Final Quantum Light Model Lab Electron Potpourri Config. 100 100 100 100 100 200 200 200 200 200 1 2 300 300 300 300 300 400 400 400 400 400 500 500 500 500 3 500 4 100 Light Name three wave properties of light. Light behaves as a wave when it _______. Answer Light 100 Refraction, diffraction, interference, reflection Light behaves as a wave when it propagates (travels). 200 Light When an electron in an atom falls from the 5th to the 2nd energy level, 4.58 x 1019 J of energy are released. What is the frequency of this energy? Answer Light 200 E = h 4.58 x 1019 J = 6.626 x 1034Jsec X Answer = 6.91 x 1014 Hz 300 Light A bright line in the spectrum of sodium has a wavelength of 5.90 x 102nm. What is the frequency? Answer Light 300 ?m = 5.90 x 102 nm x 1 m_ = 5.90 x 10-7 m 1 x 109 nm Use c = 3.00 x 108m/sec = 5.90 x 10-7 m X Answer X= 5.08 x 1014Hz 400 Light Explain the photoelectric effect. Is this a wave or particle property? Give an example of how this is useful. Answer Light 400 Light of certain frequencies striking a metal causes the metal to release electrons. (electric current is created) This is a particle property. Useful: solar panels, garage door opener safety 500 Light A device emits light with frequency of 9.37 x 107 Hz. Find the wavelength. Is the device a tanning bed, red laser or a radio tower? All Play! Answer Light 500 Use c = 3.00 x 108 m/s = 9.37 x 107 Hz = 3.20 m ?nm = 3.20m X 1 x 109 nm = 3.20x 109 nm 1 meter 3.20x 109 nm is longer wavelength than visible light, thus it is Radio 100 Quantum Model Name the scientist who stated that electrons occupy orbitals of equal energy singly, with parallel spins, before doubling up. Answer Quantum Model 100 Hund 200 Quantum Model A 3-dimensional region about the nucleus where an electron may be found is a(n) Answer Quantum Model 200 orbital 300 Quantum Model Name the 1st quantum number, describe what it indicates and what its possible values are. Answer Final Jeopardy A photon of yellow light has 3.58 x 10-19 Joules of energy. What is the wavelength of this light in nanometers? Answer Final Jeopardy Answer E = hc/ = hc = E 6.626 x 10-34 Jsec x 3.00 x 108 m/s 3.58 x 10-19 Joules = 5.55 x 10-7 m = 555 nm Quantum Model 300 Principle Quantum Number Indicates energy level of electron – distance from nucleus Values are positive integers 1, 2, 3, etc. 400 Quantum Model The noble gas configuration of an element is: [Kr]5s24d105p3. Identify the element and state how many unpaired electrons it has. Quantum Model 400 1. [Kr]5s24d105p3 -- this element is Sb. 2. It has 3 unpaired electrons. 500 Quantum Model Give the letters naming the 4 types of sublevels (shapes) and indicate the maximum # of electrons each can hold. Answer Quantum Model 500 s= 2 p= 6 d = 10 f = 14 An illuminated tungsten light bulb, a hot toaster coil, and molten lava are all examples of __________. The spectrum of these light sources would be _________. Answer Lab 100 Incandescence continuous spectrum 200 Lab Explain the difference between phosphorescence and fluorescence. Give one example of each. Answer Lab 200 Both are the absorption of energy(usually UV) with the emission of visible light. In fluorescence the object stops glowing as soon as the energy source is removed. In phosphorescence, the glowing persists for a time after the energy source is removed. An example of phosphorescence is: a glow-inthe-dark toothbrush. An example of fluorescence is: the bright white glow of dirty shoelaces under a UV light. 300 Lab A flame test is performed on a metal compound. The flame is a hot pink/magenta color. What metal must be present? (Give name and symbol) Answer Lab 300 Li Lithium 400 Lab What piece of lab equipment is needed to view a spectrum? What in this room emits a bright line spectrum? Answer Lab 400 A spectroscope The fluorescent lights or a flame test. 500 Lab What is the main difference between luminescence and incandescence? Give 2 examples each of incandescence and chemiluminescence. Answer Lab 500 Luminescence is light produced without heat. Incandescence is light from a material heated to glowing. Incandescence – a W filament light bulb, a metal wire held in a flame until it glows red. Chemiluminescence- glowsticks, fireflies, moon jellyfish, the plants on Pandora 100 Electron Configuration Identify each of the following atoms based on their electron configurations. A. [Ne]3s2 B. [Ar]3d64s2 C. [Xe]6s24f145d7 Answer Electron Configuration 100 A.Mg – magnesium B.Fe – iron C.Ir -- iridium 200 Electron Configuration Write the orbital diagram for phosphorus. Answer Electron Config 200 Answer 1s 2s 2px py pz 3s 3px py pz 300 Electron Configuration Write the noble gas configuration for Re, Rhenium Answer Electron Configuration 300 Re [Xe]6s24f145d5 400 Electron Configuration Give the electron configuratio and noble gas configuration for strontium. Answer Electron Configuration 400 2 2 6 2 6 2 10 6 2 1s 2s 2p 3s 3p 4s 3d 4p 5s [Kr]5s2 Sr: 500 Electron Configuration Write an electron configuration for an excited carbon atom. Answer All Play!! Electron Configuration 500 Ground state: 1s22s22p2 Excited configuration: 1s22s22p13s1 one of the 2p electrons is in a higher energy orbital (can be any higher orbital) 100 Potpourri Which of the following configurations is impossible according to the Quantum Model? A. B. C. D. 1s22s23p1 1s22s22p62d1 [Rn]7s26d1 [Xe]6s25d1 Answer Potpourri 100 B. Is impossible because there is no d sublevel allowed in the 2nd energy level. Determine the % by mass of nitrogen in TNT. The formula of TNT is C7H5N3O6 Answer Answers for Potpourri 200 % N in C7H5N3O6 % N = 14.01 x 3 x 100 = 18.50% 227.15 g/mol 300 Potpourri A line in the spectrum of an element has a wavelength of 7.5 x 10-7 m. 1. Can you see this light? 2. What is the energy of the light? Answer Potpourri 300 Answer • The wavelength is longer than visible (7 x 10-7 m or 700nm) thus it is infrared. No, we can’t see it. • E= hc = (6.626 x 10-34Jsec) (3.00 x 108 m/s) 7.5 x 10-7 m = 2.7 x 10-19 J 400 Potpourri State and explain the Pauli Exclusion Principle. Answer Potpourri 400 PEP: No two electrons in the same atom have the same 4 quantum numbers. If two electrons have the same first 3 quantum numbers, they are in the same orbital and thus must have different spins. 500 Potpourri A sample has the composition of 85.5% C and 14.5% H. It has a molar mass of 98. What is the molecular formula of this compound? (hint: find empirical formula 1st!) Potpourri 500 mol C = 85.5 g x 1 mol = 7.12 mol C/7.12 = 1 12.01g mol H = 14.5 g x 1 mol = 14.4 mol H/7.12 = 2.02 1.01 g Empirical = C1H2 molar mass of empirical = 14.03 98/14.03 = 7 Molecular formula = C7H14