www.sakshieducation.com MODERN PHYSICS The word ‘atom’ derived from Greek work which literally means ‘indivisible’. The picture of atom underwent significant modifications from Dalton to Erwin Schrodinger….. Different models namely, Dalton model, Thomson’s model, Rutherford’s model, Bohr’s model, Somerfield’s concept of elliptical orbits, De Broglie’s concept of Dual nature of atom, Schrodinger’s wave equation etc lead to unveil the structure of atom. (Details will be discussed in chemistry) Constituents of Atom Atom consists Central particle named as Nucleus. Nucleus consists Protons, and Neutrons. Electrons revolve around the nucleus. Proton is positively charged, electron is negatively charged, and neutron has no charge. Protons and neutrons are collectively known as Nucleons. Atomic number (Z): The number of protons in an atom is defined as Atomic number. Atomic mass or Mass number (A) The total number of protons (Z) and neutrons(N) in an atom is defined as its atomic mass number or mass number (A) A=Z+N Atomic mass unit (amu) The amu is defined as 1/12th of mass of a neutral Carbon atom. 1 amu = 1.66054021 x 10-27 Kg. Atom symbol: ZX A X atom Z Atomic number (number of protons) A Mass number (Z + N) MASS DEFECT (∆m) Mass defect is defined as the difference between the sum of the individual masses of constituents in a nucleus and the mass of the nucleus itself. www.sakshieducation.com www.sakshieducation.com ∆m = Sum of individual masses of Constituents of the nucleus Actual mass of the nucleus Ex: Let us calculate the ∆m Helium (2He4) atom 4 2He Consists 2 protons and 2 neutrons in its nucleus. Mass of proton (mp) = 1.0078amu, Mass of neutron (mn) = 1.0087amu Total mass of 2 protons = 2 x 1.0078 = 2.0156 amu Total mass of 2 neutrons = 2 x 1.0087 = 2.0174 amu ---------4.0330 amu -----------∆m = 4.0330 - 4 = 0.330 amu The magnitude of mass defect is a measure of the stability of the nucleus. MASS ENERGY EQUIVALENCE ( E) The relation between Mass & Energy conversion was postulated by Albert Einstein (1879 1955) in 1905. “Mass and Energy are mutually convertible”. The principle of mass energy equivalence is given by E = ∆m c2 Where ∆m is the mass defect C is the velocity of light (3 x108m/sec) Albert Einstein (1879 - 1955) Thus the mass defect of Helium nucleus to be 0.0304 amu has been converted a energy the energy is utilized to bind two protons and two neutrons together and is called Binding Energy (B.E) B.E of nucleus = ∆m x 931.5 Mev. NATURAL RADIO ACTIVITY Radio activity was accidentally discovered by A.H Becquerel. www.sakshieducation.com www.sakshieducation.com “The self disintegrating spontaneous activity in the form of emission & radiation by some unstable nuclei with atomic number greater than 83 is called natural radio activity” A.H. BECQUERAL CLASSIFICATIONS OF RADIATIONS FROM RADIOACTIVE SUBSTANCES A small quantity of radioactive material is kept in a deep cavity of thick block of lead.A strong electic and Magnetic field are applied and the nature of radiations are studied. Three types of emissions are observed on the three photographic plated placed on the three sides of the Lead cavity.The three types of radiations are α, β, and γ The characteristics are as follows. PROPERTIES OF α , β, AND γ, RADIATIONS PROPERTY NATURE CHARGE Speed Ionization power Penetrating power Effect of electric field Effect of magnetic field (α ) radation It consists of two protons and two neutrons Positive 107m/sec Very high Very low Deflected towards cathode Deflected (β ) radiation These are electrons (γ )radiation These are electro magnetic radiations Negative No charge 8 10 m/sec 3 x 108m/xec Less than α, more Very less than γ More than α, less Very high than γ Deflected No deflection towards anode Deflected No deflection RADIOACTIVE TRANSFORMATIONS: Since α, and β are charged particles, the emission of these particles from a nucleus should