Unit 2: Atoms and Bonding 2.76 Periodic Table Trends: 6. Families Textbook ch 7.7 -7.8 Big Idea 1: The chemical elements are fundamental building materials of matter, and all matter can be understood in terms of arrangements of atoms. These atoms retain their identity in chemical reactions. Students will be able to demonstrate understanding by laboratory investigation, analysis of data and creation of models. Learning Objectives SWBAT: : • Correlate the atomic properties of elements based on family with their chemical reactivity and physical properties Alkali Metals Group 1A elements Alkali metals are NEVER found pure in nature; they are too reactive (ALL react with water even moisture in the air) Metal +H2O metal hydroxide + H2(g) The reaction above very exothermic and Potassium, K can produce fire or explosion. reacts with Reactivity of these elements increases water and down the group must be Silvery appearance, soft enough to cut stored in with knife kerosene st Also have low 1 ionization energies. Most reactive metal on periodic table is in this group- Cs- cesium Fr- most unstable of the naturally occurring elements , highly radioactive Alkaline Earth Metals • Alkaline earth metals are less reactive than alkali metals • Alkaline earth metals are not found pure in nature; they are too reactive • 1st and 2nd ionization energies low • Harder, denser , and melt at higher temp than alkali metals – Be does not react with water or steam – Mg reacts slightly with water and more readily with steam – Ca and below follow this pattern: Ca +H2O Ca(OH)2 + H2(g) Uses: – Mg = sea water, light weight alloys for planes and trucks – Be = dark green form is Emerald. Light blue/green from is Aquamarine. – Sr = fireworks and flares Transition Metals Copper, Cu, is a relatively soft metal, and a very good electrical conductor. Mercury, Hg, is the only metal that exists as a liquid at room temperature Lanthanide & Actinide Series also called inner transition metals • F-block elements • Actinides: – ALL are unstable and radioactive • Lanthanides: – shiny- reactive metals – readily available thanks to technology Poor Metals • Al,Ga,In,Sn,Tl,Pb,Bi,Po are poor metals. • They are not very reactive and weakly posses properties • FYI: Note there is some debate about Po…some resources say it’s a semimetal …American Chemical Society calls it a poor metal (acs.org) . I won’t test you on this one. Properties of Metalloids or Semimetals They have properties of both metals and nonmetals. Metalloids are more brittle than metals, less brittle than most nonmetallic solids Metalloids are semiconductors of electricity Some metalloids possess metallic luster Silicon, Si – A Metalloid Silicon has metallic luster Silicon is brittle like a nonmetal Silicon is a semiconductor of electricity Other metalloids include: Boron, B Germanium, Ge Arsenic, As Antimony, Sb Tellurium, Te Nonmetals • Nonmetals is a family on the periodic table that includes the nonmetals that didn’t already fit in a different family. (halogens or noble gas) • Not to be confused when comparing all nonmetals to all metals by general characteristics (last PPT) Nonmetals H 1 1.00797 Nonmetals are poor Hydrogen conductors of heat and electricity Nonmetals tend to be brittle Many nonmetals are gases at room temperature Carbon, the graphite in “pencil lead” is a great example of a nonmetallic element. Examples of Nonmetals Sulfur, S, was once known as “brimstone” Graphite is not the only pure form of carbon, C. Diamond is also carbon; the color comes from impurities caught within the crystal structure Microspheres of phosphorus, P, a reactive nonmetal Halogens (a specific type of non metal Halogens are never found pure in nature; they are too reactive Halogens in their pure form are diatomic molecules (F2, Cl2, Br2, and I2) Note some debate about At…some resources place it as a metal… unstable and only micrograms have been produced so extensive testing impossible!- I won’t test you on this one. Chlorine is a yellow-green poisonous gas Noble Gases (a specific type of nonmetal) Noble gases are ONLY found pure in nature – they are chemically unreactive (mostly…see next slide) Colorless, odorless and unreactive; they were among the last of the natural elements to be discovered Neon lights Neon gas + electricity Noble Gases have been forced to react in lab • In 1962 1st noble gas compound synthesized by Neil Bartlett Today: • Xe forms three compounds: – XeF2 – XeF4 (at right) – XeF6 • Kr forms only one stable compound: – KrF2 • The unstable HArF was synthesized in 2000. XeF4 crystals References www.sciencegeek.net/Chemistry I modified the original PPTs to fit our needs in AP Chemistry. Our textbook: Brown, Lemay et all. AP edition chemistry, 13th edition, 2015