Silver Nanoparticles (nanosilver) By Chris Coulter Main use • Antibacterial : – Anything that destroys bacteria or suppresses their growth or their ability to reproduce. • Antifungal: – Anything that destroys fungi or suppresses their growth or their ability to reproduce. Silver uses through history. • The Greeks used silver vessels to keep water and other liquids fresh. • Pioneers in American found that if they placed silver or copper coins in their casks of drinking water, it kept the water safe from bacteria, algae, etc. • In the Middle Ages, the wealthy stored and ate their food from silver vessels to keep bacteria from growing. This protected them from the full brunt of the plague. • Silver leaf was used to combat infection in wounds sustained by troops during World War I. • Settlers in the Australian outback suspend silverware in their water tanks to retard spoilage. • In the early 1800s, doctors used silver sutures in surgical wounds with very successful results. • Similarly silver dollars were put in milk to keep it fresh. • Prior to the introduction of antibiotics, Colloidal Silver was used widely in hospitals and has been known as a antibacterial for at least 1200 years. Applications • • • • • • Cosmetics Odor control Antimicrobial coatings Burn and Wound dressing Appliances Filters Soap • Silver particles penetrate into cells and prevent the breathing of virus, bacteria, mold, and fungus, ultimately killing them. • Antibiotics are effective against 12 kinds of bacteria at most. • Silver can kill about 650 kinds of germs including viruses that are unaffected by antibiotics. Odor Control - kills bacteria that cause odor – Effective against athletes foot? Deodorant Socks and insoles Antimicrobial coatings - Effective against resistant strains of bacteria • • • • • • Keyboards Phones Appliances Handrails Doorknobs Toilet seats – In Hong Kong a Nano SilverTitanium Dioxide coating (NSTDC) has been certified as effective in killing a wide range of bacteria, viruses and mold including the H1N1 flu virus. This coating will be applied to all surfaces touched in the Hong Kong metro rail system. • Paint – A research group at the City College of NY working with Rice University in Houston developed an antibacterial paint. – They tested it by leaving E.Coli overnight on a plain glass slide, one coated with regular paint, and one coated with nanosilver paint. • The nanosilver paint coated slide killed all of the bacteria. – This can be used in hospitals to cover counters and walls where there is a high risk of spreading germs. – Also very useful in homes. • Especially in bathrooms to keep germs and mold from breeding. Burn and Wound Dressing • Burns are very susceptable to bacterial infections. • Current silver burn gel contains enough silver to cause toxic effects. – Nano based silver burn gel contains 30 times less silver. Doesn’t cause the side effects (skin discoloration and cell damage) while still being effective against drug resistant microbes. • Blood Clotters. Appliances Samsung Silver Nano Washing Machine and Refrigerator. Silver ions released during wash and rinse cycles Clothes become antibacterial: killing odor caused by sweat or fungus for up to 30 days Samsung Silver Nano refrigerator A Silver Nano coating to the inner surfaces of refrigerator cause an anti-bacterial and anti-fungal effect. As air circulates, the coated surfaces allow the silver ions to kill the airborne bacteria. Filters • Cotton cloth dipped in a solution of silver nanowires and carbon nanotubes. • An electrical current supplied by a small solar panel kills 98% of bacteria in a single pass. • Filters about 80,000 times faster than filters that trap bacteria. • Also used in air filters to improve effectiveness. Problems and fears • Silver itself is classified as an environmental hazard by EPA because it is more toxic to aquatic plants and animals than any metal except mercury. – Nanosilver particles are small enough to cross through egg membranes and into fish embryos. • Wastewater – Silver nanoparticles destroy the benign species of bacteria that are used for wastewater treatment. – Silver nanoparticles may become concentrated over time. – Tests are being conducted to see long term effects. Other uses • Nano silver paste and ink – Printed Circuit Boards (PCB). • Low cost • Bendable • Paper Batteries – – – – Small Durable Long lasting Can be crumpled or folded with no loss of performance Paper Batteries • One dimensional structure helps ink stick strongly. • Paper super-capacitors may last through 40,000 chargedischarge cycles. – At least 10 times more than lithium batteries. • The high surface to volume ratio of paper gives it an advantage in uses like hybrid and electric cars because of it’s quick transfer of electricity. • Can be made into a paint to make walls into a battery. Any Questions?