convert it into different nucleus, which would be stable or unstable. The disintegration of an unstable nucleus resulting in another nucleus is called RADIOACTIVE TRANSFORMATION www.sakshieducation.com www.sakshieducation.com Ejection of α particle When α - particle is emitted the atomic number of the original nucleus is reduced by 2 and its mass number by 4 units. Ex: 238 92U Th234 90 - + 2He4 Ejection of β particle: Ejection of β particle from nuclear results in the increase of atomic number by 1 unit. Ex: 90Th 234 91 Pa234 + +1 β0 Ejection of γ particle: The emissions of γ ray doesnot alter either the atomic number or the mass number of the atom. RADIOACTIVE SERIES The sequential decay of a given nuclei results in the production of a nuclei or element. This series of elements thus formed is known as a radioactive decay series. There are 3 radioactive series depending on the original progenitor. 1) uranium series 2) Actinium series 3) Thorium series The important features of the radioactive series: 1) In every one of these three series radioactivity finally ceases with a stable lead Isotope. 2) Only Inert gas formed in these series are Radon (Rn) Z = 86 3) In all the d series wherever there is a change in mass number, it alters by 4 only. 4) Depending upon the masses of the element, the series are named as Uranium (4n + 2 ) Thorium ( 4n ) Actinium ( 4n + 3 ) 5) There is another artificially produced radioactive series called as Neptunium ( 93 Np237 ) or ( 4n + 1 ) series. HALF LIFE PERIOD (T ) www.sakshieducation.com www.sakshieducation.com The half life period (T) of a radioactive substance is defined as the time required for half of its atom to disintegrate. If 1gm of radioactive element reduced to ½ gm in a time T, ¼ gm in 2T 1/8 gm in 3T and so on………. The radioactive decay constant (λ) is also used do describe the activity of a radioactive element λ = 0.693/T ISOTOPES Aston established the concept of isotopes. Atoms of the same element having same atomic number but different mass number are called Isotopes of that element. Ex: 1) 1H1 , 1H2 , 1H3 2) 10Ne20, 10Ne21, 10Ne22 etc. ISOBARS Atoms of different elements having same mass number but different atomic numbers are called Isobars. Ex : 1) 2) ISOTONES 40 , 20Ca40 13 6C , 7N etc. 19K 13 Isotones are the atoms with their nuclei having same number of neutrons but different number of protons. Ex: www.sakshieducation.com www.sakshieducation.com ELEMENT Z Si 14 P 15 A 31 32 N 17 17 ARTIFICIAL RADIOACTIVITY ARTIFICIAL TRANSMUTATION: The process of transformation of one element into another by artificial means of bombarding it with high energy particles is known as ARTIFICIAL TRANSMUTATION. Rutherford’s experiment: + 1 O17 + 1H (Alpha particle) (Nitrogen) (Oxygen) (Proton) Here α particle is used as projectile, then Proton is released. 2He 4 7N 14 8 ARTIFICIAL TRANSMUTATION BY PROTONS Cockcroft and Walton attempted to transmute elements by using Proton as projectile. Ex: 1H 1 + 11Na 23 10 Ne20 + (proton) 2He 4 (Alpha particle) Here α particle is released. ARTIFICIAL RADIOACTIVITY The product nuclei formed in the above transmutations, found to be radioactive, which is undergoing disintegration by emitting positron (positton is an elementary particle with a positive charge and mass equal to the mass of electron) this radioactivity is known as Artificial radioactivity. It was first discovered by Curie in 1934. Their experiments is bombardment of Aluminium with α Particle. 27 13Al 15 30 + 2He4 Q P * + 0n1 + (Alpha particle) (Neutrino) (energy) www.sakshieducation.com www.sakshieducation.com 30 15P 30 * 14Si + 1e0 (Positron) Madam curie A NUCLEAR PROCESS IN WHICH A STABLE ELEMENT IS CONVERTED INTO ANOTHER ELEMTN WHICH IS RADIOACTIVE IN NATURE IS CALLED ARTIFICIAL OR INDUCED RADIOACTIVITY. About 500 radioactive Isotopes have been artificially produced by bombardment of stable elements with α particle. USES OF RADIO ISOTOPES a) In medicine: 1) Radio Sodium (11Na24) is used to detect a clot in the blood of a human body 2) Radio Cobalt (27Co60 ) is used to kill cancer cells. 