Bahan Kajian MK. Pengelolaan SDALH PENGELOLAAN PENCEMARAN TANAH Smno.psdl.pdkl.ppsub.des2013 PENCEMARAN TANAH ATAU LAHAN Soil pollution or land pollution is an undesirable change in the physical ,chemical or biological characteristics of the soil that adversely affects its fertility and productivity There are many natural and synthetic materials that can adversely affect the properties of the soil Logam berat seperti tembaga, seng dan molibdenum adalah elemen penting untuk tanaman dan hewan, tetapi konsentrasi yang berlebihan dapat merusak kesuburan tanah secara keseluruhan. Logam seperti kadmium dan timbal dapat memiliki efek buruk pada kesehatan manusia dan hewan jika mereka dibiarkan menumpuk dalam rantai makanan. Terjadinya konsentrasi tinggi logam berat dalam topsoil lahan pertanian umumnya sangat lokal. Waktu tinggal sebagian besar logam berat ini cukup panjang dan mereka cenderung tidak tersedia bagi tanaman. Diunduh dari: http://www.ecifm.rdg.ac.uk/landpolluti on.htm SOURCES OF LAND POLLUTION INDUSTRIAL WASTE The main soil polluting Industries are chemical, tanneries Industries etc. DOMESTIC WASTES The various domestic garbage and wastes are the second largest sources of soil pollution The domestic wastes include polythene bags ,plastic materials ,broken packing box ,bottle etc LIMBAH PERTANIAN The materials includes fertilizers pesticides, salinity due to increased irrigation etc Sumber logam berat yang ada dalam lahan pertanian : 1. 2. 3. 4. 5. 6. 7. 8. Parent material (underlying geology) Mine wastes Atmospheric deposition Farm manures Sewage sludge Fertilizers and lime Agrochemicals Industrial wastes. Diunduh dari: http://www.ecifm.rdg.ac.uk/landpollution. htm RADIOACTIVE MATERIALS The radioactive wastes from different nuclear reactors or different testing laboratories cause severe pollution to the soil The radioactive pollutants include barium-140; rhodium-106 etc. The radioactive materials emit gamma rays which adversely affect the living organisms Agen-agen Hayati The biological agents responsible for soil pollution are the human excreta,animal excreta, birds excret The diagram above shows that when animal manure is applied to soils it is decomposed by microbes. The complex protein in the material is eventually broken down to release the nitrogen which was contained in it. The first nitrogen ion to be released is ammonium (NH4+). In warm, well-drained soils which contain a favorable balance of water and air the "aerobic" microbes soon convert ammonium nitrogen to nitrite (NO2-) and then to nitrate (NO3-) nitrogen. Diunduh dari: http://www.memun.org/SchoolsProject/Resources/zoning/Shoreland/ordinance_appB.htm Proc. R. Soc. Lond. B 21 March 1972 vol. 180 no. 1061 371-382 Eutrophication (J. W. G. Lund) Eutrofikasi adalah pengayaan oleh hara tanaman . Berikut ini dibahas eutrofikasi buatan manusia . Sumber utama pengayaan hara adalah limbah , pupuk buatan dan limbah pertanian . Populasi besar tanaman dan hewan , hidup atau mati , menyebabkan kesulitan dalam industri air dan dapat mengganggu kegiatan rekreasi , terutama “fishing”. Sebagian besar fosfor dan nitrogen dapat dihapus dari limbah buangan jika biaya memungkinkan. Penurunan volume runoff pertanian dalam julah besar dianggap tidak praktis, tetapi pengurangan runoff sangat mungkin . Penghapusan polifosfat dari deterjen adalah “dilema”, tetapi bahan pengganti yang cocok dan tidak menimbulkan ancaman lingkungan belum ada di pasaran. Diunduh dari: http://rspb.royalsocietypublishing.org/content/180/1061/371 Pp. 462-465 in: Landin, M.C. (ed.), Wetlands: Proceedings of the 13th Annual SWS Conference, New Orleans, LA, June 1992. Rader, R.B. and C.J. Richardson. 1993. The effects of agricultural run-off on small fish and macroinvertebrates in the Everglades. One of the most highly publicized fears associated with nutrient enrichment in the Florida Everglades is the loss of wading bird populations because of a decline in the density and diversity of macroinvertebrates. The object of this study was to determine the effects of nutrient enrichment on oxygen, pH, and especially macroinvertebrates along a nutrient enrichment gradient in the Everglades. Although 24-hr. oxygen profiles were lower within enriched compared to unenriched habitats, macroinvertebrate diversity and density were higher. To date, 96 and 63 taxa have been identified from enriched and unenriched sites, respectively. The density of macroinvertebrates, averaged across all sampling dates, is 2.9 X greater within enriched compared to unenriched sites. Although some analyses are not yet completed, these data indicate that nutrient enrichment has not caused harmful foodweb effects. Diunduh dari: http://www.nicholas.duke.edu/wetland/sws_93_rader.htm SOURCES OF LAND POLLUTION Chemical and nuclear plants Industrial factories Oil refineries Human sewage Oil and antifreeze leaking from cars Mining Littering Overcrowded landfills Deforestation . TIPE-TIPE PENCEMARAN TANAH Agricultural Soil Pollution i) pollution of surface soil ii) pollution of underground soil Soil pollution by industrial effluents and solid wastes i) pollution of surface soil ii) disturbances in soil profile Pollution due to urban activities i) pollution of surface soil ii) pollution of underground soil TIPE-TIPE PENCEMARAN TANAH The urine and faeces discharged by animals contain a large number of pathogenic organisms. These pollute the soil and infect a large number even the man CAUSES OF SOIL POLLUTION Diffuse Pollution Conference, Dublin 2003 Poster Papers Diffuse Pollution Conference, Dublin 2003 Poster Papers 14-102 PESTICIDE RETENTION IN THE WATERSHED AND IN A SMALL CONSTRUCTED WETLAND TREATING DIFFUSE POLLUTION K. Haarstad and B.C. Braskerud Loss of pesticides is likely from watersheds where pesticides are used. The herbicides propachlor, linuron and metamitron, and the fungicides propiconazole, fenpropimorph and metribuzin and metalaxyl, were applied on an arable soil plot. A mass balance study showed that approximately 96 % of the applied pesticides disappeared within the watershed. Three pesticides remained as residuals in the soil profile one year after the application. The 4 % of the pesticides that were lost from the watershed gave peak concentrations, appearing immediately after spraying, reaching levels that can be hazardous to aquatic life. The constructed wetland situated in the first-order stream generally managed to lower the peak concentrations significantly. For the summer season, retention varied from 12 to 67 % the first year. The second year, we observed both loss and retention. Increasing the wetland surface from 0.2 % to 0.4 % of the watershed area increased the average retention with 21 % units the first year and 9 % units the second year. Chemical properties of the pesticides could explain some of the behaviour in the watershed and in the wetland. Diunduh dari: http://www.ucd.ie/dipcon/docs/theme14/theme14_29.PDF Asian Journal of Water, Environment and Pollution Volume 6, Number 1 / 2009 Pesticide Pollution in Punjab: A Review N.S. Tiwana, Neelima Jerath, Gurharminder Singh, Ravleen Singh The use of chemical pesticides in the country has increased by more than seventeen times since 1955. The state of Punjab is one of the highest user of these pesticides especially after the ushering in of green revolution. Though the state has only 1.5% landmass of the country, it consumes about 17% of pesticides used in India. The per hectare pesticide use is highest in Punjab (923 g/ha) as compared to other agriculturally advanced states like Haryana, Andhra Pradesh, Tamil Nadu, Karnataka and Gujrat. Although the use of pesticides has helped to enhanced economic gains through crop protection yet they have had serious implications to human health and non-target plants and animals by accumulating in food and water. The present paper reviews various studies carried out in Punjab on the pesticide residues found in different food items (like wheat flour, human milk, vegetables, etc.) and their effect on human health. Diunduh dari: http://iospress.metapress.com/content/0751534g14238545/ TIPE-TIPE PENCEMARAN TANAH Wastes are unwanted and useless substances resulting from different human activities Un wanted or discarded substances that have weight and size are called solid wastes eg:sewage APPLICATION OF AGROCHEMICALS FAULTY SANITATION PRACTIES Sanitation means the whole field of controlling the environment with a view to prevent disease and health Some parts of the lands are polluted due to human excreta. It is a source of infection Nutrient Cycling in Agroecosystems Volume 36, Number 2 (1993), 95-103, DOI: 10.1007/BF00747579 Fertilizers and eutrophication in southwestern Australia: Setting the scene E. P. Hodgkin and B. H. Hamilton An excess of plant nutrients has caused serious eutrophication in aquatic ecosystems of southwestern Australia manifested by excessive growth and accumulation of green and bluegreen algae. Phosphorus is generally the limiting nutrient for algal growth and phosphatic fertilizers applied to nutrient-deficient, leaching, sandy soils are the main source of P, supplemented by rural industry point sources. Nitrogen is the limiting nutrient in marine embayments with little drainage from the land. Measures to reduce the load of P delivered to drainage include basing fertilizer application rates on soil testing for P and the use of less soluble P fertilizers. Catchment management plans are being implemented with community involvement to reduce P loads and maintain agricultural production. This introductory paper reviews the history of eutrophication in southwestern Australia and of studies into its causes, principally in the large Peel-Harvey estuary. It briefly summarises other papers in this special issue concerned with different aspects of the problem: how to fertilize the land without causing eutrophication. Diunduh dari: http://www.springerlink.com/content/hl37938503526656/ TIPE-TIPE PENCEMARAN TANAH SALINATION DUE TO IRRIGATION AND FLOOD • over irrigaton and flood will increase the salinity of soil.This has adverse effect on soil productivity SOIL EROSION • soil erosion leads to loss of productivity of soil • A ccording to Rama Rao ‘soil erosion is creeping death of soil’ INDIRECT CAUSES ACID RAIN Acid rain occurs due to acid deposition in air these acid deposition come from the motor vehicles, factory etc acid rain contains nitric acid, sulphar dioxide etc Nutrient Cycling in Agroecosystems Volume 36, Number 2 (1993), 157-164, DOI: 10.1007/BF00747587 The potential use of wetlands to reduce phosphorus export from agricultural catchments J. M. Chambers, T. J. Wrigley and A. J. McComb Natural and artificial wetlands have the potential to reduce phosphorus (P) loads from dispersed agricultural runoff and from point sources in the Peel-Harvey catchment, Western Australia. Small experimental systems containing wetland plants and substrate have shown significant removal of P from inflowing water, the proportion of P