TYPES OF CHEMICAL REACTIONS – PART A Dr. Chin Chu River Dell Regional High School CHEMICAL CHANGES (REACTIONS) ORGANIZATION OF CHEMICAL REACTIONS C + O O O C O C + O2 CO2 • Chemical reactions are merely rearrangements of atoms into different combinations called compounds. There got to be some patterns that can be categorized into different types. UNIT OBJECTIVES There are millions of reactions. Can’t remember them all. Fall into several categories. Will learn 5 types. Will be able to predict the products. For some we will be able to predict whether they will happen at all. Will recognize them by the reactants EXERCISE Balancing the following chemical equations: 1. aluminum(s) + iodine(s) aluminum iodide(s) 2. sulfur trioxide + water sulfuric acid (H2SO4) 3. lithium oxide + water lithium hydroxide Do you see the patterns? SYNTHESIS REACTIONS Called also combination reactions General Equation: A + B Animation: 2 elements, or compounds combine to make one compound. Mg +O2 MgO SO2 + H2O H2SO3 TYPES OF SYNTHESIS REACTIONS Combination of elements Element + element compound 2Hg + O2 2HgO 9Mg + 3N2 3Mg3N2 Nonmetalic Oxides + water acid SO2 + H2O H2SO3 P4O10 + 6H2O 4H3PO4 TYPES OF SYNTHESIS REACTIONS Metalic oxides + water base MgO + H2O Mg(OH)2 Na2O + H2O 2NaOH Metallic oxides + nonmetallic oxide salt MgO + CO2 MgCO3 CaO + SiO2 CaSiO3 EXERCISE Watch the following video clips and write balanced equations: 1. Thermal decomposition of copper(II) nitrate When heated, solid copper(II) nitrate decomposes into copper(II) oxide, nitrogen dioxide and water vapor. 2. Thermal decomposition of zinc carbonate When heated, solid zinc carbonate decomposes into solid zinc oxide and carbon dioxide gas. Do you see the patterns? DECOMPOSITION REACTIONS Substances break apart. General Form: AB A + B Animation: Decomposition reactions are reverse of synthesis, with exceptions. DECOMPOSITION REACTIONS Special Cases Metal Chlorate metal chloride + oxygen 2KClO3 2KCl + 3O2 Metal bicarbonate metal oxide + carbon dioxide + water 2NaHCO3 Na2O + 2CO2 + H2O DECOMPOSITION REACTIONS Special Cases Most oxides are stable, only few decompose: 2HgO Hg + O2 Electrolysis of molten salt (decomposition by electricity) is the only means for decomposition for some substances: 2H2O 2H2 + O2 2NaCl 2Na + Cl2 DEMOS 1. The methane bubble 2. The perfect combution (ethanol) http://www.youtube.com/watch?v=Lb-KB_BshUc&NR=1 3. Burning of methanol Do you see the patterns? COMBUSTION REACTIONS A compound composed of only C, H and maybe O is reacted with oxygen If the combustion is complete, the products will be CO2 and H2O. If the combustion is incomplete, the products will be CO and H2O. EXERCISES C4H10 + O2 (complete combustion) C4H10 + O2 (incomplete combustion) C6H12O6 C8H8 + O2 (complete combustion) +O2 (incomplete combustion) MORE EXERCISES Write a balanced equation for the complete combustion of each of these compounds. a) acetic acid, HC2H3O2 c) glycerol, C3H8O3 b) decane, C10H22 d) sucrose, C12H22O11 Write a balanced equation for the incomplete combustion of each of these compounds. a) glycerol, C3H8O3 c) acetic acid, HC2H3O2 b) glucose, C6H12O6 d) acetylene, C2H2