3) Radio Iodine (53I131 ) is used to test the functioning of Thyroid. b) In Industry 1) Radio Cobalt (27Co60 ) is used to detect internal flaws of cast material. 2) Radiation from radio Isotopes is used to dispel the static electricity acquired by some material. c) Agriculture 1) Unnecessary mutations of plants can be prevented by irradiating seeds using radio Isotopes. d) Meteorology 1) The course of Monsoon and the changes they undergo can be studied by injecting radioactive gases into atmosphere and they are followed with suitable detectors. e) Radio active dating 1) The age of ancient biological materials (Fossils) can be determined by using radio Carbon (6C14). 2) The age of rocks can be determined by using Uranium isotope. PROPERTIES OF α, β, AND γ, RADIATIONS CHARGE Speed Ionization power (α ) radation It consists of two protons and two neutrons Positive 107m/sec Very high Penetrating Very low PROPERTY NATURE (β ) radiation These are electrons (γ )radiation These are electro magnetic radiations Negative No charge 108m/sec 3 x 108m/xec Less than α, more Very less than γ More than α, less Very high www.sakshieducation.com www.sakshieducation.com power Effect of electric field Effect of magnetic field Deflected towards cathode Deflected than γ Deflected towards anode Deflected No deflection No deflection NUCLEAR REACTIONS There are two types of Nuclear reactions. They are 1) Nuclear fission, 2) Nuclear Fusion. NUCLEAR FISSION It was first discovered by OTTO HANN IN 1939. OTTO HANN “A Heavy unstable Nucleus such as Uranium when bombarded with slow neutrons explode into two more or less equal fragments, which fly apart with very great energy of about 200Mev. Such a nuclear disruption has been named ad FISSION’. 235 92U + 0n1 [92U236] (Combined nucleus) 56Ba 141 + 36Kr92 + 30n1 + Q (Energy) This phenomenon was explained by Neils Bohr and wheeler on the basis of liquid drop model of nucleus. CHAIN REACTION A CHAIN REACTION is a series of nuclear fission where by the neutron produced in each fission causes additional fissions. www.sakshieducation.com www.sakshieducation.com If a nucleus of 92U235 is bombarded in this process energy is liberated and also two or three neutrons are released. These neutrons in turn would be captured by the nucleus of nearby Uranium atom and they, in turn, would split, liberating fresh neutrons, which participate in further fission reaction. CONTROLLED CHAIN REACTION The control and harnessing of the energy becomes possible if the number of neutrons in the immediate environment of Uranium nuclei is limited by some means NUCLEAR REACTOR PRINCIPLE: The controlled chain reaction is the basic principle on which nuclear reactor functions. These are the sources for the generation of electric power. The first nuclear reactor was put into operation in Chicago (USA) in 1942. The essential features of a nuclear reactor are 1) The fuel, 2) Moderator 3) Control rods 4) Radioactive Shielding 5) The coolant. SCHEMATIC DIAGRAM OF NUCLEAR REACTOR: www.sakshieducation.com www.sakshieducation.com 1) FUEL: The fissionable material used in the reactor is called fuel. Isotopes of Uranium, Plutonium, and Thorium are commonly used fuels. The rods of these fuels are tightly sealed in aluminum cylinders. 2) MODERATOR: The purpose of using moderator is to slowdown the fast moving neutrons during the fission process. Heavy water or graphite or beryllium, or Hydro carbon plastics are some of the suitable material used as moderator. 3) CONTROL RODS: These absorb the neutrons and control the chain reaction. Cadmium or Boron rods are generally used for this purpose. 4) RADIATION SHIELDING: Lead blocks, Concrete walls of thickness 10m are used to prevent spreading of radioactive effect to the space around the nuclear reactor. This is called radiation shielding. 