Name:___________________________ Period:__________________________ Chemistry Unit 6 – Covalent Compounds and Covalent Bonding Chemistry Daily Journal Today’s Date What do I need to accomplish today? What do I need to finish up at home? Objective □ Learning Opportunities 6.1 Write Names and Formulas for Covalent Compounds □ □ □ □ □ □ □ □ □ □ Podcast 5.5 Bonding Basics Read p. 268-270; Questions 20-24 p. 270 Naming Molecular Compounds Writing Formulas From Names Naming Covalent Compounds Quiz (12/2) Podcast 5.6 Molecular Structures Molecular Structural Formulas Electronegativity and Polarity POGIL 12/2 Unit 6 Review 12/4 Unit 6 Molecular Geometry Quiz 12/5 6.2 Sketch Molecular Structures for Covalent Compounds 6.3 Determine if a Compound is Nonpolar Covalent, Polar Covalent, or Ionic Suggested Due Date 12/01/14 Date Completed 12/04/14 12/05/14 1 Podcast 5.5: Naming Covalent Compounds What is a covalent bond? Atoms ______________________ one or more electrons with each other to form the bond. Each atom is left with a ______________________ outer shell. A covalent bond forms between two ______________________. Example C1: Hydrogen + Hydrogen Example C2: 2 Hydrogen + Oxygen Example C3: Chlorine + Chlorine Example C4: Oxygen + Oxygen Example C5: Carbon + 2 Oxygen Example C6: Carbon + 4 Hydrogen Challenge: What are some other ionic or covalent bonds that can be formed by the elements you see? Write the chemical formula for the compound and its name on a separate piece of paper and attach to this page. -ide ending, each element has “prefix” prefix refers to _________________ of __________ – NOT CHARGE N2O4 = Exception: drop mono- for ________element CO2 = The first vowel is often dropped to avoid the combination of “___” or “___”. 1 2 3 4 5 6 7 8 9 10 mono di tri tetra penta hexa hepta octo nono deca CO = P4O10 = SO2 = Example: Name the following covalent compounds. a) CCl4 b) P2O3 c) IF7 Writing Formulas from Names 1. Identify the ____________________ involved 2. Use the ______________to write the formula Examples: a) Nitrogen dioxide c) Tetraphosphorous decoxide b) Dinitrogen trioxide d) Xenon tetrafluoride WARNING!!! **Decide whether the compound is ionic or covalent BEFORE trying to name it or write it’s formula! Example: Fe2O3 is called ____________________ or iron (III) oxide, NOT di-iron trioxide MEMORIZE THIS ONE: NH3 is called ___________. Nitrogen trihydride is OK, but it already has a name 2 Naming Molecular Compounds A. Name the following molecular compounds. 1. CO2 _______________________________ 11. PCl3 ____________________________ 2. CO _______________________________ 12. PCl5 ____________________________ 3. SO2 _______________________________ 13. NH3 ____________________________ 4. SO3 _______________________________ 14. SCl6 ____________________________ 5. N2O _______________________________ 15. P2O5 ____________________________ 6. NO _______________________________ 16. CCl4 ____________________________ 7. N2O3 _______________________________ 17. SiO2 ____________________________ 8. NO2 _______________________________ 18. CS2 ____________________________ 9. N2O4 _______________________________ 19. OF2 ____________________________ 10. N2O5 _______________________________ 20. PBr3 _____________________________ B. Write formulas for the following molecular compounds. 1. Carbon monoxide ___________________ 2. Diphosphorus pentaoxide ___________________ 3. Sulfur dioxide ___________________ 4. Phosphorus tribromide ___________________ 5. Dinitrogen tetraoxide ___________________ 6. Sulfur hexachloride ___________________ 7. Oxygen difluoride ___________________ 8. Carbon disulfide ___________________ 9. Iodine heptafluoride ___________________ 10. Chlorine trifluoride ___________________ 11. Phosphorus pentabromide ___________________ 12. Dichlorine heptoxide ___________________ 13. Trisilicon Tetranitride ___________________ 14. Phosphorus pentabromide ___________________ 15. Dicarbon octabromide ___________________ 3 Naming Molecular Compounds 1. CO2 _______________________________ 6. Chlorine trifluoride ____________ 2. PCl3 _______________________________ 7. Phosphorus tribromide ____________ 3. SO3 _______________________________ 8. Dichlorine heptoxide ____________ 4. SCl6 _______________________________ 9. Phosphorus pentabromide ____________ 5. N2O5 _______________________________ 10. Carbon monoxide ____________ Naming ALL Compounds For this section you will be naming ionic compound, molecular compounds. You will need to determine what type of compound it is and them name it correctly. Give the stock name when appropriate. Formula Type of Compound Name 1. SF6 2. PbCl2 3. ZnSO4 4. Al(OH)3 5. Al2O3 6. N2O3 For this section you will be given the name of a compound. You will need to determine what type of compound it is (ionic, molecular, acid, or base) and write the correct formula. Name Type of Compound Chemical Formula 7. Lead (II) sulfide 8. Zinc hydroxide 9. Ammonium carbonate 10. Chromium (III) sulfite 11. Sulfur trioxide 12. Tetraphosphorus decoxide 13. Plumbic carbonate 14. Sodium hydroxide 15. Barium sulfite 16. Carbon tetrachloride 4 Podcast 5.6: Molecular Structures Molecular Compounds • Molecule – A ______________ group of atoms joined together by covalent bonds • Covalent Bond – Sharing of electrons between two or more ____________________ Molecular Formulas • Represents how many atoms of each element are in the compound – Cannot be determined by the __________ - ___________ Method – Can be determined by creating a structural (Lewis dot) formula • Octet Rule – Atoms still tend to attain the electron configuration for a __________ ________ by sharing electrons Structural Formula Shows the arrangement of covalently bonded atoms using ______________ as bonds (shared electrons) and _____________ as unshared electrons Example – Hydrogen (Lewis Dot Structure) Creates an electron configuration of _____________ (noble gas) for both hydrogens by sharing the electrons (Structural Formula) Shared electrons represented by a dash Drawing Structural Formulas – Steps 1) Count the _____________________________________________________ for the compound ex. CH4 (methane) 2) Arrange the __________________ – _________________ is NEVER in the middle – Elements with only one atom are typically in the middle and usually written _____________ in the formula 3) Fill in electrons, starting around the ___________ atom(s) until all your valence electrons are used. 4) Draw ________________ (dashes) for any _______________electron pairs and leave all unshared electrons where they are. Drawing Structural Formulas – Now Try These – H2O – F2 – NH3 Bond Order • Single Bond – Two atoms held together by sharing ______ electrons (1 pair) • Double Bond 5 • • • • – Two atoms held together by sharing ______ electrons (2 pairs) Triple Bond – Two atoms held together by sharing ______ electrons (3 pairs) Double and triple bonds NEVER form with ________________ or the ___________________!! Examples Double and triple bonds are needed sometimes to satisfy the ________________ rule for all the atoms in the compound. Exceptions to Octet Rule (Page 228) – For small atoms, like Boron • BF3 – For some atoms in the 3p-block that have access to d-orbitals and can be _________-____________ • PCl5 or SF6 Molecular Shape • Compounds are ______________-DIMENSIONAL • ____________ – Valence-Shell Electron-Pair Repulsion Theory – The negative charge on electrons _________ each other creating molecular shapes where the electrons are as far away from each other as possible. Common Shapes • Tetrahedral (Angle – 109.5⁰) • Trigonal Pyramidal • Bent • Linear • Trigonal Planar • There are others – page 233 6 Name: _______________________ Molecular Formulas Lewis Dot, Structural Formulas, and Shape For each of the compounds below, create the Lewis dot structure, structural formula, and a 3-D model. Be sure to show your work for calculating the number of valence electrons and give the shape of the molecule. Molecular Formula Valence Electron Calculations Lewis Dot Structure Structural Formula Shape Polar Bonds? Yes/No Polar Molecule? Yes/No 1. H2O 2. CH4 3. HCl 4. C2H6 5. NH3 6. CO2 7 Molecular Formula Valence Electron Calculations Lewis Dot Structure Structural Formula Shape Polar Bonds? Yes/No Polar Molecule? Yes/No 7. H2O2 8. H2CO (Try building this before drawing it) 9. H2S 10. C3H8 11. PCl3 12. CCl4 8 Molecular Formula Valence Electron Calculations Lewis Dot Structure Structural Formula Shape Polar Bonds? Yes/No Polar Molecule? Yes/No 13. NO2 14. NO2-1 15. CO3 2- 16. HCN Use the table bellow to answer determine the shape of each molecule (more shapes can be found on p. 233 in your textbook): Bonding Pairs 4 3 2 1 Non-Bonding Pairs 0 1 2 3 Molecular Shape Tetrahedral Pyramidal Bent Linear 9 Molecular Compounds Review 1. Describe the difference between an ionic , a metallic, and a covalent bond. 2. How many ELECTRONS do two atoms in a triple bond share? 3. How many VALENCE ELECTRONS are in a molecule of Cl2O? 4. How many VALENCE ELECTRONS are in a molecule of CuC2H3O2? Use the table bellow to answer the following three questions: Bonding Pairs Non-Bonding Pairs 4 0 3 1 2 2 1 3 Molecular Shape Tetrahedral Pyramidal Bent Linear 5. Draw the structural formula (with the dashes) of I2 and give the shape of the molecule. Describe whether the BONDS on the central atom are polar or nonpolar. Then tell whether the overall molecule is polar or nonpolar. 6. Draw the structural formula (with the dashes) of PF3 and give the shape of the molecule. Describe whether the BONDS on the central atom are polar or nonpolar. Then tell whether the overall molecule is polar or nonpolar. 7. Draw the structural formula (with the dashes) of SCl2 and give the shape of the molecule. Describe whether the BONDS on the central atom are polar or nonpolar. Then tell whether the overall molecule is polar or nonpolar. 8. Determine if the following substances are ionic compounds, molecular compounds, then name the substance or give its chemical formula (not just the charges). Type of compound a. Name/Formula PI3 ____________________ __________________________________ b. K2CO3 ____________________ __________________________________ c. KI ____________________ __________________________________ d. Nitrogen dioxide ____________________ __________________________________ e. Tin (IV) cyanide ____________________ __________________________________ 10