GFS Chemicals, Inc. Innovation and Commercialization through Chemistry ISO 9001:2008 Certified Agenda •Introduction •Reagents-Catalog •Inorganics •Organic Chemical Division •Electronic Chemicals •Discussion/Action Decades of both chemical and engineering experience allow GFS to address opportunities in highly specialized custom inorganic and organic manufacturing. Background •1928-Founded, Columbus Ohio. Perchlorate salts defined early business. •Third generation privately held company. •Global Business. •100 Employees •Commercial quantities from gram samples up to metric ton quantities. •Customer base ranges from development companies to Fortune 500 companies. International Operations • Sourcing Operations in • Shanghai China • Serving over 80 countries worldwide • www.GFSInternational.com – Japanese – German – French – Spanish Customer Support • 96%+ of orders ship on time • GFS maintains inventory for the most popular reagents • 95% Lead Time Accuracy • 80 Years excellent product quality • Knowledgeable/Technical Staff • Customer Satisfaction scores are among the highest in the industry Customer Benefits • Problem Solving Chemists Complement Your Project Team • Supporting Major Industry Around the Globe • Manufacturing High Quality Chemicals up to metric tons • Custom Packaging, Drying and Production • Competence • Your Global Sourcing artner Industries Served • • • • • • • • • • • Environmental Semiconductor Pharmaceutical Flavor & Fragrance Superconductivity Petrochemical Agricultural Automotive Defense Biotechnology Power and Energy (Fuel Cells, Batteries, etc) Industries Served • • • • • • • • • Electronics Chemicals Aerospace Polymers Coatings Catalysts Optics Contract Manufacturing Water treatment and Analysis • Beverage/Dairy • Quality Control Laboratories Safety and Environment • GFS is a Tier II Chem Stewards organization focused on safety improvement practices and waste minimization, recovery policies and controls • Selected Employees are DOT, IATA and IMO certified to support all modes of material logistics to ensure safe and legal shipments world wide. Compliance and Quality • GFS organic production operations are a zero discharge facility compliant with all local and federal EPA regulations • We adhere to ISO 9001:2008 standards for quality practices and have been ISO certified since 1997 GFS Catalog Operations • 70,000 Sq Ft. Operation, Manufacturing and Distribution Center • Repack and Fulfillment Center • Private Label Operation • Amco Clear Water Analysis Division • Bottling Operations • Quality Control Labs • Manufacturing and Sourcing over 4000 Analytical Reagents Inorganic Bulk Manufacturing U.S. Based Inorganic Product Development and Manufacturing Bulk Inorganics • Lithium Perchlorate (Battery Electrolyte & Organic Catalyst) • Lithium Carbonate, 99.998% (Lithium Crystals & Organic Catalyst) • Lithium Iodide (Battery Electrolyte & Organic Catalyst • Precious Metal Salts (Silver Nitrate) • Ammonium Borane (OSU & EBA &D) Inorganic Specialties • • • • • Perchloric acid & Salts Ceric Ammonium Nitrate (Etchants & Catalysis) Purified compounds for metal complexes Ultra dry salts for moisture sensitive applications Rare Earths, Lithium, Sodium and Magnesium salts & solutions • Precious metal ion exchange resins Bulk Inorganic Salts • • • • • • Nitrates Sulfates Chlorides Perchlorates Carbonates Periodates • • • • • Oxalates Acetates Formates Phosphates Citrates Specialty Inorganics • Rubrene (OLED & Dye) • Anhydrous Cerous Chloride (Fuel Cell & Grignard Initiator) • Hydroxyquinoline, Aluminum Salt (OLED) • Polyoxometalate complexes Organic Manufacturing Leaders in the development and commercialization of specialty alkynes and derivatives Markets Served • • • • • • • Electronics/Semiconductors Pharmaceutical/Biotechnology Agribusiness (Pesticides $Herbicides) Polymers Catalysts Flavors & Fragrances Dyes & Colorants Product Offering • GFS Chemicals remains focused on a core set of synthetic methodologies • In support of alkyne production, we offer down stream intermediates such as olefins, heteroaromatics and heterocycles • We offer over 2000 organic chemicals in our product base Core Synthetic Chemistry Na & Li/Liquid Ammonia Chemistry – – – – Alkylations Aminations Reductions (Birch, trans) Ethynylations Halogenations – Brominations – Chlorinations – Iodinations Core Synthetic Chemistry Alkyne Chemistry – – – – – – Eliminations Ethynylations Sonogashira Glaser Coupling Cadiot-Chodkiewicz Click Chemistry Core Synthetic Chemistry • Organometallic Chemistry – Grignard – Alkyl lithium – Coupling (Suzuki, Stille, Negishi, Kumada) – Heck Reaction – LI/NA Amide – Cis-reductions Core Synthetic Structures • Alkynes – – – – – – – Aromatic Terminal Internal Alcohols Ketones Acids Conjugated • Olefins – – – – – – – Cis/trans En-yne Cyclic Grignards Vinyl Aryl Alkyl Core Synthetic Structures • Halogenated Organics • Heteroaromatic – – – – Alkynes Olefins Alkyl Aromatic – – – – – – Quinolines Indoles Pyrimidines Bipyridines Phenanthrolines Terpyridines Electronics Chemicals GFS Serves a Range of Electronics Applications •Conductive Inks •Thermally Conductive Interface Materials •Thermal Imaging •Electro-Optic Materials •Metal Polishing •Photo Resists •OLED’s Function/Technology Function Technology Chromophores Alkynes Photo Chromic Indicators Acetylene Oxidation Reduction Indicators Phenanthrolines, Bipyridine Fiber Optics Heterocyclic Amine Ligands Thermally Conductive Interface Materials Alkynes Electroplating Chemicals Alkynes Electro-optics Materials Alkynes OLED’s Bis tips ethynl pentacene Photo Voltaics Alkynes Electronics Products 109 294 770 1597 2,2’-bipyridine Bathocuproine, Sulfonated, Sodium Salt 4,4-dicarboxy2,2’biquinoline Potassium Salt Tris(Bathophanthroline) Ruthenium (II) Chloride 3110 3282 3287 3294 1,1-diphenyl-2-propyn1-ol 2-phenyl-3-butyn-2ol 1-phenyl-2-propyn-1ol Propargyl Acrylate 3340 3395 3721 3906 (Trimethylsilyl) Acetylene 3-amino-3-methyl-1butyne Tert-butyl Magnesium Chloride 3-methyl-1-hexyne 3979 5195 5515 5382 Hexylmagnesium Bromide Isopropylmagnesium Bromide 3-ethyl-1-heptyne 2,4,6-Tri(4-pyridyl)1,3,5-Triazine Acetylene Chemistry O O HC CH R1C CR2 (CH2)9CH3 Propargylic Amines N N H H2N N H NH Specialty Thiophenes Br •OLED/Conductive Polymer Applications •Pharma and Biotech Applications S S O H O O H S S O R S Why GFS Chemicals •Broad Product Range •Experienced •Customer Focus •Customer Service Discussion/Action • Questions • Areas of interest or cooperative effort opportunities • Consider GFS Chemicals for your future Specialty Organic Chemicals needs