Chemical Formulas and Chemical Compounds Chapter 7 Review – Answers Pages 53 - 54 1. 2. C. The charge on each Fe In a stock name ion such as iron(III) sulfate, the roman number tells us ____. The result of C. Change the formula so changing a that it no longer subscript in a represents the correctly written compound it previously chemical formula represented. is to _____. Pages 53 - 54 3. The explosive TNT has the molecular formula C7H5(NO2)3. a. How many elements make up this compound? 4 elements b. How many oxygen atoms are present in one molecule of C7H5(NO2)3? 6 oxygen atoms c. How many atoms in total are present in one molecule of C7H5(NO2)3? 21 atoms d. How many atoms are present in a sample of 2 1023 molecules of C7H5(NO2)3? atoms 2 10 molecules 21 4.2 10 24 atoms molecule 23 Pages 53 - 54 4. How many atoms are present in each of these formula units? a. Ca(HCO3)2 11 atoms b. C12H22O11 45 atoms c. Fe(ClO2)3 10 atoms d. Fe(ClO3)2 9 atoms Pages 53 - 54 5. (see below) a. What is the formula for the compound dinitrogen pentoxide? N2O5 b. What is the Stock name for the covalent compound CS2? Carbon disulfide Pages 53 - 54 6. Some binary compounds are ionic, others are covalent. The types of bonding partially depend on the position of the elements in the periodic table. Label each of these claims as True or False; if False, specify the nature of the error. a. Covalently bonded binary molecular compounds typically form from nonmetals. True Pages 53 - 54 6. Some binary compounds are ionic, others are covalent. The types of bonding partially depend on the position of the elements in the periodic table. Label each of these claims as True or False; if False, specify the nature of the error. b. Binary ionic compound form from metals and nonmetals, typically from opposite sides of the periodic table. True Pages 53 - 54 6. Some binary compounds are ionic, others are covalent. The types of bonding partially depend on the position of the elements in the periodic table. Label each of these claims as True or False; if False, specify the nature of the error. c. Binary compound involving metalloids are always ionic. False; metalloids on the right of the stair-step line act as nonmetals in compounds Pages 53 - 54 8. Fill in the blanks in the table below. Compound Name Formula Aluminum sulfide Al2S3 Aluminum sulfite Al2(SO3)3 Lead(II) chloride PbCl2 Ammonium phosphate (NH4)3PO4 Pages 55 - 56 4. Tin has possible oxidation numbers of +2 and +4 and forms two known oxides. One of them has the formula SnO2. a. Give the stock name for SnO2. Tin(IV) oxide b. Give the empirical formula for the other oxide of tin. SnO Pages 55 - 56 5. Scientists believe that two separate reactions contribute to the depletion of the ozone layer, O3. The first reaction involves oxides of nitrogen. The second involves free chlorine atoms. Both reactions follow. When a compound is not stated as a formula, write the correct formula in the blank beside its name. a. _____(nitrogen monoxide) + O3 → NO NO2 (nitrogen dioxide) + O2 ______ b. Cl + O3 → ______ ClO (chlorine monoxide) + O2 Pages 55 - 56 6. Consider the covalent dinitrogen trioxide when answering the following: a. What is the formula for dinitrogen trioxide? N2O3 Pages 57 - 58 1. Label each of the following statements as True or False: True a. If the formula mass of one molecule is x amu, the molar mass is x g/mol. False b. Samples of two different chemicals with equal numbers of moles must have equal masses as well. True c. Samples of two different chemicals with equal numbers of moles must have equal numbers of molecules as well. Pages 57 - 58 2. How many moles of each element are present in a 10.0 mol sample of Ca(NO3)2? 10.0 mol calcium 20.0 mol nitrogen 60.0 mol oxygen Pages 57 - 58 3. Consider a sample of 10.0 g of the gaseous hydrocarbon C3H4 to answer the following questions. a. How many moles are present in this sample? 10.0 g mol 0.25 mol 40.0 g b. How many molecules are present in the C3H4 sample? 0.25 mol 6.02 10 molecules 23 1.50 10 molecules mol 23 Pages 57 - 58 3. Consider a sample of 10.0 g of the gaseous hydrocarbon C3H4 to answer the following questions. c. How many carbon atoms are present in this sample? 1.50 1023 molecules 3 carbon atoms 23 4.50 10 atoms molecule d. What is the percentage composition of hydrogen in the sample? g 4.0 H mol 100 10.0%H g 40.0 C3 H 4 mol Pages 57 - 58 4. The chief source of aluminum metal is the ore alumina, Al2O3. a. Determine the percentage composition of Al in this ore. g 54 Al mol 100 52.9% Al g 102 Al 2 O3 mol b. How many pounds of aluminum can be extracted from 2.0 tons of alumina? 