Review Unit 6 – Bonding I. Bond Types: Fill in the table to show the basics of bond types. Type of Electrons Type of What holds Bond atoms transferred Compound the bond involved or shared? formed together? M/N Trans Ionic Polar e- transfer, Ionic electrostatic forces N/N Shared Covalent Sharing of eCovalent Polar and Nonpolar M Shared Alloys Sharing of eMetallic II. Short Answer: 1. Why are some covalent bonds polar? Higher electronegative atoms unequally share the electrons in the bond. 2. Which of the following compounds express polarity? To which element are the compounds polar too? a. H2O Yes O b. HF Yes F c. CCl4 No d. CO2 Yes O 3. What are Binary Acids? List 4 and include the formula for each. Binary acids consist of H and another element. HF HCl HI HBr 4. What are Tertiary Acids? List 4 and include the formula for each. Tertiary Acids include H and a polyatomic ion in most cases. HNO3, HClO3, HPO4, and H2SO3 5. How does electronegativity relate to the strength of an acid? The higher the electronegativity the greater the strength of the acid. 6. Is it possible for a bond to be partially ionic? Explain. No, only whole electrons are transferred in an ionic bond resulting in a definite charge. 7. What is an ion? How does it form? An ion is a charged atom that forms from the gain or loss of electrons. 8. What is a polyatomic ion? What kind of bond holds the atoms in a polyatomic ion together? A polyatomic ion is a charged, covalently bonded molecule that combines with a metal to form an ionic compound. 9. Show the electron configuration for each of the atoms below and the configuration for the ion as well. a. Ca 1s2 2s2 2p6 3s2 3p6 4s2 Ion: 1s2 2s2 2p6 3s2 3p6 b. N 1s2 2s2 2p3 Ion: 1s2 2s2 2p6 c. Hg (ion: 2+) [Xe] 6s2 4f14 5d10 Ion: [Xe] 4f14 5d10 *** Remember the valence shell is the highest quantum number. That is why 6s left. III. Lewis Dot Structures: Show the bonding that would occur in the following compounds. 1. Carbon tetrachloride 4. Barium oxide 2. Potassium chloride 5. Nitrogen trihydride 3. Copper (II) fluoride 6. Hydrosulfuric acid IV. Ionic, Molecular and Metallic Compounds: Complete the chart below. Type of Bond Solubility Yes Ionic Covalent Only with like molecules No Conductivity In aqueous and little in molten No Melting Point Relatively high Yes moderate Relatively low Metallic V. Write formulas for the following compounds. 1. magnesium oxide MgO 2. Potassium hydroxide KOH 3. copper (II) carbonate CuCO3 4. acetic acid CH3COOH 5. lead (II) nitrate Pb (NO3)2 6. carbon disulfide CS2 7. iron (III) chloride FeCl3 8. ammonium phosphate (NH4)3PO4 9. nitrogen tribromide NH3 10.potassium tungstate K2WO4 11.nitrous acid HNO2 12.hydrosulfuric acid H2SO4 13.sulfur dioxide SO2 14.sodium chlorate NaClO3 15.copper (I) sulfite Cu2SO3 VI. Write names for the following compounds. 8. PCl3 Phosphorus trichloride 9. (NH4)2CO3 Ammonium 1. BaCl2 Barium Chloride Carbonate 2. K2CO3 Potassium Carbonate 10. NO2 Nitrogen Dioxide 3. HgI2 Mecury (II) Iodide 11. AuBr Gold(I) Bromide 4. HNO3 Nitrous Acid 12. H3PO3 Phosphorus acid 5. Ca(NO3)2 Calcium Nitrate 13. Na2O Sodium Oxide 6. CuO Copper (II) Oxide 14. NBr Sodium Bromide 7. HI Hydroiodic acid 15. CaO Calcium oxide Vocabulary Chapter 8 chemical bond cation anion ionic bond electrolyte lattice energy delocalized electrons alloy 1. 2. 3. 4. 5. 6. 6. 7. 8. formula unit monatomic ion oxidation number polyatomic ion oxyanion electron sea model metallic bond Chapter 9 covalent bond molecule Lewis structure endothermic exothermic structural formula Given a name for a compound, be able to give the chemical formula. (ionic, covalent or acid) Give the chemical formula for a compound, be able to name it. (ionic, covalent or acid) Be able to explain why two elements will form an ionic bond. Be able to explain properties of metals, based on their bonding. Be able to explain why water is a polar molecule. Be able to explain what an electrolyte is. Be able to draw Lewis Structures of ionic compounds or molecules. Be able to determine if a bond is polar, nonpolar covalent or polar covalent. Know properties of ionic and covalent compounds and metals.