removed being dependent on P concentration and flow rate of water through the system. The use of artificial wetlands to treat diffuse agricultural runoff is limited by the highly seasonal runoff typical of this Mediterranean climate, while use at point sources has so far been unsuccessful because compounds from the effluent clog the wetland filters. Treatment at point sources may well be feasible after further research.Natural wetlands in the catchment absorb P received in runoff from farmland and, in the absence of any outflow channels to the drainage system, confine this P within the boundaries of the wetland. Disturbance to wetlands may reduce their efficiency in absorbing nutrients and may release P stored in the vegetation and sediment to the water. The conservation of natural wetlands is recommended to maximise nutrient retention in the catchment. Diunduh dari: http://www.springerlink.com/content/r1rj40h752056r65/ TIPE-TIPE PENCEMARAN TANAH DISPOSAL OF RADIOACTIVE SUBSTANCES Radioactive substaces pollute the soil . They have adverse effects on fauna and flora. EFFECTS OF SOIL POLLUTION EFFECT ON HUMAN HEALTH Chlorinated hydrocarbons contained in the agrochemicals cause cancer, birth defects, neurological disorders etc. Most of the organic phosphates are toxic and human being may suffer from diarrhea, vomiting, breathing difficulty etc high concentration may cause paralysis, coma and death Biogeochemistry (2006) 77: 441–463 Springer 2006 DOI 10.1007/s10533-005-3070-5 Escalating worldwide use of urea – a global change contributing to coastal eutrophication PATRICIA M. GLIBERT, JOHN HARRISON, CYNTHIA HEIL and SYBIL SEITZINGER. While the global increase in the use of nitrogen-based fertilizers has been well recognized, another change in fertilizer usage has simultaneously occurred: a shift toward urea-based products. Worldwide use of urea has increased more than 100-fold in the past 4 decades and now constitutes >50% of global nitrogenous fertilizer usage. Global urea usage extends beyond agricultural applications; urea is also used extensively in animal feeds and in manufacturing processes. This change has occurred to satisfy the world’s need for food and more efficient agriculture. Long thought to be retained in soils, new data are suggestive of significant overland transport of urea to sensitive coastal waters. Urea concentrations in coastal and estuarine waters can be substantially elevated and can represent a large fraction of the total dissolved organic nitrogen pool. Urea is used as a nitrogen substrate by many coastal phytoplankton and is increasingly found to be important in the nitrogenous nutrition of some harmful algal bloom (HAB) species. The global increase from 1970 to 2000 in documented incidences of paralytic shellfish poisoning, caused by several HAB species, is similar to the global increase in urea use over the same 3 decades. The trend toward global urea use is expected to continue, with the potential for increasing pollution of sensitive coastal waters around the world. Diunduh dari: JOURNAL OF CHINESE JOURNAL OF ECOLOGY cje 2004, Vol. Issue (1): 73-77 Biodegradation and bioremediation of pesticide pollution YOU Minsheng, LIU Xin This paper discussed the concept of bioremediation, pesticidedegrading microorganisms, acquisition and identification of pesticide-degrading microorganisms, and elucidated the research on enzymes in bioremediation of pesticide pollution, measurement on efficiency and mechanism of pesticide bioremediation,as welll as variables which affect the process of pesticide bioremediation. The authors also summarized the advantages and disadvantages of pesticide bioremediation, and discussed the development trends of pesticide bioremediation. Diunduh dari: http://www.cje.net.cn/EN/abstract/abstract5239.shtml TIPE-TIPE PENCEMARAN TANAH 1. 2. 3. 4. 5. Industrial wastes are extremely toxic to living beings . The toxins enter the food chain causing a number of undesirable effects Domestic wastes spread several chronic diseases Industrial as well as domestic wastes can cause water borne diseases Radioactive substances contained in the soil can cause several health problems In the heaps of different industrial and urban wastes rates, fleas and flies multiply and spread various diseases. The fleas help in spreading the plague .The flies spread the diseases like dysentry etc. World Academy of Science, Engineering and Technology 72 2010 Use of Pesticides and Their Role in Environmental Pollution Muhammad Jamil Khan, Muhammad Sharif Zia and Muhammad Qasim Insect pests are the major source of crop damage, yield and quality reduction in Pakistan and else where in the world. Cotton crop is the most hit crop in Pakistan followed by rice and the second most important foreign exchange earning crop. A wide variety of staple, horticultural and cash crops grown, reflect serious problems of many types of insect pests. To overcome the insect pest problem, pesticide use in Pakistan has increased substantially which has now been further intensified. Pesticides worth more than billions of rupees are imported every year. This paper reviews the over all pesticide use in Pakistan in relation to pesticide prices, support price of cotton and rice, pesticide use in different provinces of Pakistan on different crops and their impact on crop productivity. The environmental pollution caused by the use of pesticides, contamination of soil and water resources and the danger associated with the disposal of their empty containers is also discussed in detail. Diunduh dari: http://www.waset.org/journals/waset/v72/v72-24.pdf EFEK PENCEMARAN TANAH EFFECT ON PLANT AND ANIMAL LIFE The animal borne diseases which spread through soil are anthrax and leptospirosis radioactive pollutants affects the soil and soil fertility these radiations kill plant species Phosphate fertilizer is considered deterimental to crop production long lasting effects of pesticides are visible in animals. EFFECTS ON THE ECONOMY For removing the pollutants from the soil ,a certain amount of Mar Pollut Bull. 2007;55(1-6):74-90. Epub 2006 Oct 9. Assessing the impact of nutrient enrichment in estuaries: susceptibility to eutrophication. Painting SJ, Devlin MJ, Malcolm SJ, Parker ER, Mills DK, Mills C, Tett P, Wither A, Burt J, Jones R, Winpenny K. The main aim of this study was to develop a generic tool for assessing risks and impacts of nutrient enrichment in estuaries. A simple model was developed to predict the magnitude of primary production by phytoplankton in different estuaries from nutrient input (total available nitrogen and/or phosphorus) and to determine likely trophic status. In the model, primary production is strongly influenced by water residence times and relative light regimes. The model indicates that estuaries with low and moderate light levels are the least likely to show a biological response to nutrient inputs. Estuaries with a good light regime are likely to be sensitive to nutrient enrichment, and to show similar responses, mediated only by site-specific geomorphological features. Nixon's scale was used to describe the relative trophic status of estuaries, and to set nutrient and chlorophyll thresholds for assessing trophic status. Estuaries identified as being eutrophic may not show any signs of eutrophication. Additional attributes need to be considered to assess negative impacts. Here, likely detriment to the oxygen regime was considered, but is most applicable to areas of restricted exchange. Factors which limit phytoplankton growth under high nutrient conditions (water residence times and/or light availability) may favour the growth of other primary producers, such as macrophytes, which may have a negative impact on other biological communities. The assessment tool was developed for estuaries in England and Wales, based on a simple 3category typology determined by geomorphology and relative light levels. Nixon's scale needs to be validated for estuaries in England and Wales, once more data are available on light levels and primary production. Diunduh dari: Diffuse Pollution Conference Dublin 2003 3A: Agriculture 3-14 COLD-CLIMATE VEGETATIVE BUFFER ZONES AS PESTICIDE-FILTERS FOR SURFACE RUNOFF N. Syversen Vegetative buffer zones adjacent to watercourses can be effective filters for diffuse pollution from agriculture. Several investigations, even during snowmelt season, have shown that retention of sediments and sediment-bound nutrients in runoff water has been high through buffer zones (BZ). It is likely that BZ also can be effective filters for sediment-bound pesticides. The retention of glyphosate, propiconazole, fenpropimorph and soil particles was studied in surface runoff experiments with 5-m wide buffer zones. Volume proportional samples were collected after each runoff episode (1999- 2002). The distribution coefficient (Kd) shows moderate to high adsorption of the pesticides to the experimental soil. Results show average retention efficiency of about 74%, 61%, 85% and 34% for particles, glyphosate, propiconazole and fenpropimorph, respectively. The amount of AMPA (which is a degradation product of glyphosate), entering the BZ was high; approximately the same amount as for glyphosate. The retention efficiency through the BZ for AMPA was about 78%. There were no significant differences in removal efficiency (in %) between winter with snowmelt and summer. This is possibly due to detachment of coarser aggregates during winter, which trap more easily in the BZ. The conclusion based on this study suggests BZ to be contributors to reduced pesticide input to surface waters. Diunduh dari: Agricultural Runoff-Characteristics and Control Raymond C. Loehr Journal of the Sanitary Engineering Division, Vol. 98, No. 6, November/December 1972, pp. 909-925 Agricultural runoff consists of nonpoint sources that range from almost natural runoff to that from concentrated agricultural operations such as animal feedlots and fertilized fields. Control of the latter is possible by waste management and land conservation techniques. Increases in agricultural efficiency have been associated with a variety of potential and real environmental problems. The paper attempts to quantify some pollution problems due to agricultural runoff and to put these problems in perspective. The major topical areas include erosion, animal feedlots, rural runoff, pollution characteristics, and effect of fertilizers. Management methods to control the quantity and pollutional quality of the runoff are noted. The paper stresses that agriculture should institute a systematic, coordinated approach for specific production operations to reduce excesses that could cause environmental degradation. Diunduh dari: http://cedb.asce.org/cgi/WWWdisplay.cgi?127982 PENCEGAHAN DAN KONTROL PENCEMARAN TANAH PENGELOLAAN SAMPAH YANG EFISIEN Koleksi SAMPAH dan limbah dari berbagai tempat dan membuangnya di tempat yang jauh, merupakan metode yang paling populer daalam pengelolaan limbah padat Namun