 25) 26) 27) 28) 29) 30) calcium carbonate ammonium sulfite iron (II) hydroxide uranium (VI) nitrate ozone lithium dichromate hydrogen nitrate barium bicarbonate nitrogen dioxide carbon monoxide methanol ammonium oxalate argon octafluoride gold (III) nitrate cobalt (II) chloride hexahydrate Ca2+ CO32NH41+ SO32Fe2+ OH1U6+ NO31Li1+ Cr2O72H1+ NO31Ba2+ HCO31- NH41+ C2O42Au3+ NO31Co2+ Cl1- CaCO3 (NH4)2SO3 Fe(OH)2 U(NO3)6 O3 Li2Cr2O7 HNO3 Ba(HCO3)2 NO2 CO CH3OH (NH4)2C2O4 ArF8 Au(NO3)3 CoCl2 · 6 H2O 3 types of organic compounds important for this class: aliphatic hydrocarbons - chains cyclic hydrocarbons - rings aromatic hydrocarbons - benzene rings Naming hydrocarbons involves looking at 3 aspects: 1. Number of carbons linked in a continuous chain. 2. The presence of single, double or triple bonds in the carbon chain. 3. The presence of structures other than hydrogen attached to the main carbon chain (functional groups). 1 2 3 4 5 6 how many carbons are bonded in a chain gives the prefix of the name: methethpropbutpenthex- 7 8 9 10 11 12 heptoctnondecundecdodec- other prefixes include: 13 14 15 20 25 tridectetradecpentadeceicospentacos- 30 40 50 100 triaconttetracontpentaconthect- carbon atoms make 4 chemical bonds. carbon atoms can be linked to each other by one pair of electrons (single bond), two pair (double bond), or three pair (triple bond). the presence of double or triple bonds on the carbon chain changes the chemical family. alkanes all carbons are connected by single bonds the suffix –ane is added to the name of the compound the general formula is CnH2n+2 hexane alkenes the carbon chain contains at least one double bond the suffix –ene is added to the name of the compound the general formula is CnH2n propene alkynes the carbon chain contains at least one triple bond the suffix –yne is added to the name of the compound the general formula is CnH2n-2 propyne is defined as the structure associated with a chemical formula. for many organic compounds it is possible to have more than one isomer for a given formula. the simplest isomers are alkenes and alkynes where the double or triple bond can have more than one location: 1-butene 2-butene number the carbons from the end closest to the multiple bond: 1- hexene the double bond is located closest to the lefthand side, so that is where numbering starts. 2-hexene the double bond is closer to the right-hand side, so numbering begins there. 1-hexene 1-hexene these two are the same molecule. 1-butyne 2-butyne hydrocarbon chains halogens alcohols Hydrocarbon chains are carbon chains attached to the main chain: this is called methylbutane Prefixes are used to indicate the number of carbons in the chain: 1 carbon - methyl2 carbons - ethyl3 carbons - propyl- when it is possible to attach the hydrocarbon in more than 1 place numbering is used: 2-methylpentane 3-methylpentane 4-methyl-2-pentene 2,3-dimethylpentane 3,4-dimethyl-2-pentene 2,4-dimethyl-3-ethylpentane Halogens - group 17 elements attached to the carbon chain: 1-fluoro-3-chloropentane 1-fluoro-1,1-diiodo-5,5,5-trichloro2-pentyne Alcohols - are formed when –OH groups are attached to the main chain: 1-pentanol 2-penten-1-ol cyclopropane cyclohexane cyclohexene 2-chloro-4-fluorocyclohexene benzene benzene phenol toluene dichlorobenzene ortho- meta- para- Complete organic nomenclature assignment Quantum mechanics is a mathematical treatment into which both the wave and particle nature of matter could be incorporated. since the electron is both a wave and a particle it is impossible to give it’s location or speed with certainty. gives a probability density map of where an electron has a certain statistical likelihood of being at any given instant in time. The probability map reveals the atomic orbitals, and their corresponding energies. An orbital is described by a set of three quantum numbers. This relates to the energy of the electron As n becomes larger, the atom becomes larger and the electron is further from the nucleus. This is directly related to the period of the atom on the Periodic Table This quantum number depends on the value of n. The values of l begin at 0 and increase to n – 1. Value of l 0 1 2 3 Type of orbital s p d f Theoretical g, h, i, etc. orbitals exist, but no atoms have been created to use them. This quantum number defines the shape of the orbital. This quantum number depends on l. The magnetic quantum number has integer values between –l and +l. Magnetic quantum numbers give the threedimensional orientation of each orbital. Value of l = 0. Spherical in shape. Radius of sphere increases with increasing value of n. Value of l = 1. Have two lobes with a node between them. Value of l is 2. Four of the five orbitals have 4 lobes; the other resembles a p orbital with a doughnut around the center. electrons have spin, which creates a magnetic field there are two