Bonds and Compounds How to write, name and/or draw various Chemical Compounds Ions and Ionic Compounds • An ion is created whenever an atom gains or loses an electron to become more stable like a Noble Gas, meaning that its valence number is now 8! • Metals are always positive, which means that they lose electrons. • Nonmetals are usually negative with a few exceptions, like Nitrogen which has 8 different ion possibilities. How to make an ionic compound • To make an ionic compound, one must combine a positive ion with a negative ion. • The positive ion is ALWAYS listed first, followed by the negative one. • Example: Na+ + Cl- NaCl • **The Key is that ALL charges must be cancelled out, and the overall charge on the compound MUST be ZERO!! Criss-Cross Method • When the ratio is one-to-one or two-totwo, it is easy to cancel the charges. However, it can become a little more complicated, so scientists use the Criss-Cross Method to help illustrate how the math is done. • Example: • Fe3+ + SO42- = Fe2(SO4)3 Naming Ionic Compounds • The first part of the name comes directly from the first ion in the compound. • The second part of the name has the base of the second ion, but MUST end in –ide, ate, or –ite. • Examples: NaCl Sodium Chloride K2CrO4 Potassium Chromate Al2(SO3)3 Aluminum Sulfite Writing the formula from the name • Unfortunately, there is no shortcut to this. You MUST learn the ion to know what their charges are to write the formula from the names. It takes practice and perseverance. • Examples: • Calcium Carbonate CaCO3 • Ammonium Phosphate (NH4)3PO4 Review and Practice • Name the following ionic compounds: (NH4)3PO4 CaSO4 • Write the formulas for the following ionic compounds: Tin (IV) Fluoride Iron (III) peroxide More Practice • Write the formulas for the following ionic compounds: Magnesium Hydroxide Copper (I) Sulfate Lead (II) Phosphate Ammonium Dichromate Zinc Acetate Iron (II) Oxide Mercury (I) Chloride Silver Nitrate Covalent or Molecular Compounds • Covalent compounds are created using covalent bonds. A covalent bond involves the “sharing’ of electrons between two different atoms. These atoms can be the same type of atoms or different. • To show the sharing of electrons, scientists use Lewis Dot Structures and structural formulas that use dashes for bonds. Naming Covalent Compounds Number 1 • To name covalent 2 compounds, one 3 must know ten important prefixes. 4 These prefixes 5 indicate how many 6 of each atom is present in the 7 molecule that has 8 been created. 9 10 Prefix MonoDiTriTetraPentaHexaHeptaOctaNonaDeca- Naming them… • First, you must see if the two atoms are nonmetals. If so, then you have a covalent compound. (Be careful not to mistake an ion for an atom!) • Second, note how many of each atom is present in the compound. • Third, choose the prefix that will work for the name. (The first atom only gets a prefix if there is more than one; the second atom ALWAYS gets a prefix.) • Fourth, name it using the prefixes as needed. (Be careful…some compounds have common names that are the preferred names. Examples… • CO2 Carbon dioxide • H2O Dihydrogen monoxide (Water) • NH3 Nitrogen trihydride (Ammonia) • P4O10 Tetraphosphorus decoxide Types of Chemical Reactions • There are five major types of reactions. • These reactions are found in nature and can be manmade. • In addition, these reactions often take in heat or energy (endothermic) or release heat or energy (exothermic). Synthesis Reactions • These reactions have two or more reactants that come together to form ONE product. • Generic equation: A + B AB • Example: 2H2 + O2 2H2O Decomposition Reactions • These reactions involve ONE reactant breaking down to form two or more products. • Generic Equation: AB A + B • Example: RhO3 RhO + O2 Single-Replacement Reactions • These reactions require a single atom combined with a compound to then form a new compound and a new singular atom. (**Governed by the Activity Series of Metals) • Generic Equation: A + BC AC + B • Example: 2Li + H2SO4 Li2SO4 + H2 Double-Replacement Reactions • These reactions involved two ionic compounds’ cations switching anion partners to form new compounds. (**A gas or precipitate usually forms!) • Generic Equation: A+ B- + C + D- A + D- + C+ B• Example: AgBr + NaCl AgCl + NaBr Combustion Reactions • All combustion reactions involve oxygen gas as a reactant and the release of great amounts of energy as a product. There are types of combustion reactions: Metals with oxygen to form metal oxides and hydrocarbons with oxygen to form carbon dioxide and water. Combustion Reactions (cont.) • Examples of both combustion reactions: 2Mg + O2 2MgO + light C2H4 + 3O2 2CO2 + 2H2O + energy