koleksi dari tempat yang berbeda dan membuangnya ke tempat yang jauh , rantainya panjang dan mahal Untuk menghindari masalah ini, harus dibangun stasiun-stasiun peralihan di berbagai lokasi (TPS) . Journal of Environmental Protection JEP >> Vol.2 No.4, June 2011 PP.429-434 Groundwater Pollution Due to Pesticides and Heavy Metals in North West Bank This study aims at determining the quantitative effect of pesticides including 2, 4D dichlorphenoxy acetic acids, Paraquat, Atrazine (2-chloro-4-ethylamino-6isopropylamino-striazine), and MCPP 2-(2-Methyl-4-chlorophenoxy) pro-panioic acid on groundwater quality due to agricultural in Jenin and Tulkarem, northern part of the West Bank. The concentrations of pesticides in Jenin was found to be higher than those in Tulkarem where the majority of the samples taken had concentration 10 µg/L. It is concluded that the contamination of the tested wells was due to pesticides and not wastewater disposal, since most of the samples were free from pathogenic indicators. Results revealed that using these wells for drinking purposes has a potentially high health risk. This is mainly due to the uncontrolled industrial and agricultural activity as well as the lack of monitoring. Concentrations of heavy metals including cadmium (Cd), lead (Pb), iron (Fe), zinc (Zn), chromium (Cr) and copper (Cu) were also quantitatively determined for the same period extending from April, 2004 to May, 2005. Concentrations of Pb and Cr in most of the tested wells in Tulkarem complied with the WHO guideline; while nitrate (NO3) and potassium (K) concentrations exceeded the permissible concentra-tions. Diunduh dari: http://www.scirp.org/journal/PaperInformation.aspx?paperID=5271 Nutrient Cycling in Agroecosystems Volume 36, Number 2 (1993), 135-140, DOI: 10.1007/BF00747584 Changing fertilizer practices J. S. Yeates Traditional fertilizer practices using mostly single (ordinary) superphosphate applied to pastures on sandy-surfaced soils in the coastal areas of south-western Australia has contributed greatly to the eutrophication of waterbodies of the region. To reduce eutrophication, it is necessary to modify traditional fertilizer practices, involving the accurate definition of nutrient requirements for specific situations, and the evaluation of fertilizer strategy options to achieve optimal levels of yield. A model was developed to integrate available information on phosphorus, sulphur and potassium responses in pastures, and to estimate optimum fertilizer application requirements. The model uses a Mitscherlich function to describe pasture responses to applied fertilizer. Use of the model to estimate optimum fertilizer application rates also allows evaluation of the cost to agricultural production of reducing fertilizer application rates based on environmental rather than on agricultural productivity objectives. Diunduh dari: http://www.springerlink.com/content/v6g4p0472282h283/ PENCEGAHAN DAN KONTROL PENCEMARAN TANAH o o separate garbage bins can be used to collect different varieties of wastes for recycling purposes paper should not be mixed with glass or plastic which are difficult to recycle RECYCLING OF WASTES o Most of the non-degradable materials can be removed from the wastes and can be recycled to freshly usable one The clothes ,papers and glasses can easily be recycled it reduces the consumption of original resources secondly it lessens the volume of the wastes o o J Zhejiang Univ Sci B. 2008 March; 9(3): 197–209. doi: 10.1631/jzus.B0710626 Mechanisms and assessment of water eutrophication Xiao-e Yang, Xiang Wu, Hu-lin Hao, and Zhen-li He Water eutrophication has become a worldwide environmental problem in recent years, and understanding the mechanisms of water eutrophication will help for prevention and remediation of water eutrophication. In this paper, recent advances in current status and major mechanisms of water eutrophication, assessment and evaluation criteria, and the influencing factors were reviewed. Water eutrophication in lakes, reservoirs, estuaries and rivers is widespread all over the world and the severity is increasing, especially in the developing countries like China. The assessment of water eutrophication has been advanced from simple individual parameters like total phosphorus, total nitrogen, etc., to comprehensive indexes like total nutrient status index. The major influencing factors on water eutrophication include nutrient enrichment, hydrodynamics, environmental factors such as temperature, salinity, carbon dioxide, element balance, etc., and microbial and biodiversity. The occurrence of water eutrophication is actually a complex function of all the possible influencing factors. The mechanisms of algal blooming are not fully understood and need to be further investigated. Diunduh dari: LAND-FILLING CONSTRUCTION OF SANITARY LATRINES DILUTION. Dilution is one way of removing pollutants from the soil . It involves running large quantities of water through the soil to leach out the pollutants VAPOUR EXTRACTION. In vapour extraction ,air is injected in to the soil to remove organic compounds that evaporate quickly. Bioremediation cleans up the soil by introducing bacteria and other micro-organisms. OTHER MEASURES steps should be taken to prevent and control soil erosion strict pollution control legislation and effective implementation should be made use of biopesticides over chemical pesticides should be encouraged biodegradable organic waste should be used for generation of biogas. PNAS July 19, 2005 vol. 102 no. 29 10002-10005 Eutrophication of aquatic ecosystems: Bistability and soil phosphorus Stephen R. Carpenter Eutrophication (the overenrichment of aquatic ecosystems with nutrients leading to algal blooms and anoxic events) is a persistent condition of surface waters and a widespread environmental problem. Some lakes have recovered after sources of nutrients were reduced. In others, recycling of phosphorus from sediments enriched by years of high nutrient inputs causes lakes to remain eutrophic even after external inputs of phosphorus are decreased. Slow flux of phosphorus from overfertilized soils may be even more important for maintaining eutrophication of lakes in agricultural regions. This type of eutrophication is not reversible unless there are substantial changes in soil management. Technologies for rapidly reducing phosphorus content of overenriched soils, or reducing erosion rates, are needed to improve water quality. Diunduh dari: http://www.pnas.org/content/102/29/10002.long Soil Pollution: Masuknya zat-zat, organisme biologis, atau energi ke dalam tanah, sehingga mengakibatkan perubahan kualitas tanah, yang kemungkinan akan mempengaruhi penggunaan tanah secara normal atau membahayakan kesehatan masyarakat dan lingkungan hidup. Soil Use and Management Volume 27, Issue 3, pages 404–414, September 2011 Effects of conservation agriculture on runoff, soil loss and crop yield under rainfed conditions in Tigray, Northern Ethiopia Tesfay Araya, W. M. Cornelis, J. Nyssen, B. Govaerts, H. Bauer, Tewodros Gebreegziabher, Tigist Oicha, D. Raes, K. D. Sayre, Mitiku Haile, J. Deckers An experiment was carried out in a rainfed field using a permanent raised bed planting system for 3 yr (2005–2007) in Adigudem, northern Ethiopia in order to evaluate the effect of CA on runoff, soil loss and crop yield. CA practices were introduced in fields with Vertisols in a randomized complete block design on permanent 5 × 19 m plots. Three treatments were evaluated: (1) conventional tillage (CT) with a minimum of three tillage operations and removal of crop residues, (2) terwah (TER) that was similar to CT except that contour furrows were included at 1.5 m intervals, and (3) derdero+ (DER+), which consists of permanent raised beds with a furrow and bed system, retention of 30% of standing crop residues and zero tillage on the top of the bed. All ploughing as well as the maintenance of the furrows of the permanent raised beds was done using a local ard plough called maresha. Results from monitoring over 3 yr showed that soil loss and runoff were significantly higher (P < 0.05) in CT followed by TER and DER+. Average soil losses of 5.2, 20.1 and 24.2 t/ha were recorded from DER+, TER and CT, respectively. Runoff was 46.3, 76.3 and 98.1 mm from DER+, TER and CT, respectively. Grain yield was significantly lower (P < 0.05) in DER+ under teff in 2006, probably due to the high sensitivity of teff to weeds. The yield of wheat in 2007 was significantly higher in DER+ followed by TER. The terwah system is recommended as a first measure for wider adoption to reduce runoff and soil loss and to increase crop yield. The long-term goal is to achieve a derdero+ system, i.e. a permanent raised bed planting system along with the application of crop residues. Soil contaminants are spilled onto the surface through many different activities. Most of these are the result of accidents involving the vehicles that are transporting waste material from the site at which it originated to the site at which it is to be disposed. Soil contamination is caused by the presence of man-made chemicals or other alteration in the natural soil environment. This type of contamination typically arises from the rupture of underground storage tanks, application of pesticides, percolation of contaminated surface water to subsurface strata, oil and fuel dumping, leaching of wastes from landfills or direct discharge of industrial wastes to the soil. The most common chemicals involved are petroleum hydrocarbons, solvents, pesticides, lead and other heavy metals. JAWRA Journal of the American Water Resources Association Volume 7, Issue 1, pages 124–132, February 1971 CONCENTRATIONS OF POLLUTANTS IN AGRICULTURAL RUNOFF Dan M. Wells, Ellis W. Huddleston, Robert G. Rekers Eighteen rural lakes in Lubbock County were sampled on a routine basis following runoff-producing rainfall for a period of approximately eighteen months to determine whether or not runoff from intensively farmed agricultural areas contained significant concentrations of nitrates, phosphates, herbicides, or insecticides. An additional fifteen lakes lying within a triangle bounded by the cities of Plainview, Canyon, and Hereford, Texas, were sampled one time during the summer of 1969 to provide additional data regarding the nature and extent of the potential problem in an area with a different soil type and a slightly different cropping pattern. Based on results of detailed analyses of pproximately two hundred samples of water collected from the lakes and an equal number of sediment samples collected from the same lakes at the same time, it appears that the concentrations of all chemical pollutants in runoff from agricultural lands in the High Plains are well below the allowable concentrations for drinking water. Diunduh dari: http://onlinelibrary.wiley.com/doi/10.1111/j.1752- Polutan di Permukaan Tanah When any liquid pollutant is on or just below the ground surface for any period of time, one of three things could happen to it, if it is not cleaned up first. 