4000 lbs ore 0.529 lb Al 2100 lb Al 1 lb ore Pages 57 - 58 5. Compound A has a molar mass of 20 g/mol, and compound B has a molar mass of 30 g/mol. a. What is the mass of 1.0 mol of compound A? 20 grams b. How many moles are present in 5.0 g of compound B? 5.0 g mol 0.17 mol 30.0 g c. How many moles of compound B are needed to have the same mass as 6.0 mol of compound A? 6.0 mol A 20 g A 120 g A mol A 120 g B mol B 4 mol B 30 g B Pages 59 - 60 1. Write empirical formulas to match the following molecular formulas: a. C2H6O4 CH O 3 2 b. N2O5 N O 2 5 c. Hg2Cl2 HgCl d. C6H12 CH2 Pages 59 - 60 2. A certain hydrocarbon has an empirical formula of CH2 and a molar mass of 56.12 g/mol. What is its molecular formula? 12.0 g g g 2 1.0 14.0 mol mol mol g 56.12 mol 4 g 14.0 mol C4H8 Pages 59 - 60 3. A certain ionic compound is found to contain 0.012 mol of sodium, 0.012 mol of sulfur, and 0.018 mol of oxygen. 0.012 mol Na 1 2 2 0.012 0.012 mol S 1 2 2 0.012 0.018 mol O 1.5 2 3 0.012 a. What is its empirical Na2S2O3 formula? b. Is this compound a sulfate, sulfite, or neither neither? Pages 59 - 60 5. Gas X is found to be 24.0% carbon and 76.0% fluorine by mass. a. Determine the empirical formula of gas X. 24.0 g C 2 mol C 1 g 2 12.0 mol 76.0 g F 4 mol F 2 g 2 19.0 mol CF2 Pages 59 - 60 5. Gas X is found to be 24.0% carbon and 76.0% fluorine by mass. b. Given that the molar mass of gas X is 200.04 g/mol, determine its molecular formula. g g g 12.0 2 19.0 50 mol mol mol g 200 mol 4 g 50 mol C4F8 Pages 59 - 60 6. A compound is found to contain 43.2% copper, 24.1% chlorine and 32.7% oxygen by mass. a. Determine its empirical formula. 43.2 g Cu 0.6803 mol Cu 1 g 0.6803 63.5 mol 24.1 g Cl 0.6808 mol Cl 1 g 0.6803 35.4 mol 32.7 g O 2.043 mol O 3 g 0.6803 16.0 mol CuClO3 Pages 59 - 60 6. A compound is found to contain 43.2% copper, 24.1% chlorine and 32.7% oxygen by mass. b. What is the correct Stock name of the compound in part a? Copper(I) chlorate Pages 61 - 64 1. Write formulas for the following compounds: a. Copper(II) carbonate CuCO3 b. Sodium sulfite Na2SO3 c. Ammonium phosphate (NH4)3PO4 d. Tin(IV) sulfide SnS2 Pages 61 - 64 2. Write the Stock names for the following compounds: a. Mg(ClO4)2 Magnesium perchlorate b. Fe(NO3)2 Iron(II) nitrate c. Fe(NO2)3 Iron(III) nitrite d. CoO Cobalt(II) oxide Pages 61 - 64 3. (see below) a. How many atoms are representd by the formula Ca(HSO4)2? 13 b. How many moles of oxygen atoms are in a 0.50 mol sample of this compound? 4 mol oxygen Pages 61 - 64 5. Following are samples of four different compounds. Arrange them in order of increasing mass, from smallest to largest. a. 25 g of oxygen gas b. 1.00 mol of H2O c. 3 1023 molecules of C2H6 d. 2 1023 molecules of C2H6O2 c, b, d, a Pages 61 - 64 6. (see below) a. What is the formula for sodium hydroxide? NaOH b. What is the formula mass of sodium hydroxide? 40 g/mol c. What is the mass in grams of 0.25 mol of sodium hydroxide? 10 grams Pages 61 - 64 7. 8. What is the percentage composition of ethane gas, C2H6, to the nearest whole number? 80% carbon, 20% hydrogen Ribose is an important sugar (part of RNA), with a molar mass of 150.15 g/mol. If its empirical formula is CH2O, what is its molecular formula? C5H10O5 Pages 61 - 64 9. Butane gas, C4H10, is often used as a fuel. a. What is the mass in grams of 3.00 mol of butane? 174 grams b. How many molecules are present in that 3.00 mol sample? 1.81 1024 molecules c. What is the empirical formula of the gas? C H 2 5 Pages 61 - 64 10. Napthalene is a soft covalent solid that is often used in mothballs. Its molar mass is 128.18 g/mol and it contains 93.75 % carbon and 6.25 % hydrogen. Determine the molecular formula of napthalene from this data. C10H8 Pages 61 - 64 11. Nicotine has the formula CxHyNz. To determine its composition, a sample is burned in excess oxygen, producing the following results: 1.0 mol of CO2 0.70 mol of H2O 0.20 mol of NO2 Assume that all the atoms in nicotine are present as products. a. Determine the number of moles of carbon present in the products of this combustion. 1.0 mol C b. Determine the number of moles of hydrogen present in the products of this combustion. 1.4 mol H c. Determine the number of moles of nitrogen present in the products of this combustion. 0.2 mol N Pages 61 - 64 11. Nicotine has the formula CxHyNz. To determine its composition, a sample is burned in excess oxygen, producing the following results: 1.0 mol of CO2 0.70 mol of H2O 0.20 mol of NO2 Assume that all the atoms in nicotine are present as products. d. Determine the empirical formula of nicotine based on your calculations. e. In a separate experiment, the molar mass of nicotine is found to be somewhere between 150 and 180 g/mol. Calculate the molar mass of nicotine to the nearest gram. C5H7N 162 g/mol