Course: PCLS Unit: Kinetics & Thermochemistry Dates: 11/24-12/5 1 The unit exam is scheduled for 12/4 & 12/5. Learning Objectives: 6.1: Interpret experimental data on reaction rates 6.2: Identify the requirements for a successful chemical reaction using the model of collision theory. 6.3: Describe the factors that can change the rate of a reaction and explain how they increase or decrease the rate. 7.1: Describe temperature and heat flow in terms of the motions of molecules 7.2: Define and interpret exothermic and endothermic chemical processes using models showing relative energies of reactants and products 7.3: Explain how the energy of a reaction depends on the processes of bond breaking and bond making 7.4: Use calorimetry to determine enthalpy of reaction (Q=cm ΔT) Student Outcomes: Collect data on reaction rates Interpret reaction rate data graphically Explain the process of heat flow and its relationship to temperature Interpret energy level diagrams to determine if reactions are exothermic or endothermic Draw molecular diagrams to explain bond-making and bond-breaking processes in a chemical reaction Use mathematical reasoning to determine enthalpy of a reaction Unit Topics: Collision theory Reaction rates Energy (Exothermic & endothermic reactions, and bond energy) Chemical Processes Calorimetry Topic Objectives: 1. Describe the events that must take place if a successful reaction is to occur. 2. Define “reaction rate” and provide an example. 3. Identify and explain the factors that affect reaction rates and how they affect the rates. 4. Explain the difference between temperature and heat. 2 5. Describe the elements of the thermochemical universe. 6. Compare and contrast endothermic and exothermic processes. 7. Construct and interpret energy diagrams (reaction rate graphs) including relative energies of reactants and products. 8. Draw and explain what happens to the energy when chemical bonds are broken and when they are formed. 9. Identify the amount of energy contained in simple molecular bonds. 10. Explain the concept of specific heat. 11. Solve calorimetry problems using Q = cm ΔT Unit Labs & Activities: Embedded in the work packets are practice problems, short investigative labs & activities. ***DO NOT DO THIOSULFATE ROSES*** Textbook Readings: Hewitt: Ch. 13, p. 337-350 Glencoe: Ch. 15; Sections 1-3 Problems (Glencoe): p. 521-522 #4-11 p. 525 #12-15 p. 528 #16-22 p. 533 #26-31 Section Review Summaries: p. 551 Additional Problems: p. 552 #53-57, 62-67, and 69-73 Online Resources Collision Theory http://themadscientist.weebly.com/kinetics.html Reaction Rates http://themadscientist.weebly.com/reaction-rates.html Thermochemistry http://themadscientist.weebly.com/energy.html Heat vs. Temperature 1. Video: Inflation of airbags in cars 2. Zonal Education: Heat & Temperature 2a. BrainPOP! Heat (Login: SAS1912; password: Shanghai) 3 3. Physics Classroom: Thermal Physics (Complete lesson 1; a, b, c & d) Endothermic vs. Exothermic 4. Chemguide: Chemical Energetics 5. WISC Online: Energy in chemical reactions 6. Video: Endothermic & exothermic reactions (1) http://youtu.be/L-G7pLufXAo and (2) http://youtu.be/idxf-4BKRAI Calorimetry 7. Physics Classroom: Calorimetry 8. Video: http://youtu.be/SAR-5wdQKSY Enthalpy 9. WISC Online: Enthalpy Bond Energy 10. Bond Energy Powerpoint & Corresponding Worksheet 11. Videos: http://youtu.be/o8HF-kdQuys 12. Bond Enthalpy http://www.avogadro.co.uk/h_and_s/bondenthalpy/bondenthalpy.htm 13. Bond Energies http://chemwiki.ucdavis.edu/Theoretical_Chemistry/Chemical_Bonding/General_Principl es/Bond_Energies 14. Energy changes in chemical reactions http://www.bbc.co.uk/schools/gcsebitesize/science/add_edexcel/chemical_reactions/en ergychangesrev2.shtml 4 Pacing Calendar (November 24-December 5) Monday 24(1B) Exam 3 Objectives 6.2 & 6.3 Tuesday 25(2A) Exam 3 Objectives 6.2 & 6.3 Wednesday 26(2B) Quiz: 6.2 & 6.3 Objectives 7.1 & 7.2 Thursday 27(3A) Quiz: 6.2 & 6.3 Objectives 7.1 & 7.2 Friday NO SCHOOL 1(3B) Quiz: 7.1 & 7.2 Objectives 7.3 & 7.4 2(4A) Quiz: 7.1 & 7.2 Objectives 7.3 & 7.4 IDP FINAL DUE 3(4B) All quizzes should be taken by now. IDP FINAL DUE 4(1A) Exam 5(1B) Exam 8(2A) Project Poster 9(2B) Project Poster 10(8P) Gallery Walk *Ideally, you should master two objectives by the end of each class. You are allowed to move at your own pace. You do not have to take the quizzes on the day listed, but you cannot take Quiz 2 without completing Quiz 1. All quizzes should be completed by December 3. You may come to me for review, discussion, clarification, questions, or whatever you need to understand the material. You have to come prepared to ask questions and demonstrate that you have reviewed the readings, tutorials, videos, and attempted to work the problems in the packets.