1- pollutant might be washed away by precipitation, causing little or no harm to the ground on which it was found ( however, pollutants will simply accumulate somewhere else) The pressure of diffuse pollution on soils: polluted soils will eventually loose their important function as filter and buffer in the water cycle. Soils are the key element in the water cycle determining the quality of groundwater, surface water, and finally drinking water. Diunduh dari: http://www.eugris.info/FurtherDescription.asp?Ca=2&Cy=0&T=Diffuse%20pollution&e=91 Water Research Volume 21, Issue 8, 1987, Pages 889–890 Fluoride in irrigation waters of Agra district, Uttar Pradesh Vinay Singh, Ram Narain, Chandra Prakash Air bawah tanah di daerah semi-kering Agra diperiksa untuk mengetahui konsentrasi F dan kandungan bahan kimia lainnya. Konsentrasi F di perairan bervariasi 0,2-3,2 mg / l dan 56% dari air yang mengandung konsentrasi F yang membahayakan, ternyata dipakai untuk air minum. Namun, perairan ini tidak berbahaya bagi sebagian besar tanaman sehubungan dengan konsentrasi F nya. Konsentrasi fluoride tidak berkorelasi dengan EC, B dan konsentrasi Na dari air tanah. Diunduh dari: http://www.sciencedirect.com/science/article/pii/S0043135487800040 .. Journal of Hazardous Materials Volume 171, Issues 1–3, 15 November 2009, Pages 189–199 Nitrate contamination in groundwater of some rural areas of Rajasthan, India Surindra Suthar , Preeti Bishnoi, Sushma Singh, Pravin K. Mutiyar, Arvind K. Nema, Nagraj S. Patil Efforts were made to evaluate the level of nitrate in some agro-economy based rural habitations of northern Rajasthan, India. A total of 64 groundwater samples from 21 different villages/sub-villages of district Sri Ganganagar, India were collected and analyzed for nitrate (as NO3−), sulphate (as SO42−) and few other parameters. NO3− level in groundwater was 7.10–82.0 mg l−1 for individual samples. But average NO3− for total samples was 60.6 ± 33.6 (SD) mg l−1, which indicates the non-suitability of groundwater for drinking purposes, if BIS permissible limit (22.6 mg l−1) is considered as reference level. SO42− ranged form 28.6 to 660.3 mg l−1 in this area. The regression analysis indicates the difference sources for NO3− and SO42− contamination in different regions rather than a common source. The point and non-point sources of NO3− and SO42− in groundwater of this region may be Nfertilizer, sewerage, animal waste, organic manure, geology of sub-surface soil layers, pit latrines, etc. Results thus indicated that groundwater of this part of the State is severely polluted due to anthropogenic activities. The continuous consumption of such water may pose serious health hazardous in local residents. Diunduh dari: http://www.sciencedirect.com/science/article/pii/S0304389409008929 Polutan di Permukaan Tanah 1. 2. the pollutant, if volatile, could evaporate, again causing little harm to the soil ( however, not a solution to the bigger pollution problem, as it might become a source of air pollution). pollutant could infiltrate through the unsaturated soil, in much the same way as ground water. The genesis and evolution of soil and groundwater pollution. Pollutants percolate through soil, simultaneously releasing into the gas-phase volatile components, if any, that can also diffuse back to the atmosphere. Diunduh dari: http://wpage.unina.it/giutosca/mesocosmo/index_en.html Agricultural Sciences in China Volume 10, Issue 3, March 2011, Pages 423–430 Investigations on Nitrate Pollution of Soil, Groundwater and Vegetable from Three Typical Farmlands in Beijing Region, China Lian-feng DU, , Tong-ke ZHAO, , Cheng-jun ZHANG, Zhi-zhuang AN, Qiong WU, Bao-cun LIU, Peng LI, Mao-ting MA The aim of this study was to determine the nitrate pollution status of soil, groundwater, and vegetable from three typical farmlands (croplands, vegetable fields, and orchards) in Beijing region. During the investigation, hundreds of the soil, groundwater, and vegetable samples from three typical farmlands were collected and analyzed. In addition, attributes of all samples were recorded for data analysis. The results showed that nitrate was substantially accumulated in soil profiles, while the soil nitrate concentrations of vegetable fields and orchards were higher than those of croplands. Nitrate concentration in 0-30 cm soil of vegetable field and orchard were 3.8 and 1.2 times of that of cropland, respectively. Nitrate content of groundwater in vegetable field was 13.8 mg L−1 (with the over-standard ratio 44.8%), which was 2.8 folds of that in cropland. Nitrate concentration of groundwater under orchard was 9.3 mg L−1 (with the over-standard ratio 23.5%), which was 1.9 folds of that in cropland. High concentrations of the nitrate in vegetables were detected, particularly green leafy vegetables ranked first with 2 685.5 mg kg−1, followed by rhizome vegetables, cabbages, and fruit vegetables. The nitrate over-standard ratios of rhizome vegetables, green leafy vegetables, fruit vegetables, and cabbages were 80.9, 37.9, 29.7, and 2.2%, respectively. The results revealed that the high nitrate concentrations of soil, vegetable, and groundwater might result from the high fertilization dose. Diunduh dari: http://www.sciencedirect.com/science/article/pii/S1671292711600217 Polutan di Permukaan Tanah Agricultural practices, including the use of agricultural chemicals, are another primary source of pollution on or near the ground surface. Most agricultural chemicals are watersoluble nitrates and phosphates that are applied to fields, lawns and gardens to stimulate the growth of crops, grass and flowers. Soil health in agricultural systems M.G Kibblewhite, K Ritz and M.J Swift. Soil health is presented as an integrative property that reflects the capacity of soil to respond to agricultural intervention, so that it continues to support both the agricultural production and the provision of other ecosystem services. The major challenge within sustainable soil management is to conserve ecosystem service delivery while optimizing agricultural yields. It is proposed that soil health is dependent on the maintenance of four major functions: carbon transformations; nutrient cycles; soil structure maintenance; and the regulation of pests and diseases. Each of these functions is manifested as an aggregate of a variety of biological processes provided by a diversity of interacting soil organisms under the influence of the abiotic soil environment. Analysis of current models of the soil community under the impact of agricultural interventions (particularly those entailing substitution of biological processes with fossil fuel-derived energy or inputs) confirms the highly integrative pattern of interactions within each of these functions and leads to the conclusion that measurement of individual groups of organisms, processes or soil properties does not suffice to indicate the state of the soil health. A further conclusion is that quantifying the flow of energy and carbon between functions is an essential but non-trivial task for the assessment and management of soil health. Phil. Trans. R. Soc. B 27 February 2008 vol. 363 no. 1492 685-701 Ag Chemicals 1. 2. When not used by the plants the nutrients can enter streams and lakes during the run-off or leaching events. Once in a body of water, these chemicals continue to promote the growth of plants, the resulting plant detritus is food for micro-organisms, and as the population of such organisms grows, the supply of oxygen in the water is depleted. Optimizing nutrient management for farm systems Keith Goulding, Steve Jarvis and Andy Whitmore Increasing the inputs of nutrients has played a major role in increasing the supply of food to a continually growing world population. However, focusing attention on the most important nutrients, such as nitrogen (N), has in some cases led to nutrient imbalances, some excess applications especially of N, inefficient use and large losses to the environment with impacts on air and water quality, biodiversity and human health. In contrast, food exports from the developing to the developed world are depleting soils of nutrients in some countries. Better management of all essential nutrients is required that delivers sustainable agriculture and maintains the necessary increases in food production while minimizing waste, economic loss and environmental impacts. More extensive production systems typified by ‘organic farming’ may prove to be sustainable. However, for most of the developed world, and in the developing world where an ever-growing population demands more food, it will be essential to increase the efficiency of nutrient use in conventional systems. Nutrient management on farms is under the control of the land manger, the most effective of whom will already use various decision supports for calculating rates of application to achieve various production targets. Increasingly, land managers will need to conform to good practice to achieve production targets and to conform to environmental targets as well. . Phil. Trans. R. Soc. B 12 February 2008 vol. 363 no. 1491 667-680 B.O.D. "Biochemical Oxygen Demand", or "BOD". This means that the water is capable of supporting a large population of bacteria that will have a high demand for oxygen. Biochemical oxygen demand curves: (A) typical carbonaceous-demand curve showing the oxidation of organic matter, and (B) typical carbonaceous- plus nitrogeneousdemand curve showing the oxidation of ammonia and nitrite. (Modified from Sawyer and McCarty, 1978.) Diunduh dari: http://water.usgs.gov/owq/FieldManual/Chapter7-Archive/chapter7.2/7.2.html Agriculture and Environment Volume 3, Issue 1, December 1976, Pages 57–67 Nitrate pollution of groundwater from nitrogen fertilizers and animal wastes in the Punjab, India Bijay Singh, G.S. Sekhon Fifty-seven water samples were obtained from wells situated on cultivated farms and near village settlements in the Ludhiana and Hoshiarpur districts of Punjab (India). Water samples collected in June and September, 1975 were analysed for nitrate. Probability plots indicated that 90% of the well-water samples may contain less than 45 mg NO3−/l, the upper safe limit. The nitrate content of well water near villages was significantly higher than in the cultivated area. Animal wastes appear to be the major contributor in the village environment. The nitrate concentration of well water decreased significantly with depth to water table, but correlated positively with amount of nitrogenous fertilizers added per unit area per year. Soil profile samples taken in June, 1975 from farms in the immediate vicinity of the sampled wells were analysed for nitrate and water content. The amount of NO3− contained in the soil profile down to 2.10 m depth correlated significantly with the nitrate concentration of well water in September, thus confirming that nitrates tend to reach the water table during the rainy season (July–September). The projected geometric mean nitrate concentration of ground water (computed on the expectation that the nitrate content of the saturated zone would equal that of the 1.50−2.10 m soil layer) was found to be 35.6 mg NO3−/l, many times higher than the observed mean of 1.88 mg NO3−1/l. Diunduh dari: http://www.sciencedirect.com/science/article/pii/0304113176900072 Phil. Trans. R. Soc. B 12 February 2008 vol. 363 no. 1491 659-666 Water pollution by agriculture Brian Moss School of Biological Sciences, University of Liverpool Liverpool L69 3BX, UK (brmoss@liverpool.ac.uk) Agriculture disrupts all freshwater systems hugely from their pristine states. The former reductionist concept of pollution was of examining individual effects of particular substances on individual taxa or sub-communities in freshwater systems, an essentially ecotoxicological concept. It is now less useful than a more holistic approach that treats the impacts on the system as a whole and includes physical impacts such as drainage and physical modification of river channels and modification of the catchment as well as nutrient, particulate and biocide pollution. The European Water Framework Directive implicitly recognizes this in requiring restoration of water bodies to ‘good ecological quality’, which is defined as only slightly different from pristine state. The implications for the management of agriculture are far more profound than is currently widely realized. DIUNDUH DARI: http://rstb.royalsocietypublishing.org/content/363/1491/659.short Biocontrol- avoiding use of chemicals 1. 