5) COOLANT: The substance used to absorb heat generated in the reactor is called the coolant. Generally Water with pumps is used as coolant. WORKING www.sakshieducation.com www.sakshieducation.com The reactor core (consisting Moderator and Fuel rods) and pump are in contact with a heat exchanger which is generally water. This water changes into steam which is utilized to turn the turbine. IN THIS NUCLEAR REACTOR, IF THE CHAIN REACTION IS UNCONTROLLED, THE DEVICE IN TURNS AN ATOM BOMB. NUCLEAR POWER PLANT: ATOMIC EXPLOSION: NUCLEAR FUSION A nuclear reaction in which lighter nuclei are combined together to form heavier product nuclei with the release of enormous amount of energy is called FUSION. EX: Two Hydrogen nuclei combine to form Helium Isotope. www.sakshieducation.com www.sakshieducation.com 2 +1e0 + 2 0ν0 + Q (positron) (neutrino) (energy) The energy released is 27.67 Mev. 4 1 H1 2 He4 + The above reactions are called proton - proton cycle. The proton cycles are responsible for energies of the stars like Sun. HYDROGEN BOMB: Uncontrolled fusion is the principle of Hydrogen Bomb. IMPORTANT CONSTANTS 1) 2) 3) 4) 5) 6) 7) 8) 9) Radius of nucleus: 2.4 x 10-15m 1 amu = 1.66054021 x 10-27 Kg Nucleus density = 2.92 x 1017 Kg/m3 Charge of electron (e) = 1.6 x 10-19 Coulombs Mass of electron (m) = 9.11 x 10-31 Kg e/m of electron = 1.76 x 1011 C/Kg 1 amu = 931.5 Mev (or) 931.5 x 106 ev ∆m in case of He atom = 0.0304 amu (or) 1.5 x 10 -10Joules (or) 6.24 x 1012 Mev 16 1 Kg = 9 x 10 Joules www.sakshieducation.com www.sakshieducation.com 1 Joule = 1.15 x 10-17 Kg 1 Mev = 1.6 x 10-13 J Mass of proton (mp ) = 1.0078 amu Mass of Neutron (mn) = 1.0087 amu Speed of α particle = 107 m/sec Speed of β particle = 108 m/sec Speed of γ particle = 3 x 108 m/sec = speed of light Energy released in fission reaction of Uranium = 200Mev Energy released in Fusion of Hydrogen = 27.67 Mev Energy required to start a fusion reaction = 0.01Mev (or) 80 x106 degrees Kelvin 20) Energy of Thermo neutrons = 0.04ev. 10) 11) 12) 13) 14) 15) 16) 17) 18) 19) IMPORTANT QUESTIONS 1 MARK: 1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 11) 12) Define Mass defect? What is natural radioactivity? What is radioactive transformation? State the law of radioactive disintegration? What is moderator? Define nuclear fission? What is a chain reaction? Define nuclear fusion? State the law of Einstein’s mass energy equivalence? What happens when an α partcle is ejected from a radioactive element? What happens when a β partcle is ejected from a radioactive element? What happens when a γ partcle is ejected from a radioactive element? 2 MARKS: 1) 2) 3) 4) Define Isotopes? Give examples? Define Isobars? Give examples? Define Isotones? Give examples? Differentiate between artificial and natural radioactivity? 4 MARKS: 1) 2) 3) 4) 5) What are the properties of α, β, and γ radiations? What is radioactive dating? Explain? Mention the uses of Radio Isotopes in medicine, industry, agriculture and meteorology? What are the components of a nuclear reactor? What are their functions? What is the principle of nuclear reactor? How is a chain reaction controlled in a nuclear reactor? 5 MARKS: www.sakshieducation.com www.sakshieducation.com 1) Draw a neat labeled diagram of Nuclear reactor? BITS 1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 11) 12) 13) 14) 15) 16) 17) 18) 19) 20) 21) 22) 23) 24) 25) 26) 27) 28) 29) 30) 31) The description of the distribution of mass and positive and negative charges in an atom is called an ______________________ Alpha particle is _________ charged particle. Mass of the electron is __________ of mass of alpha particle ________ discovered neutron in 1932. Protons and neutrons are collectively called ____ The amu is defined as 1/12th of the mass a ________ atom. The