Science 10 Chemistry Mr McDonald Matter http://www.meta-synthesis.com/webbook/31_matter/matter2.jpg Elements • We have the periodic table of the elements • There is order to the table based on characteristics of the elements – What are some of these characteristics? Atoms • Recall • Mass number – total number of protons and neutrons in the nucleus • Atomic Number – number of protons • Number of protons is constant but neutron and electron numbers can be different – Electrons: be in a full outer shell (if so called an ION) – Neutrons: be the same as protons but if not it’s an isotope Electron shells • For the first 20 elements the shells are: – 2, 8, 8, (2) • These are the only electrons that you need to know. • But after the 20th element the shells can contain more electrons, based on orbitals. Various models of the atom • • • • Dalton’s – “billiard ball” model Thomson – “raisin bun” model Rutherford – “Electron Cloud” model Bohr – best model to date Bohr • Makes an extension of the Rutherford model that the electrons are at certain energy levels from the nulceus Bohr Diagrams • Shows the total number of electrons surrounding the atom Electron Dot Diagrams • Used to describe the amount of valence (outer shell) electrons for each atom. Review of terms • Nucleus: The central part of an atom; contains the protons and neutrons. • Electrons: small, negatively charged particles. Are found in electron shells OUTSIDE the nucleus. • Electron Shells (orbital): 3D space where electrons are likely to be found. • Valence electrons: Electrons found in outermost electron shell. It is these electrons that move from atom to atom. • Octet Rule: All atoms strive for a FULLY FILLED outer (valence) electron shell. For most atoms (1st row excluded—where 2 electrons is a “full” shell”), this is eight electrons. Atoms can gain or lose electrons to achieve an octet (8) of electrons. Ions • Ion: An atom that has either gained or lost an electron to achieve a stable octet of electrons. – Cation: an atom that has LOST electrons to form a positively charged ion. Example: Na Na+ + e– Anion: an atom that has GAINED electrons to form a negatively charged ion. Example: F + e- F- . All elements that form negatively charged ions have their name changed by adding “… ide” to the end. Thus, fluorine becomes a fluoride ion. Compounds • Binary compounds – Ionic compounds • Compound between non-metal and metal • Conducts electricity in aqueous solution – Molecular compounds • Between non-metal and non-metal Determining formula • Need to determine the stable ion for each atom, we write the positive ion first and the negative ion last • Take the charge of each element and “crossover” to give how the elements combine • If you have a factor of one another, can simplify • Step 1: Si4+ O2• Step 2: Si4+ O2- Si2O4 • Step 3: Si2O4 SiO2 Naming compounds • Naming of compounds are different depending on the type of compound (ionic and molecular) Naming compounds • When there are more than one element need to describe this in the naming. # of atoms Prefix # of atoms Prefix 1 mono 6 hexa 2 di 7 hepta 3 tri 8 octa 4 tetra 9 nona 5 penta 10 deca Rules for the Prefix System • ONLY use the Prefix system for non-metal/non-metal compounds— NEVER for ionic compounds! (Exceptions: Classical (ous/ic) system: Used for metal ions with more than two possibilities; also used on occasion for metalloid compounds. • If the first element named has only one atom, we do NOT use the Mono prefix—it is assumed the first element has one atom unless otherwise specified. • Compounds where the first element named is hydrogen are acids— they use an entirely different naming system (see later PPT). Note that acids are always aqueous solutions; if the element is a gas, it is named using the prefix system. Example: HCl (g) is called hydrogen chloride; HCl (aq) is called hydrochloric acid. • In some compounds, the vowel at the end of the prefix is dropped; this is done to make the name easier to say. Example: N2O dinitrogen monoxide (not monooxide). This is usually done when the second named element starts with a vowel (like oxygen). Homework • Pg38 • # 9(NOT #b, #c do Cl), • 13a,d,f, 15b,c,d, 18a,b,d,e,f • Draw the ionic form of (charge): –N F Al Be Ca B Some examples • Name – SO2 SO3 OF2 O2F2 • Write formula – Sulfur difluoride sulfur tetrafluoride – Sulfur hexafluoride disulfur difluoride Naming for ionic compounds • There is no use of prefixes. • The formula is based on the electron transfer between the two elements – Which is based on the ions • Remember that ionic compounds are more of a crystal lattice so the formula is just a formula unit Some examples • Name – LiCl KBr CaCl2 MgO • Write formula – Sodium fluoride barium bromide – Magnesium fluoride aluminium chloride Using the Stock system • Some elements can have more than one cation • This is used to identify which cation to use • For example copper(II) is Cu2+ and copper(III) is Cu3+ Polyatomic Ions • Different atoms bonded by covalent bonds to give an ion. • These are unit when placed in a compound they are treated as one unit • When naming these compounds you would follow the same rules as ionic compounds. Example • • + Ammonium NH4 2Sulfate SO4 • If these combine, the cross-over method would be used to give + 2• NH4 SO4 -> (NH4)2SO4 • Ammonium Sulfate Hydrogen Compounds • Compounds with Hydrogen are a little different • They can be acids, or compounds with hydrogen and carbon. • We will learn about simple acids in section 2.3 and the hydrogen and carbon compounds in later chemistry courses. Seatwork/Homework • Pg 55 all odd numbered letters and 6 • Naming sheets for compounds