2. 3. Choose a cover crop as a bio-control for a specific pest Time tillage to give crops the best advantage from the resulting biological activity Manage habitats at the edge of fields to support predators of pests General model for an integrated pest management (IPM) program. Diunduh dfari: http://www.apsnet.org/publications/apsnetfeatures/Pages/biocontrol.aspx Procedia Environmental Sciences Volume 4, 2011, Pages 294–302 Effect of chemical nitrogen fertilizer application on the release of arsenic from sediment to groundwater in Bangladesh Md. Shamim Uddin, Kiyoshi Kurosawa The effect of chemical nitrogen fertilizer application on groundwater arsenic pollution was examined. Arsenic and N concentrations in peat sediment were high. In the groundwater, a high arsenic concentration was observed under a high ammonium-N concentration with reducing conditions. From _15N analysis, the source of N in peat sediment and groundwater was possibly chemical N fertilizer. Thus, we assumed that a high N environment created by the fertilizer led the groundwater to reducing conditions through the enhancement of microbial activity, and the reducing condition promoted the arsenic release from peat sediment to the groundwater. Diunduh dari: http://www.sciencedirect.com/science/article/pii/S1878029611000600 Phil. Trans. R. Soc. B 27 February 2008 vol. 363 no. 1492 789-813 Greenhouse gas mitigation in agriculture Pete Smith, Daniel Martino, Zucong Cai, Daniel Gwary, Henry Janzen, Pushpam Kumar, Bruce McCarl, Stephen Ogle, Frank O'Mara, Charles Rice, Bob Scholes, Oleg Sirotenko, Mark Howden, Tim McAllister, Genxing Pan, Vladimir Romanenkov, Uwe Schneider, Sirintornthep Towprayoon, Martin Wattenbach and Jo Smith. Agricultural lands occupy 37% of the earth's land surface. Agriculture accounts for 52 and 84% of global anthropogenic methane and nitrous oxide emissions. Agricultural soils may also act as a sink or source for CO2, but the net flux is small. Many agricultural practices can potentially mitigate greenhouse gas (GHG) emissions, the most prominent of which are improved cropland and grazing land management and restoration of degraded lands and cultivated organic soils. Lower, but still significant mitigation potential is provided by water and rice management, set-aside, land use change and agroforestry, livestock management and manure management. The global technical mitigation potential from agriculture (excluding fossil fuel offsets from biomass) by 2030, considering all gases, is estimated to be approximately 5500–6000 Mt CO2eq. yr−1, with economic potentials of approximately 1500–1600, 2500–2700 and 4000–4300 Mt CO2eq. yr−1 at carbon prices of up to 20, up to 50 and up to 100 US$ t CO2-eq.−1, respectively. In addition, GHG emissions could be reduced by substitution of fossil fuels for energy production by agricultural feedstocks (e.g. crop residues, dung and dedicated energy crops). The economic mitigation potential of biomass energy from agriculture is estimated to be 640, 2240 and 16 000 Mt CO2-eq. yr−1 at 0–20, 0–50 and 0–100 US$ t CO2-eq.−1, respectively. Biocontrol 1. 2. Choose pesticides partially based on the nontarget organisms they affect Choose a source of compost and manure based on how it impacts disease or cropenhancing organisms Diunduh dari: http://www.ucc.ie/en/biomerit/Research/envbio/ Soil Pollution Information needed to clean up materials added to soil include: 1) Kind of material - organic or inorganic - is the material biodegradable, is the material dangerous to animals and humans, 2) how much material was added to the soil, will it overload the organisms in the soil; 3) C:N ratio of the material, are additional nutrients needed ( N & P) Soil Pollution 4) Kind of Soil - will the soil be able to handle the material before groundwater is contaminated, 5) Growing conditions for the soil organisms - is it too cold, too wet etc. 6) How long has the material been on the site - is there evidence of environmental problems, is it undergoing decomposition. 7) Immediate danger to people and the environment - Urgency of the situation. Bioremediation Proses pengolahan yang menggunakan mikroorganisme (jamur, jamur, atau bakteri) biasanya dilakukan untuk memecah, atau mendegradasi substansi toksik menjadi zat yang kurang beracun atau tidak beracun (karbon dioksida dan air) FERTILIZER POLLUTION REDUCTION STRATEGIES Theresa Connor, P.E., General Manager, and Jack Merriam Environmental Manager Sarasota County Water Planning and Regulatory 1001 Sarasota Center Blvd., Sarasota, Fl 34240 Sarasota County became interested in controlling pollution from fertilizers as a result of community concerns about red tide blooms over the last several years. The Board of County Commissioners asked staff to look at ordinances to control fertilizer usage such as the one passed in St. Johns County. After looking at the St. Johns County ordinance and talking with their staff and commissioners Sarasota County decided to pursue a different route. Instead of jumping right in and passing an ordinance, Sarasota County decided to establish a series of “Community Conversations” with four different stakeholder groups: industry, government, civic groups, and environmental groups to look at all options. The conversations were a series of facilitated meetings which worked through questions or exercises with the ultimate goal of developing a set of comprehensive recommendations to the Board of County Commissions. The details of the process, statistics from survey questions, and the final recommendations will be part of the paper. http://www.stormwater.ucf.edu/conferences/9thstormwatercd/documents/fertili Conditions that favor Bioremediation 1. 2. 3. 4. 5. 6. Temperature favorable for organisms Water available (near field capacity) Nutrients (N, P, K) in adequate supply C:N ratio of material < 30:1 Material added is similar to naturally occurring organic material Oxygen in sufficient quantity In-situ-Bioremediation Biostimulation (stimulates biological activity) Bioventing (Inject air/nutrients into unsaturated zone – good for midweight petroleum, jet fuel) Biosparging (Inject air/nutrients into unsaturated and saturated zones) Bioaugmentation (inoculates soil with microbes) Less expensive •Creates less dust •Less possibility of contaminant release into environment •Good for large volumes •Slower •Doesn’t work well in clays or highly layered subsurfaces Biostimulation Biosparging Research of Environmental Sciences, Vol.13, No.3, 2000. Characteristics and Control Countermeasures of Pesticide Pollution and Its Damage on Environment in China Hua Xiaomei , Jiang Xiliu This paper summarized the present status and main characteristics of pesticide pollution and damage on environment with respect of acute damage and long -term and potential effects. The causes of environmental damage resulting from pesticides were analyzed. Suggestions that pesticide product structure need to be adjusted and that environment management for pesticides needs to be enhanced were proposed as an important approach for current effective control of the environmental damage. Diunduh dari: http://www.oecd.org/dataoecd/21/58/1934406.pdf Rev. salud pública [online]. 2010, vol.12, n.2, pp. 300-307. ISSN 0124-0064. TOBON-MARULANDA, Flor á; LOPEZ-GIRALDO, Luís A and PANIAGUA-SUAREZ, Ramón E. Water pollution caused by pesticides in an area of Antioquia. Objective Determining the frequency of pesticide use in agricultural, pig and poultry production to understand its influence on water resources in the village of Monterredondo in the municipality of San Pedro de Los Milagros (Antioquia) and diagnosing its quality. Methods 100 % of the households in the village were surveyed regarding chemical use. Physicochemical and microbiological analysis of three water samples was carried out in the Universidad de Antioquia's Environmental Engineering laboratory using standardised methods. Results The Hato stream was contaminated by 1,600x103 NMP/100ml coliforms and 220x10 NMP/100ml E. coli. The Fray Juana stream had 1,600x103 NMP/100ml coliform contamination. Water sources were also contaminated by the use of pesticides such as Lorsban (chlorpyriphs), Burst (chlorpyriphs), Whip (chlorpyriphs), Neguvon (metriphonate) and Furadan (carbophuran) and insecticides like Ganabaño (cypermethryn) and disinfectants and Limpido (6 % sodium hypochlorite). Conclusion Agricultural, pig and poultry production in the village has been producing a negative impact on water resources due to its reduced availability and pollution. The water from the samples analysed here was not suitable for human consumption. Diunduh dari: http://www.scielo.org.co/scielo.php?pid=S0124- Ex-situ -Bioremediation Slurry-phase Soil combined with water/additives in tank, microorganisms, nutrients, oxygen added Solid-phase Land-farming: soil put on pad, leachate collected Soil biopiles: soil heaped, air added Composting: biodegradable waste mixed with bulking agent • Easier to control • Used to treat wider range of contaminants and soil types • Costly • Faster http://naldc.nal.usda.gov/download/18701/PDF Nutrient Cycling in Agroecosystems 59: 269–284, 2001. Processes controlling soil phosphorus release to runoff and implications for agricultural management R.W. McDowell , A.N. Sharpley, L.M. Condron, P.M. Haygarth & P.C. Brookes. Phosphorus (P) loss from agricultural land to surface waters is well known as an environmental issue because of the role of P in freshwater eutrophication. Much research has been conducted on the erosion and loss of P in sediments and surface runoff. Recently, P loss in sub-surface runoff via agricultural drainage has been identified as environmentally significant. High soil P levels are considered as a potential source of P loss. However, without favourable hydrological conditions P will not move. In this paper, we review the basis of soil P release into solution and transport in surface and sub-surface runoff. Our objectives are to outline the role of soil P and hydrology in P movement and management practices that can minimize P loss to surface waters. Remedial strategies to reduce the risk of P loss in the short-term are discussed, although it is acknowledged that long-term solutions. Affect of soil pH on adsorption of 4 heavy metals Pb Adsorption Cu Zn Cd 3 3.5 4 Soil pH 4.5 5 5.5 6 6.5 7.0 Annu. Rev. Energy Environ. 