UNIT 3: BONDING WHAT IS BONDING??? 1.Combination of atoms to form a compound (with different properties) 2. Determined by electrons in atoms 3. Why bond? To increase stability To decrease energy To fill valence!! 4. A balanced combination of positive and negative ions. 5. Simplest whole number ratio OCTET RULE Chemical compounds form so that each element has a full octet of electrons in its highest energy level. This can happen through gaining, losing, or sharing electrons. AGENDA 11/17/14 Review Unit 5 Tests Redo policy Before Thanksgiving Break? Review Ionic Compounds Properties Continue Puzzle Piece activity Let’s Clarify the directions HW: Finish analysis questions for Activity TYPES OF BONDING Ionic Bond The chemical bond resulting from electrostatic attraction between positive and negative ions. Metals tend to lose electrons and form cations. Nonmetals tend to gain electrons and form anions IONIC COMPOUND PROPERTIES Solid state is a crystalline structure Hard, brittle solids High melting point NaCl Do is 801oC not conduct electricity as solids Do conduct as liquids and solutions Not discreet molecules, instead called formula units Puzzle Method Identify charges of both the cation and the anion. Collect puzzle pieces that correspond to the ions. Adding more of only those charges, continue adding pieces until you have a complete and stable compound. EXAMPLES…. Sodium Oxide Calcium Sulfide Aluminum Chloride LET’S CLARIFY Each pair needs new puzzle pieces The goal of fitting the pieces together is to make a complete rectangle or square. Cations can only bond with anions!! Your job is to make 20 combinations Do Not try the Naming Yet!!! AGENDA 11/18/14 Finish Formula Writing Lab Homework for tomorrow Go Over Unit 5 Test Collect Formula Writing Lab (3 and 8) 1 per group Notes on writing and naming Ionic Compounds INTRO TO FORMULA WRITING LAB Meet with your lab partners Compare answers to analysis questions , and your conclusions. Determine which of the two labs you will turn in. Both partners names should be on the lab. WHITE BOARDS ARE BACK!! Get into your white board groups One marker per group PRACTICE FORMULA WRITING Write the correct formula for the following cation and anion pairs: 1. 2. 3. 4. 5. Na+ and ClMg+2 and FC-4 and H+ Ag+3 and O-2 Ag+3 and N-3 Bonus Question: Is there a pattern you notice between the charges on the ions and the subscripts in the formulas? CRISS-CROSS METHOD Identify charges of both the cation and the anion. Switch the charge value to be the opposite ion’s newest subscript. Repeat for the other ion. Example: Ag+3 Ag2O3 O-2 ONE EXCEPTION Ag+3 and N-3 Do the criss-cross method If the subscripts can be reduced…reduce them! NAMING AN IONIC COMPOUND… Cation is always named first Cation take the name of the element Transition metals use the formula to find the charge (Roman numeral = charge) Anion Monatomic (only one element) end in –ide EXAMPLES… CaF2 calcium fluoride Li2S Lithium sulfide FeCl2 (This is a transition metal) Iron (II) chloride (ferrous chloride) FeCl3 (This is a transition metal) Iron (III) chloride (ferric chloride) MORE EXAMPLES… PtO2 Platinum CuBr Copper (I) bromide (cuprous bromide) Zn3N2 Zinc (IV) oxide (II) nitride (Zn is almost always +2) Sn3P2 Tin (II) phosphide (stannous phosphide) MORE PRACTICE… Ca(OH)2 Calcium hydroxide NaSCN Sodium thiocyanate Al2(CrO4)3 Aluminum chromate Mg(NO2)2 Magnesium nitrite PRACTICE, PRACTICE, PRACTICE… NH4Cl Ammonium Au2(CO3)3 Gold (III) carbonate Pb(CN)4 Lead chloride (IV) cyanide FePO4 Iron (III) phosphate AGENDA 11/18/14 Review Ionic Formula Writing Notes on Polyatomic Ions Naming Notes on naming Covalent Compounds Properties of covalent compounds HW: Naming monatomic and polyatomic formulas COVALENT MOLECULES Bonds that exist between two non-metals Two anions!! Both atoms want to gain electrons so they share electrons in bonds to complete their octet. MOLECULAR SUBSTANCES These exist between two different anions. Ex: Carbon monoxide, CO, C==O Many different solid forms, not crystalline Relatively low melting and boiling point. Poor conductors in all states! Do not dissolve in water very well. Organic compounds are examples of molecular substances. NETWORK SOLIDS Bonds between one non-metal element Ex: C60 Buckminsterfullerene Buckyballs Diamond, Graphite, and Carbon nanotubes NETWORK SOLIDS Different shapes in the solid form. High melting and boiling points Often hard and brittle Non-conducting solids Do not dissolve in water well NAMING COVALENT COMPOUNDS First element using full element name 2. Second element name as if it were an anion (-ide) 3. Use prefixes to denote # of atoms present for both of the elements - exception: mono is NOT used for the first element. Ex: CO Carbon monoxide Mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca 1. PREFIXES One mono Two di Three tri Four tetra Five penta Six hexa Seven hepta Eight octa Nine nona Ten deca EXAMPLES: N2O3 dinitrogen trioxide N2O5 Dinitrogen pentoxide Xenon tetrafluoride XeF4 Oxygen dichloride OCl2 Diphosphorus trioxide P2O3 AGENDA 11/20/14 Review all types of naming Notes on metallic substances Practice Practice Practice HW: Naming covalent compounds NAME ALL OF THESE CORRECTLY!! 1. S2F3 4. PbO2 2. BeS 5. LiOH 3. CO2 6. NCl3 METALLIC BONDS: WHEN METALS COME TOGETHER METALLIC BONDING Metallic bonds are described as a cluster of positive metal ions surrounded by a sea of their shared valence electrons. Metallic Bonding is the type of bonding found in metallic substances. The positive ions remain fixed in a crystal lattice, while the loosely-held valence electrons move freely throughout the entire crystal. Melting/boiling points between covalent and ionic compounds. Not soluble in water. A Model of Metallic Bonding The positive metal ions are surrounded by a huge cloud of free flowing electrons. Insert figure 8.9 PROPERTIES OF METALS EXPLAINED BY THE ESEA… Metals are great conductors of electricity. Why? Electricity can be described as a movement of charged particles, so if you have mobile charged particles present then electricity can flow. For metals, the sea of electrons is basically a cloud of mobile charged particles. METALS ARE MALLEABLE AND DUCTILE Malleable: Can be beaten into a thin sheet Ductile: Can be pulled into a wire. Why? If you add stress you force like charges closer together. They repel each other and move apart, but instead of shattering, the particles rearrange with the sea of electrons. HITTING A METAL LAST PROPERTY: METALS ARE SHINY! Metals are shiny!! Why? The valence electrons move within the “sea” around the positive ions of the metals. When the light wave hits the electrons in the “sea”, the light “bounces” off of them or is reflected back by the electrons. When this light hits our eyes, the appearance we see is that the metal is shiny. SHINY METALS: