Semester Exam Review These are all the review questions from our 5 exams. Before using a bunsen burner, be safe by making sure your… • Hair is tied back; ID badge is not dangling, etc. What piece of measurement equipment have we used that does not require you to estimate a digit? • electronic balance What must be on file for all chemicals in the stockroom? • MSDS – material safety data sheet What is this piece of equipment called? • Erlenmeyer flask Which of these numbers has the most significant figures? 8.020 E -5 60,400 .0000204 5.4 x 106 • 8.020 E -5 (4 SF) Perform the following calculation and express your answer to the proper number of significant figures: 338.715 mL - 241.6 mL • 97.1 mL (round to tenths place) Perform the following calculation and express your answer to the proper number of significant figures: 14.8 g / 27.01mL • 0.548 g/mL (3 S.F.) Perform the following calculation and express your answer to the proper number of significant figures: 11.2 cm x 1.20 cm x 1.178 cm • 15.8 cm3 Convert 12.5 g into ounces (1 ounce = 28.35 g) • 0.441 ounces Which of the following units would be used to express a density? cm2 g/m kg/mL L • Kg/mL (mass/volume) Iron has a density of 7.87 g/mL. What would the volume of a 3.0 g piece of iron be? • 0.38 mL Change this number to scientific notation: 7000 g • 7E3g or 7 x 103 g (1 S.F.) What volume in mL would you record from this graduated cylinder? • 103.62 mL (5 S.F.) Perform the following calculation and express your answer to the proper number of significant figures: 3.18 E -5 g • 4.5 x 102 g/mL / 7.0 E -8 mL or 450 g/mL Name 1 extensive physical property • Mass, length, volume, etc. Which of these properties could be used to identify an unknown substance? Length density weight volume • Density (an intensive property) All pure substances must be either an _______ or a _______ • Element or compound A mixture of sand and salt could be separated using their differences in ______ • solubility A mixture of water and alcohol could be separated using this technique • distillation A mixture of sand and water could be separated using this technique • filtration What is the frequency of light with a wavelength of 560. nm? •5.36 E 14 Hz Calculate the energy of a photon with a frequency of 7.35 E 8 Hz •4.87 E -25 J Which of the following photons has the highest frequency? l=700 nm l=3.5 E -7 nm n=8.2 E 14 Hz •l=3.5 E -7 nm Which of the following photons has the least energy? l=700 nm l=3.5 E -7 nm n=8.2 E 14 Hz •l=700 nm Which of the following photons would be visible? l=275 nm l=645 nm l=3.2 E -11 m •l=645 nm (between 400 and 700 nm) Calculate the energy of a photon with a wavelength of 4.72 E -6 m •4.21 E -20 J Which scientist is credited with discovering the nucleus? • Rutherford Which scientist studied experiments with light to describe the orbits (or energy levels) where electrons exist • Bohr Which scientist proved the existence of subatomic particles? •Thomson (discovery of negatively charged patrticles) The existence of _________ disproved Dalton’s theory that all atoms of an element were identical. • isotopes Set up your white board like this # protons # neutrons # electrons For the following atoms or ions, give the numbers of protons, neutrons, and electrons. a neutral atom of manganese with a mass number of 55 • 25, 30, 25 argon-41 • 18, 23, 18 a potassium-39 cation with a +1 charge • 19, 20, 18 A neutral atom of beryllium with a mass number of 9 • 4, 5, 4 A +1 potassium cation with a mass number of 39 • 19, 20, 18 platinum-194 • 78, 116, 78 hydrogen-3 • 1, 2, 1 a -3 anion of arsenic-75 • 33, 42, 36 88Sr2+ 38 • 38, 50, 36 Write the electron configuration for the element potassium •1s22s22p63s23p64s1 Write the electron configuration for the element titanium •1s22s22p63s23p64s23d2 Write the noble gas configuration for the element rubidium •[Kr]5s1 Write the orbital notation for the element carbon •↑↓ ↑↓ 1s 2s ↑ ↑ 2p . What element is in group 6 of period 4? •Cr What element in period 4 makes an ion with a -2 charge? •Se What element has 4 valence electrons in the 2nd energy level? •C What halogen is located in period 4? •Bromine What charge would the ion of an alkaline earth metal have? •+2 A group on the periodic table contains the most reactive metals. How many valence electrons do these elements have? •1 (alkali metals) Which of the following elements experiences the most shielding? aluminum mercury antimony rubidium •Hg - 5 energy levels of shielding Which of the following elements would have the smallest atomic radius? As •As Ag Cr K ___________ is the tendency of an element to attract shared electrons in a covalent bond. •Electronegativity Which of the following elements would have the lowest ionization energy? Rb •Rb Sr Na Li Which of the following elements would have the highest ionization energy? K •Kr Ca As Kr Which of the following elements has the lowest electronegativity? Si •Sr Sr Br O Which of these elements would make a covalent bond with nitrogen? Al •C Mg Ba C Which of these elements would make an ionic bond with chlorine? O •Li F Li Xe Polyatomics: Charges PO4-3 PO3-3 BO3-3 AsO4-3 SO4-2 SO3-2 CO3-2 CrO4-2 NO3-1 NH4+1 NO2-1 ClO3-1 ClO2-1 BrO3-1 OH-1 CH3COO-1 HCO3-1 CN-1 Polyatomics: How many oxygens? BO3 CO3 NO3 PO4 SO4 ClO3 CrO4 4 oxygens 3 oxygens These are the formulas for the ions with –ate” endings. With one less oxygen, they would be “-ite” ions. AsO4 BrO3 5 ions don’t follow this: Cyanide CN-1 Hydroxide OH-1 Bicarbonate HCO3-1 Acetate CH3COO-1 Ammonium NH4+1 Write the formula for the only polyatomic anion below: ammonium bicarbonate sulfide bromide •HCO3- What polyatomic ion is this: NO2 •nitrite What polyatomic ion is this: -2 SO4 •sulfate What polyatomic ion is this: OH •hydroxide Write the formula for ammonium chloride •NH4Cl Write the formula for sodium chromate •Na2CrO4 Write the formula for calcium cyanide •Ca(CN)2 What is the name of this chemical: SrO •Strontium oxide What is the name of this chemical: Al(BrO3)3 •Aluminum bromate What is the name of this chemical: Fe(ClO3)3 •Iron (III) chlorate Write the formula for trinitrogen monoxide •N3O Write the formula for carbonic acid •H2CO3 Write the formula for propane •C3H8 Write the formula for cyclohexane •C6H12 Lewis Structures and Geometries 1. Fill out NASL – consider ion charge with A 2. Choose central atom – never H, always C if present, otherwise whichever element is furthest from Fluorine) 3. Bond atoms to central atom using shared electrons (2 electrons per bond) – if it seems like there are too many shared, make double or triple bonds – if more shared needed, borrow from lone 4. Fill in lone pairs so every atom has its octet – central atom can have more than an octet * On central atom only Geometry Bonded atoms* Lone pairs* Linear Bent Trigonal Planar 2 2 3 0 2 0 Trigonal Pyramidal Tetrahedral See-saw 3 1 4 4 0 1 Trigonal Bipyramidal Octahedral 5 0 6 0 Draw the correct Lewis dot structure for CH2O Draw the correct Lewis dot structure for CH2O What geometry can you predict for this molecule (CH2O) ? •Trigonal Planar (3 bonded atoms, 0 lone pairs) Draw the correct Lewis dot structure for SCl2 What geometry can you predict for this molecule (SCl2) ? •Bent (2 bonded atoms, 2 lone pairs) What geometry can you predict for a molecule with 6 atoms bonded to a central atom and no lone pairs present on the central atom? •octahedral What type of bond exists between chlorine (EN = 3.0) and bromine (EN = 2.8) •Non-polar covalent If a substance is liquid at room temperature, what types of bonds do you expect hold it together? (ionic, covalent, or metallic) •Covalent bonds If a substance dissolves in water and makes a solution that conducts electricity, what types of bonds do you expect hold it together? •Ionic bonds Write the formula for aluminum bromide •AlBr3 Write the formula for calcium chlorate •Ca(ClO3)2 Write the formula for sulfuric acid •H2SO4 Write the formula for iron (III) carbonate •Fe2(CO3)3 Which of the following is soluble in water? MgCrO4 •Rb2CrO4 AgCrO4 Rb2CrO4 Which of the following is soluble in water? Strontium oxide iron (II) chloride barium carbonate lead (II) iodide •Iron (II) chloride Which of the following is soluble in water? CaSO4 •NiClO3 NiClO3 Cu3BO3 Which of the following is soluble in water? Magnesium cyanide zinc chromate calcium phosphide gold (I) acetate •Gold (I) acetate What precipitate would form from a reaction of silver nitrate with magnesium sulfate? •Silver sulfate What precipitate would form from this reaction? CaCl2 + NaBrO3 •Ca(BrO3)2 What type of reaction is represented below? Element + compound element + compound •Single replacement What gas will be produced if sulfuric acid reacts with magnesium metal? •Hydrogen gas What gas will be produced if potassium chloride reacts with oxygen gas? •Chlorine gas (Cl2) What set of coefficients will balance this equation? SrBr2 + Na2SO4 NaBr + SrSO4 • 1:1:2:1 What evidence would indicate that the following reaction occurred? 3 Ca(OH)2 (aq) + 2 H3PO4 (aq) 6 H2O (l) + 1 Ca3(PO4)2 (s) •A precipitate What evidence would indicate that the following reaction occurred? HNO3 (aq) + Fe (s) H2(g) + Fe(NO3)3 (aq) •Gas bubbles Which of the following metals would you likely find pure (not bonded to another element)? sodium nickel lithium calcium •nickel Write a balanced equation for the following reaction: aqueous lithium carbonate reacts with a zinc acetate solution 1 Li2CO3 (aq) + 1 Zn(CH3COO)2 (aq) 2 Li(CH3COO) (aq) + 1 ZnCO3 (s) What is the molar mass of nitrogen gas? •28.02 g/mol What is the molar mass of lithium chloride? •42.39 g/mol What is the molar mass of ammonium hydroxide? •35.06 g/mol Calculate the mass of 0.75 moles of sulfur •24 g Sulfur How many atoms are in 1.25 moles of dysprosium? •7.53 x1023 atoms Dy What is the mass of 2.4 x 1024 molecules of water? •72 g of H2O What is % of carbon in propane? •81.68% What percent of zinc nitrate is oxygen? •50.7 % What is the empirical formula for P4O10 ? •P2O5 What is the empirical formula of the a compound with the following percent composition: **remember the rhyme** 43.0% Sr •SrCrO4 25.5% Cr 31.4% O The empirical formula for a cpmpound is CH2 and its molar mass is 98.21 g/mol. What is the compound’s molecular formula? •C7H14 The empirical formula for a cpmpound is CHBr and its molar mass is 278.76 g/mol. What is the compound’s molecular formula? •C3H3Br3