difference between the sum of the individual masses of the constituents of nucleus and the mass of the nucleus is called __ The mass defect of Helium atom is ______ The magnitude of the mass defect is a measure of ____ of nucleus The mass energy equivalence was given by _____ The mass energy equivalence E = ___ The energy used to bind the protons and neutrons in a nucleus is called ____ Binding energy = mass defect x _____ Electron volt is a unit of _____ The ability of certain substances to transform incident ultraviolet radiations into visible light is called ____ The self disintegrating spontaneous activity in the form of emission of radiations by some unstable nucleus with atomic number greater than 83 is called ______ _____ can absorb the radioactive rays given by radioactive substance. _____ are doubly ionized Helium atom ______ particles have high ionization extent of the gases through which they pass. _______ rays are electromagnetic radiations in radioactive emission. Γ rays travel with the speed of ________ _________ rays have low Ionization power. _______ rays have high penetrating power. ______ rays are used in treatment of cancer. The disintegration of an unstable nucleus resulting in another nucleus is called _______ After α decay, the position of the element shifts _____ places left in the periodic table. After α decay, the atomic number of the parent nucleus decrease by _ and its mass number by ________ 238 90 92U Th 234 + _________ In β decay the element changes into another element of _____ mass number and atomic number increases by ______ The sequential decay of a given nucleus results in the production of a series of nuclei of elements known as _________ In transformation series, radioactivity finally ceases with a stable ____ isotope as the end product. www.sakshieducation.com www.sakshieducation.com 32) The inert gas present each series is _____ 33) In the radioactive series whenever the mass number changes it changes by _____ 34) The time required for half of the atoms of a radioactive substance to disintegrate is known as _____ 35) The decay constant λ = _____ 36) Atoms of different elements having same mass number but different atomic number are called ________ 37) Atoms with nuclei having same number of neutrons but different number of protons are called _______ 38) Atoms of same element having same atomic number but different mass number are called _________ 39) Speed of β particles is ______ 40) 1 Mev = _____ Joules. 41) Radius of nucleus _______ 42) _________ Isotope is used to determine the age of fossils 43) ________ is used as moderator in Nuclear reactor. 44) In a nuclear reactor, the part which consists the moderator and fuel rods is known as __________ MATCHING 1) 2) 3) 4) 5) Uranium series Thorium series Actinium series Neptunium series Age of rocks ANSWERS: 1) 2) 3) 4) 5) 1) B Atomic number Mass defect Mass number Atomic mass unit Units of energy ANSWERS; 1) C 2) ( ( ( ( ( ) ) ) ) ) A) B) C) D) E) F) 4n+1 4n + 2 4n U Isotope 4n + 3 Carbon Isotope 2) C 3) E ( ( ( ( ( ) ) ) ) ) A) Stability of an atom B) amu C) Number of protons D) ev E) Sum of protons and neutrons A 3) E 4) B 4) A 5) F 5) D ANSWERS FOR BITS 1) Atomic model 2) Positively 3) 1/7000 4) Chadwick 5) Nucleons 6) Carbon 7) mass defect 8) 0.0304 amu 9) Stability 10) Einstein 11) ∆mc2 12) binding energy 13) 931.5 Mev 14) Energy 15) Flourosence 16) Natural radioactivity 17) Lead 18) α particles 19) α particles www.sakshieducation.com www.sakshieducation.com 20) γ particles 21) Light 22) γ rays 23) γ rays 24) γ rays 25) Radioactive disintegration 26) 2 27) 2, 4 28) α particle 29) same, 1 30) Radioactive series 31) Lead 32) Radon 33) decrease by 4 units 34) Half life period (T) 35) 0.693/T 36) Isobars 37) Isotones 38) Isotopes 39) 108 m/sec 40) 1.6 x 10-13 Joules 41) 10-13 Cm 42) Carbon 43) Heavy water or Graphite 44) Reactor core www.sakshieducation.com