Chapter 10 Worksheet Examples Worksheet: MOLAR MASS Example: Calculate the molar mass (gram molecular weight) of a mole of iodine, I2. Unit for molar mass I = 126.9(2) = 253.8 g mol From the formula of the compound From the mass off of the periodic table. Example: Calculate the molar mass of a mole of aluminum sulfate (Al2(SO4)3). From the masses off of the periodic table. From the formula of the compound Al = 26.98 (2) = 53.96 S = 32.07 (3) = 96.21 Unit for molar mass O = 16.00 (12) = 192.00 ---------------------------------------g add together = 342.17 mol Worksheet: MOLE AS A UNIT OF MASS Example: What is the mass of 5.00 moles of water? X 90.1 g H2O 18.02 g/mol 5.00 mol Molar Mass Calculation H = 1.01 (2) = 2.02 O = 16.00 (1) = 16.00 -----------------------------= 18.02 g/mol Molar mass From the problem Example: What is the mass of 0.50 moles of calcium carbonate? X 50.045 g CaCO3 100.09 g/mol 0.50 mol From the problem Molar Mass Calculation Ca = 40.08 (1) = 40.08 C = 12.01 (1) = 12.01 O = 16.00 (3) = 48.00 -----------------------------Molar mass = 100.09 g/mol Example: How many moles of calcium chloride are in 333 grams of calcium chloride From the problem 333 g CaCl2 110.98 g/mol 3.00 mol Molar Mass Calculation Ca = 40.08 (1) = 40.08 Cl = 35.45 (2) = 70.9 -----------------------------= 110.98 g/mol Molar mass ÷ Worksheet: AVOGADRO’S NUMBER Example: How many molecules of water are there in 3.00 moles of water? X 1.806x1024 mcl H2O 6.02x1023 mcl/mol 3.00 mol The number of atoms/molecules in one mole is always 6.02x1023 From the problem Example: How many moles of neon are there in 2.408x1024 atoms of neon? From the problem 2.408x1024 atm Ne 6.02x1023 atm/mol 3.99 mol The number of atoms/molecules in one mole is always 6.02x1023 ÷ Worksheet: MOLAR VOLUME OF A GAS Example: What is the volume, in liters, of a 2.00 mole sample of methane (CH4) at STP? X 44.8 L CH4 22.4 L/mol 2.00 mol From the problem The number of liters in one mole is always 22.4 Example: How many moles of ethane (C2H6) are there in 5.60 liters of ethane? From the problem 5.6 L C2H6 22.4 L/mol 0.25 mol The number of liters in one mole is always 22.4 ÷ Worksheet: MIXED MOLE PROBLEMS Molar mass is g/mol and you find grams from the periodic table. We’ve done problems of one step. Moles to a unit or unit to moles. Now we can do multi step problems using this picture to help us see where we need to go next. This picture is a summary of all of the problems we have done up to this point along with helpful hints to units and numbers. The better you understand this the easier mole conversions will be. Example: What would be the volume in liters of 40.36 grams of neon at STP? From the problem 40.36 g Ne 20.18 g/mol 2.00 mol From the periodic table The number of liters in one mole is always 22.4 We’re not to liters yet… 44.8 L Ne 22.4 L/mol 2.00 mol X ÷ Example: How many molecules would there be in 56 liters of carbon dioxide at STP? From the problem The number of liters in one mole is always 22.4 56 L CO2 22.4 L/mol 2.5 mol 1.505x1024 mcl CO2 6.02x1023 mcl/mol 2.5 mol We’re not to molecules yet… The number of atoms/molecules in one mole is always 6.02x1023 X ÷ Worksheet: PERCENT COMPOSITION & FORMULAS Example: Calculate the percent composition of sodium hydrogen carbonate (NaHCO3)? Step 1 – find molar mass of the compound. Step 2 – divide mass of each element by molar mass. Step 3 – multiply answers by 100%. Molar Mass Calculation Na = 22.99 (1) = 22.99 H = 1.01 (1) = 1.01 C = 12.01 (1) = 12.01 O = 16.00(3) = 48.00 ---------------------------------------------- = 84.01 g/mol 22.99 100% 84.01 27.37% Na 1.01 100% 84.01 1.20% H 12.01 100% 84.01 14.30%C 48.00 100% 84.01 57.14%O Example: Which pair of molecules has the same empirical formula? a) C2H4O2 CH2O c) NaCrO4 b) C6H12O6 Molecular formula CH2O Empirical formula d) Na2Cr2O7 These two can not be “reduced”. An empirical formula is similar to a reduced fraction. Example: Calculate the empirical formula for a compound with 67.6% Hg, 10.8% S, 21.6% O? Step 1 – change percents to grams (assume we have 100 gram sample then percents are the number of grams). Step 2 – change the grams to moles. Step 3 – divide all answers by the smallest number (of the answers). Step 4 Step 4 – the results become the subscripts for the formula. Step 3 10.8 g 21.6 g Hg S O 200.59 g ÷ Step 2 67.6 g mol 0.34mol 1 0.34mol 32.07 g mol 0.34mol 1 0.34mol ÷ Step 1 HgSO4 16.00 g mol 1.35mol 4 0.34mol Example: Find the molecular formula of ethylene glycol, which is used as antifreeze. The molecular mass is 62g/mol and the empirical formula is CH3O? Step 1 – Find the empirical formula mass (EFM) Step 2 – Divide the molar mass (from problem) by the EFM to get the multiplier. Step 3 – Use the multiplier to determine the subscripts by multiplying each subscript by the multiplier. Step 1 EFM Calculation C = 12.01 (1) = 12.01 H = 1.01 (3) = 3.03 O = 16.00(1) = 16.00 ---------------------------------------- =31.04 g/mol Step 3 Step 2 62 2 32.01 MULTIPLIER C2H6O2