spin states possible, +1/2 and -1/2 a single orbital can hold a maximum of two electrons, which must have opposite spin. No two electrons in the same atom can have exactly the same energy. For example, no two electrons in the same atom can have identical sets of quantum numbers. thus every electron location is defined in terms of 4 things: a) Principal Quantum Number - 1 to 7 b) Angular Quantum Number – s, p, d or f c) Magnetic Quantum Number – implied by number of electrons in each shape; s has 2, p has 6, d has 10 and f has 14 d) Spin Quantum Number – why each orbital can contain 2 electrons Electrons tend to occupy the lowest available orbital. The simplest atom, hydrogen has 1 electron. In its’ lowest, or ground state, this electron will occupy the 1s orbital, the lowest energy orbital available (see chart, page 105) The next element, helium, has two electrons, both of which will occupy the 1s orbital. Element three, lithium, has three electrons. The first two will fill the 1s orbital while the third must move up to the next energy level, 2s. Thus the electron configuration of an atom is the arrangement of the electrons from the lowest energy level to the highest. Consist of Number denoting the energy level. Letter denoting the type of orbital. Superscript denoting the number of electrons in those orbitals. For instance: Iron (Fe) – contains 26 electrons 1s22s22p63s23p64s23d6 watch the order of filling Potassium - 19 electrons 1s22s22p63s23p64s1 Silver - 47 electrons 1s22s22p63s23p64s23d104p65s24d9 Tungsten - 74 electrons 1s22s22p63s23p64s23d104p65s24d105p66s24f145d4 Plutonium - 94 electrons 1s22s22p63s23p64s23d104p65s24d105p66s24f145d10 6p67s25f6 Write the correct electron configuration for the following: Si, S, P, Ca, As, Fe, Br, Kr, At, U, Na1+, F1-, Ne - 14 e1- 1s22s22p63s13p3 - 16 e1- 1s22s22p63s23p4 - 15 e1- 1s22s22p63s23p3 - 20 e1- 1s22s22p63s23p64s14p1 - 33 e1- 1s22s22p63s23p64s23d104p3 - 26 e1- 1s22s22p63s23p64s23d6 - 35 e1- 1s22s22p63s23p64s23d104p5 - 36 e1- 1s22s22p63s23p64s23d104p6 - 85 e1- 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p5 - 92 e11s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f4 Na1+ - 10 e1- 1s22s22p6 F1- - 10 e1- 1s22s22p6 Ne - 10 e1- 1s22s22p6 Si S P Ca As Fe Br Kr At U promotion of an outer ‘s’ electron to the adjacent ‘p’ orbital. turns non-bonding electrons into bonding electrons allows atoms to make more chemical bonds and achieve a lower energy applies to elements from groups 2, 13 and 14 only for these elements promotion is the rule Element Unhybridized Hybridized beryllium 1s22s2 1s22s12p1 boron 1s22s22p1 1s22s12p2 carbon 1s22s22p2 1s22s12p3 are another way to illustrate the position of electrons. They are best learned by comparison with electron configuration: Na (11 protons, 11 electrons) electron configuration: 1s22s22p63s1 orbital diagram: 1s 2s ↑↓ ↑↓ 2p ↑↓ ↑↓ ↑↓ 3s ↑ Group Representative Element Electron configuration Orbital Diagram 1 lithium 1s22s1 1s ↑↓ 2s ↑ 2 beryllium 1s22s12p1 ↑↓ ↑ ↑ 13 boron 1s22s12p2 ↑↓ ↑ ↑ ↑ 14 carbon 1s22s12p3 ↑↓ ↑ ↑ ↑ ↑ 15 nitrogen 1s22s22p3 ↑↓ ↑↓ ↑ ↑ ↑ 16 oxygen 1s22s22p4 ↑↓ ↑↓ ↑↓ ↑ ↑ 17 fluorine 1s22s22p5 ↑↓ ↑↓ ↑↓ ↑↓ ↑ 18 neon 1s22s22p6 ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ Repeat the last assignment, giving the orbital diagrams for the elements. 2p Na1+, F1-, Ne are all the same: gives information only concerning the valence electrons. Valence electrons are the electrons on the outside of an atom; they are the electrons responsible for bonding and are also the electrons gained or lost when an atom ionizes. Valence electrons are electrons in the s and p orbitals of the highest energy level reached by the electrons of an atom. In this class when valence electrons are mentioned, the only elements concerned are those in groups 1, 2, and 13 through 18. group 1 group 2 group 13 group 14 group 15 group 16 group 17 group 18 Repeat last assignment, making lewis diagrams. Fe and U have no lewis diagrams both give information about valence electrons. if valence electrons are paired, they cannot be used for bonding with other atoms. They are lone-pair electrons. unpaired valence electrons are bonding electrons. 5 valence electrons 1 lone pair 3 bonding electrons; this atom makes 3 chemical bonds. 4 valence electrons 0 lone pair 4 bonding electrons; this atom makes 4 chemical bonds 7 valence electrons 3 lone pair 1 bonding electrons; this atom makes 1 chemical bond 8 valence electrons 4 lone pair 0 bonding electrons; this atom makes 0 chemical bonds Each box represents one orbital. Half-arrows represent the electrons. The direction of the arrow represents the spin of the electron. Pauli Exclusion Principle – no two electrons in the same orbital can have the same spin “For degenerate orbitals, the lowest energy is attained when the number of electrons with the same spin is maximized.”