2000. 25:53–88 Copyright c 2000 by Annual Reviews. All rights reserved PHOSPHORUS IN THE ENVIRONMENT: Natural Flows and Human Interferences Vaclav Smil Phosphorus has a number of indispensable biochemical roles, but it does not have a rapid global cycle akin to the circulations of C or N. Natural mobilization of the element, a part of the grand geotectonic denudation-uplift cycle, is slow, and low solubility of phosphates and their rapid transformation to insoluble forms make the element commonly the growth-limiting nutrient, particularly in aquatic ecosystems. Human activities have intensified releases of P. By the year 2000 the global mobilization of the nutrient has roughly tripled compared to its natural flows: Increased soil erosion and runoff from fields, recycling of crop residues and manures, discharges of urban and industrial wastes, and above all, applications of inorganic fertilizers (15 million tonnes P/year) are the major causes of this increase. Global food production is now highly dependent on the continuing use of phosphates, which account for 50–60% of all P supply; although crops use the nutrient with relatively high efficiency, lost P that reaches water is commonly the main cause of eutrophication. This undesirable process affects fresh and ocean waters in many parts of the world. More efficient fertilization can lower nonpoint P losses. Although P in sewage can be effectively controlled, such measures are often not taken, and elevated P is common in treated wastewater whose N was lowered by denitrification. Long-term prospects of inorganic P supply and its environmental consequences remain a matter of concern. Forms of heavy metals found in soils that had received sewage sludge (45mg/ha) for 5 years % of Elements in each form Forms Cd Exchangeable/adsorbed Organically bound Carbonate/iron oxides residual * 1 20 64 16 Cr Cu Ni Pb Zn 1 5 19 77 2 34 36 29 5 24 33 40 1 2 3 28 85 39 12 31 * sulfides and other very insoulble forms .. January 2005 Quarterly Journal of Engineering Geology and Hydrogeology, 38, 53-63. Pesticide pollution of the Triassic Sandstone aquifer of South Yorkshire D. C. Gooddy, M. E. Stuart, D. J. Lapworth, P. J. Chilton, S. Bishop, G. Cachandt, M. Knapp and T. Pearson Diffuse pollutants such as pesticides pose a significant threat to groundwater quality. Following the wet autumn and winter of 2000–2001 an upturn in trace pesticide concentrations was detected in blended water drawn from part of the Triassic Sandstone aquifer. A groundwater sampling and monitoring programme was undertaken to assess whether this increase would continue. Over a period of 18 months, 190 groundwater samples were collected from the upper part of the aquifer and analysed for 40 pesticides and for nitrate. A total of 25 pesticides were found of which 16 were detected more than once. Positive pesticide detections were in excess of the EU maximum admissible concentration (MAC) for individual substances of 0.1 μg l−1 on 33% of occasions. The most commonly detected pesticides generally have higher agricultural application rates and/or relatively greater solubilities. Very high concentrations of mecoprop (up to 7.1 μg l−1) were consistently found at two of the sampling sites. Analysis of mecoprop enantiomers suggested more than one source for this contaminant. High concentrations of atrazine (up to 1.4 μg l−1) were also detected at three sites and high concentrations of isoproturon (1.2 μg l−1) were found where very high mecoprop concentrations were also present. Nitrate concentrations exceed the EU MAC of 11.3 mg l−1 N at four sites. The spatial and temporal distribution of pesticides obtained from the monitoring network shows no clear trends for prediction of future concentrations. Nitrate-N concentrations and pesticide detections show no clear relationship, suggesting different source, transport or degradation pathways. Diunduh dari: . http://qjegh.lyellcollection.org/content/38/1/53.abstract SOIL POLLUTION CONTROL PENGENDALIAN PENCEMARAN TANAH CLEAN – Soil, Air, Water Volume 39, Issue 4, pages 356–361, April, 2011 Pesticide Pollution in Surface- and Groundwater by Paddy Rice Cultivation: A Case Study from Northern Vietnam Marc Lamers, Maria Anyusheva, Nguyen La, Van Vien Nguyen, Thilo Streck This study was designed to examine the environmental exposure of surface- and groundwater pollution in remote mountainous regions of northern Vietnam. In 2008, we monitored the loss of four commonly applied pesticides (imidacloprid, fenitrothion, fenobucarb, dichlorvos) from paddy rice farming systems to a receiving stream on the watershed scale and quantified groundwater pollution. For the entire monitoring period, runoff loss of pesticides from the watershed was estimated to range between 0.4% (dichlorvos) and 16% (fenitrothion) of the total applied mass. These losses were correlated well with the octanol–water partition coefficient and water solubility of pesticides (r2 = 0.78–0.99). In the groundwater collected from eight wells, all target pesticides were frequently detected. Maximum measured concentrations were 0.47, 0.22, 0.17, and 0.07 µg L −1 for fenitrothion, imidacloprid, fenobucarb, and dichlorvos, respectively. Our results strongly indicate that under the current management practice pesticide use in paddy fields poses a serious environmental problem in mountainous regions of northern Vietnam. Diunduh dari: http://onlinelibrary.wiley.com/doi/10.1002/clen.201000268/abstract PENGENDALIAN PENCEMARAN TANAH Tanah yang terkontaminasi merupakan salah satu masalah lingkungan yang secara historis diabaikan oleh manusia. Akhir-akhir ini, hubungannya dengan dampak kesehatan manusia dan dampak ekologinya mulai dibahas. Teknik yang paling banyak digunakan pada tanah yang tercemar adalah “mengambil” dan “Membuang”nya di lingkungan TPA yang lebih aman. Diffuse Pollution Conference Dublin 2003 3F: Agriculture 3-125 HOW MUCH DOES DIFFUSE POLLUTION AFFECT AN AQUATIC ECOSYSTEM Hideo NAKASONE and Tomohisa YAMAMOTO Japanese people like green tea very much, as well as its vivid green color and sweet taste. In order to produce such kind of tea, farmers apply a great amount of nitrogen fertilizer. The amount of fertilizer has reached to 1,000 kg/ha to our understanding heard from several farmers. Tea plants uptake about 300 kg/ha, hence, the residues become diffused pollution. Since the soil condition of tea fields is aerobic, ordinary nitrogen fertilizer oxidizes to nitrate quickly and diffuses into soils. Usually the cation exchange capacity (CEC) of soil is great, however, if a great amount of nitrate acid soil loses its CEC, then the H+ ions runoff. We observed that the pH is 4.3 in small river water, and further when there was heavy rain, the river water became below a pH of 3.5 at times. As a result, the small irrigation reservoir receives this water below pH 5.0, and thus fauna cannot live there. Diunduh dari: http://www.ucd.ie/dipcon/docs/theme03/theme03_24.PDF PENGENDALIAN PENCEMARAN TANAH Meskipun sangat mudah untuk mengambil tanah yang terkontaminasi dari satu tempat dan dipindahkan ke tempat lain, namun akan lebih bermanfaat kalau remediasinya dalam bentuk disain landfill. Seringkali TPA ditempatkan di lahan basah atau berdekatan dengan sungai, sehingga mendorong migrasi kontaminan dan akhirnya mengancam penduduk sekitar. The Effects of Fertilizer Pollution The major issue with fertilizer pollution is a process called eutrophication, where the surface of a body of water becomes nutrient rich, causing an algal bloom. When the algae start to die off, the organic material in the water will reduce the available oxygen in the water, causing many other organisms to die off. Eutrophication is a natural process for warm, shallow lakes, but the addition of fertilizer pollutants can make the process occur over a series of decades, as opposed to centuries. Fertilizer pollution can even harm larger bodies of water, like the Gulf of Mexico. The northern Gulf of Mexico has a dead zone, where oxygen in the water is not sufficient for most forms of life, starting at the mouth of the Mississippi, where surface water pollutants from half the country wind up, and spread over about 6,000 square miles of water. Read more: Fertilizers & Pollution | eHow.com http://www.ehow.com/info_7962176_fertilizers-pollution.html#ixzz20XYAZSlC PENGENDALIAN PENCEMARAN TANAH Limbah dapat distabilkan setelah pembuangan, dan sebelum atau selama penempatan untuk mengurangi mobilitas setelah penempatannya. Stabilisasi mungkin termasuk pemadatan dengan beton atau bahan serupa atau perlakuan kimia secara langsung bahan-bahan kontaminan tertentu. Pembakaran atau perlakuan termal dari tanah yang terkontaminasi dapat digunakan untuk menghilangkan kontaminan organik yang tidak tahan panas atau yang mudah terbakar. Nutrient Cycling in Agroecosystems Volume 26, Numbers 1-3 (1990), 209-215, DOI: 10.1007/BF01048758 Environmental effects of N fertilizer use — An overview B. H. Byrnes In recent years concern has grown over the contribution of nitrogen (N) fertilizers to the environmental problems of nitrate pollution of waters and the pollution of the atmosphere with nitrous oxide, other oxides of nitrogen, and ammonia. These gases potentially contribute to the greenhouse effect or global heating because of their increasing concentrations in the atmosphere and to the destruction of the stratospheric ozone layer, which protects the earth from ultraviolet radiation. In light of these concerns, proposals to mitigate these problems have been considered, and others will be forthcoming. When they have been used in high amounts, fertilizers and animal manures have created problems of nitrate pollution. Nitrous oxide (N2O) is a greenhouse gas and may also contribute to the destruction of the stratospheric ozone when it is converted to nitric oxide. N2O is primarily produced in the biological processes of nitrification and denitrification. Nitric oxide and nitrogen dioxide are also produced in biological processes and are important in atmospheric reactions in the troposphere and stratosphere. There is little indication that N fertilizers contribute very much to the production of nitrous oxide. More research is needed to characterize and measure the emissions of the oxides of nitrogen and ammonia and to make better estimates of global emissions based on process-related models. More efforts to increase the efficiency of nitrogen fertilizer use through modifications or use of inhibitors of biological processes as well as better management of rates, timing, and incorporation are needed to ensure increased food production while conserving natural resources. Diunduh dari: http://www.springerlink.com/content/n0hv432605607657/ PENGENDALIAN PENCEMARAN TANAH A variety of other processes have been employed to treat contaminated soils once excavated and removed from a site. Included among these are biological degradation in dedicated bioreactors and sophisticated extraction schemes, for example, supercritical extraction, followed by the application of destruction processes to the effluent. An alternative to removal options of remediating soil is the use of in situ means that do not require soil removal. These are generally the options of choice if they can be demonstrated effective at reducing the volume, toxicity, or exposure to the wastes. EREM Vol 53, No 3 (2010) Nitrification Potential of Soils under Pollution of a Fertilizer Plant Gintarė Sujetovienė Oil in the form of mineral and organic bonds are available to microbes and plants as NO3- and NH4+, produced in consequence of ammonification, nitrification and N fixation. The laboratory experiment was conducted on samples of podzolic sandy soils. Soil samples were taken in the surroundings of a nitrogen fertilizer plant Achema, situated in the center of Lithuania. The objective of the study was to determine the effect of soil contamination on the nitrification process. Nitrification generally proceeded more rapidly in control soils than in soils under the Achema pollution. On the average, 0.004 mg NO2-N was nitrified per g N mineralized per hour in the plots under the influence of the nitrogen fertilizer producing plant pollution. In comparison with nitrified N in reference soils the values were significantly higher - 0.253 (p < 0.05). Soils from background ecosystems had, on the average, 63 times higher nitrification rate than in polluted soils. The eutrophication of pine sandy soils stimulated biological processes and that was likely related to higher soil pH and initial NH4+. Diunduh dari: http://www.erem.ktu.lt/index.php/erem/article/view/83 PENGENDALIAN PENCEMARAN TANAH The principle option to decontaminate soils are: 1. Removal options for soil remediation 2. In situ soil remediation processes Diunduh dari: http://www.dowa-eco.co.jp/en/soil.html .. Int. J. Environ. Sci. Tech. Vol. 2, No. 1, pp. 41-47, Spring 2005 Agricultural activities impact on groundwater nitrate pollution H. Mahvi, J. Nouri, A. A. Babaei and R. Nabizadeh Concern over agricultural diffuse pollution sources in integrated water quality management has been growing recently. High nitrogen fertilizers application rates may increase the potential groundwater pollution. These effects were investigated in Andimeshk and Susa plains that cover an area of 1100 km2 between the Dez and Karkhe rivers in north of Khozestan-Iran. This region divided to 4 sub-regions A, B, C, and D. Additionally 168 groundwater samples were collected from 42 water wells during the months April, May, August, and September of 2004. The Hackspectrophotometer nitrate test was used to measure the NO3- concentration in water samples. Information about further nitrate data was obtained. A questionnaire procedure was used for collection N-fertilizers application rate data in studied area. The results demonstrated that all of the groundwater samples have NO3- concentration below the EPA MCL (44.27 mg/l) and WHO guideline (50 mg/l). The mean nitrate concentrations are 16.1, 19.5, 13.3, and 7.9 mg/l in sub-regions A, B, C, and D respectively. There are different amount of N-fertilizers applied in sub-regions A, B, C, and D. Correlation between NO3- concentrations and N-fertilizers rate suggests a inverse correlation between N fertilizers application rate and ground waters nitrate concentrations in studied area (r=-0.69). Diunduh dari: http://www.bioline.org.br/pdf?st05006 PENGENDALIAN PENCEMARAN TANAH Removal options for soil remediation • These techniques are techniques that consists in to take the contaminated soil and apply a method to decontaminate. This techniques are: Incineration, landfilling, stabilization and solidification, and ex situ bioremediation. • The methods are the same that are defined in the waste manager chapter. Diunduh dari: http://www.biology-online.org/articles/phytoremediation-alecture/phytostabilization.html PENGENDALIAN PENCEMARAN TANAH TECHNIQUES In situ soil remediation processes • These techniques consist in treat the soil in the same land or place where is contaminated. The techniques or methods are: Pump and treat extraction of contaminated groundwater, enhancement of pump and treat processes, vacuum extraction in the unsaturated zone and in situ bioremediation of soils. • Pump and treat extraction of contaminated groundwater is the technique that remove the contaminated groundwater or separate contaminated phases via withdrawal wells for above-ground treatment. Diunduh dari: http://www.biology-online.org/articles/phytoremediation-a-lecture/different- Environmental Pollution Series B, Chemical and Physical Volume 7, Issue 1, 1984, Pages 43–48 Nitrogen fertilisation and nitrate pollution of groundwater in sandy soils M. Khanif Yusop, O. Van Cleemput, L. Baert The study of the relation between N fertilisation and groundwater pollution was carried out on two fields in the sandy area of Belgium during a two-year period. The fields under study were grown with maize and barley and received fertiliser N and manure at normally applied rates. The NO3−-N and Cl− content of the groundwater at 0·5, 1·0, 1·5 and 2·0 m depth was monitored every two weeks. The total rainfall during the two consecutive years was about 800 mm. On one of the fields, the NO3−-N content at all depths was most of the time above 11·3 mg NO3−-N dm−3, the WHO safe limit. However, on the other field the nitrate level was much lower, except at 0·5 m depth. The difference between the two fields was attributed to differences in the rate of N input. The fluctuations during the two-year study were influenced by N fertilisation and rainfall distribution. The NO3−-N/Cl− ratio indicated that denitrification in the deeper zones of the soil was not prominent. Diunduh dari: http://www.sciencedirect.com/science/article/pii/0143148X84900363 PENGENDALIAN PENCEMARAN TANAH TECHNIQUES • • Enhancement of pump and treat processes are methods of remediation of soils. These methods are of limited usefulness when significant quantities of NAPLs exist. Due to the low solubility of most soil contaminants, large volumes of water are required to remove contaminants present in a separate phase even if it were possible to maintain the water at saturation. Diunduh dari: http://www.biology-online.org/articles/phytoremediation-a- Agriculture and Environment Volume 4, Issue 3, March 1979, Pages 207–225 Nitrate pollution of groundwater from farm use of nitrogen fertilizers — A review Bijay Singh, G.S. Sekhon The fears that the use of fertilizer nitrogen on farms is contributing considerably to nitrate pollution of groundwater have increased in the past few years. Investigations have indicated that nitrate is accumulating in the shallow groundwaters of some irrigated areas with intensive agriculture using fertilizers. In certain areas, natural geologic deposits of nitrate contribute a large percentage of nitrate leached to groundwater formations. Soil organic matter, animal wastes and plant residues also contribute, but their relative inputs are difficult to determine. The amount of fertilizer nitrogen leaching as nitrate below the root zone and the stability of nitrate in the unsaturated zone and in aquifers are the factors that determine the extent of nitrate pollution of groundwater from fertilizer N. The amount and distribution of rain and irrigation affect the leaching of nitrate below the root zone. However, exactly to what extent nitrate leaching occurs is determined by the amount of water percolating down the profile, which in turn is affected by growing plants. Vegetative cover is the most important factor affecting nitrate leaching by utilizing water (as transpiration) and fertilizer nitrogen. Nitrate in the unsaturated zone and aquifers is generally stable because there is insufficient supply of oxidizable carbon for denitrifiers to utilize. But the possibility of such an occurrence is not ruled out. For computing nitrogen application rates which can ensure both optimum crop yields and permissible nitrate leaching loss, the fertilizer efficiency factor needs careful consideration. Maximizing the efficiency of fertilizer nitrogen can reduce the risk of nitrate pollution from fertilizers. Diunduh dari: http://www.sciencedirect.com/science/article/pii/0304113179900225 PENGENDALIAN PENCEMARAN TANAH TECHNIQUES Vacuum extraction in the unsaturated zone is a process that is similar conceptually to pump and treat of groundwater is soil vacuum extraction (SVE) in the water-unsaturated zone. A vacuum is applied to the unsaturated zone by placing a vacuum pump on a well screened in the unsaturated zone. This pulls vapours through the soil, removing any volatile components that have volatilised in the subsurface Diunduh dfari: http://www.biology-online.org/articles/phytoremediation-a- Water Science and Technology Volume 39, Issue 3, 1999, Pages 67–75 Diffuse agricultural nitrate pollution of groundwaters in India G.D. Agrawal, S.K. Lunkad, T. Malkhed Nitrate pollution of groundwater due to urban waste and industrial effluents usually centres around cities. This study has shown that nitrate levels in groundwater over vast agricultural areas can be correlated with intensive irrigated agriculture, corresponding use of nitrogenous fertilizers and groundwater development, and consequent diffuse agricultural pollution has already endangered the safety of potable groundwater for future generations in both rural and urban areas. Chemical and bacterial treatment of groundwater for nitrate removal relies on advanced technology and is considered costly even in the developed world. In a country like India where economic resources are inadequate, action on the suggested preventive measures may be taken without delay at this stage when alarming trends have been recorded. Diunduh dari: http://www.sciencedirect.com/science/article/pii/S0273122399000335 PENGENDALIAN PENCEMARAN TANAH TECHNIQUES • In situ bioremediation of soils is perhaps the most desirable of all treatment processes is in situ biodegradation to render the soil harmless and to naturally recycle the contaminants. • There are a number of compounds that undergo detoxification by microbial processes at rates that are sufficient to justify natural recovery of contaminated soils. Bioremediation is also attractive because of several advantages that its application has over more conventional technology. Bioremediation techniques are typically more economical than more traditional methods. It is estimated that bioremediation would cost one-third to one-half that of incineration. In some cases pollutants can be treated at the site, thus reducing the risk exposure to cleanup personnel and potentially wider exposure as a result of transportation accidents . Diunduh dari: http://agrotechno-park.blogspot.com/2011/10/advantage-and-disadvantages-of.html How Does Fertilizer Pollute? Fertilizer pollution is considered a nonpoint source of water pollution, meaning that there is no single point of contamination, but rather a slow and sporadic addition of the pollutant over a wide area. The fertilizer you add to your lawn or garden can get into the water supply in one of two ways: by being carried off the surface of the land by rainfall, or by seeping through the soil and contaminating the ground water beneath the land. Fertilizer can also pollute if it is accidentally dropped onto paved ground, where it is quickly moved into water runoff without even getting a chance to be absorbed by the soil. Fertilizer is not inherently bad, as all plants need these nutrients to survive, but when an area is overfertilized or incorrectly fertilized, that pollution becomes a problem. Read more: Fertilizers & Pollution | eHow.com http://www.ehow.com/info_7962176_fertilizerspollution.html#ixzz20XXmqFii .diunduh dari: http://www.ehow.com/info_7962176_fertilizers-pollution.html . Ways to Prevent Fertilizer Pollution Langkah paling penting yang dapat dilakukan untuk mencegah pencemaran pupuk adalah melakukan uji tanah sebelum memupuk. Sebagian besar negara memiliki laboratorium, seringkali melalui kerjasama dengan perguruan tinggi, di mana petani dapat mengirim sanpel tanah, dan dengan sedikit biaya, petani dapat belajar hara apa yang dibutuhkan dan hara mana yang sudah cukup. Petani juga dapat memilih pupuk organik, yang ketersediaan haranya lebih lambat daripada pupuk anorganik yang normal. Akhirnya, jangan memupuk di sepanjang sungai atau danau, tidak jangan memupuk sesaat sebelum hujan lebat turun Read more: Fertilizers & Pollution | eHow.com http://www.ehow.com/info_7962176_fertilizerspollution.html#ixzz20XYG0Tu5 Nutrient Cycling in Agroecosystems Volume 43, Numbers 1-3 (1995), 5-7, DOI: 10.1007/BF00747675 Fertigation for minimizing environmental pollution by fertilizers J. Hagin and Anat Lowengart Intensification of agriculture by irrigation and enhanced use of fertilizers may generate pollution by increased levels of nutrients in underground and surface waters. Most of the irrigation is by open systems having a relatively low efficiency of water application. A higher efficiency may be gained by pressurized irrigation systems. Drip irrigation generates a restricted root system requiring frequent nutrient supply that may be satisfied by applying fertilizers in irrigation water, i.e. by fertigation. Maximization of crop yield and quality and minimization of leaching below the rooting volume may be achieved by managing fertilizers concentrations in measured quantities of irrigation water, according to crop requirements. Diunduh dari: http://www.springerlink.com/content/f7360216p2685610/ SusTools - Tools for Sustainability: Development and Application of an Integrated Framework (Contract N° EVG3-CT-2002-80010) Final Report on Work Package 4 Damage Costs of Nitrogen Fertiliser and Their Internalization H. von Blottnitz & A. Rabl, D. Boiadjiev, T. Taylor & S. Arnold, This report summarizes the environmental impacts and costs of synthetic nitrogen (N) fertiliser and discusses options for reducing these impacts, including their consequences for farmers and for producers of fertiliser. The external costs of the fertiliser life cycle that could be estimated are large, about 0.3 €/kgN (compared to the current market price of about 0.5 €/kgN); much of that is due to global warming by N2O and CO2 emissions during fertiliser production and N2O emissions from fertilised fields. If the external cost were internalized by a pollution tax or tradable permits that are auctioned by the government, the economic consequences would be heavy, with a large profit loss for farmers. But if it is internalized by tradable permits that are given out free, the revenue loss for farmers is small. With the internalisation of 0.3 €/kgN the farmers’ profit contribution crop yield × crop price – fertiliser used × fertiliser price decreases by < 0.5 % for most crops, except for crops with low €/ha revenue; the average loss to farmers in the UK is about 0.1%. The revenue loss for fertiliser producers is larger (for most crops <10% with the internalisation of 0.3 €/kgN, except for crops with low €/ha revenue). The loss for fertiliser producers increases linearly with the amount of external cost that is internalized, by contrast to the loss for farmers which increases quadratically. Diunduh dari: http://wwwcenerg.ensmp.fr/english/themes/impact/papers/WP4_N_Fertil%20FinalReport.pdf Communications in Soil Science and Plant Analysis, 36: 1625–1639, 2005 Copyright # Taylor & Francis, Inc. ISSN 0010-3624 print/1532-2416 online DOI: 10.1081/CSS-200059104 Nitrogen Fertilizer Losses from Rice Soils and Control of Environmental Pollution Problems A. T. M. A. Choudhury and I. R. Kennedy Nitrogen (N) requirements of rice crop are met from both the soil and fertilizers. Because of acute N deficiency in most rice soils, fertilizer N must be applied to meet the crop demand. N fertilizer applied to rice crops is partially lost through different mechanisms, including ammonia volatilization, denitrification, and leaching. These losses may cause environmental problems such as polluting the atmosphere, aquatic systems, and groundwater. These problems cannot be alleviated completely. However, they can be reduced a considerable extent by various techniques. Research has been conducted around the world to minimize N fertilizer losses. This paper reviews this information on N fertilizer losses, indicating management practices for minimizing these losses from the soil-water system. Diunduh dari: http://www.bashanfoundation.org/ivan/ivanpollution.pdf Landbauforschung Völkenrode 2 (52):81-90 Impact of fertilizers on aquatic ecosystems and protection of water bodies from mineral nutrients Ulrich Kremser and Ewald Schnug Pollution by nutrients from agricultural activities causes many problems in the environment. Fertilization is considered as one of the main sources of pollution of water bodies caused by agriculture. When high fertilizer rates are applied which are not in line with the codes of good agricultural practice, nutrient losses, e.g. by surface runoff, take place which pollute land-based and aquatic ecosystems. Fertilizer use, its impact on water bodies and their protection are comprehensively discussed in this contribution. An oversupply with inorganic nitrogen and phosphorus compounds causes an increased nitrification, oxygen demand, intensification of the primary production of plankton including „red tides“, excessive growths of macro-algae and other water plants as well as formation of the toxic un-ionized ammonia. The negative impact of nutrient losses from agriculture on ecosystems in ponds, lakes, rivers as well as to seas and oceans varies . Oxygen deficiencies in the bottom waters of shallow areas may result in the production of hydrosulfide which is highly toxic. Low oxygen concentration in deep water layers where fish spawn may prevent the development of eggs. Increased density of macro-algae in shallow waters of seas might affect the composition of species too. Defense strategies were developed in order to minimize the environmental burden caused by agricultural pollution. The so-called end of the pipe solution which means to clean up the water body after pollution occurred is rather inefficient in natural waters. A preferable alternative is the reduction or even prevention of pollution, e.g. by making fertilization more efficient and more environmentally friendly. Programs for protecting the water bodies against input of nutrients from agriculture are developed and are being implemented. Such programs could be supported by concepts like balanced fertilization, ecological agriculture etc.. The more updated programs are serving a holistic view and try to combat, minimize or prevent pollution by nutrients. Diunduh dari: http://sharepoint.snoqualmie.k12.wa.us/ckms/spiesse/Lists/Announcements .. Journal of Contaminant Hydrology Volume 20, Issues 3–4, December 1995, Pages 167–184 Fertilizer-N use efficiency and nitrate pollution of groundwater in developing countries Bijay-Singh, Yadvinder-Singh, G.S. Sekhon Around 76% of the world's population lives in developing countries where more fertilizer-N is currently applied than in developed countries. Fertilizers are applied preferentially in regions where irrigation is available, and soil and climatic conditions are favorable for the growth of crop plants. Due to low N application rates during the last 3 or 4 decades, negative N balances in the soil are a characteristic feature of the crop production systems in developing countries. In the future, with increasing fertilizer-N application rates, the possibility of nitrate pollution of groundwater in developing countries will be strongly linked with fertilizer-N use efficiency. A limited number of investigations from developing countries suggest that, in irrigated soils of Asia or in humid tropics of Africa, the potential exists for nitrate pollution of groundwater, especially if fertilizer-N is inefficiently managed. In a large number of developing countries in West and Central Asia and North Africa, the small amount of fertilizer applied to soils (mostly Aridisols) that remain dry almost all the year, do not constitute a major threat for nitrate pollution of groundwater, except possibly when soils are irrigated. In Asia and the Pacific regions, where 70% of the fertilizers are used to grow wetland rice on soils with low percolation rates, leaching of nitrates is minimal. Climatic water balance and soil moisture conditions do not favor leaching of nitrates from the small amount of fertilizer-N applied to Oxisols and Ultisols in Latin America. In developing countries located in the humid tropics, attempts have not been made to correlate fertilizer-N use with nitrate level in groundwater; however, fertilizers are being increasingly used. Besides high rainfall, irrigation is becoming increasingly available to farmers in the humid tropics and substantial leaching of N may also increase. Diunduh dari: http://www.sciencedirect.com/science/article/pii/0169772295000674